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In addition to these natural CIs, an external electric field can create light-induced conical intersections (LICIs), as the dipole\u2013field interaction shifts the coupled potential energy surfaces. This work explores the effect of LICIs on the minor molecular (NH + H2) channel of ammonia photodissociation, building on prior work that studied the major radical (NH2 + H) channel. The molecular channel can involve intersystem crossing to the low-lying triplet state. A Floquet Hamiltonian was used to simulate the dynamics of ammonia photodissociation in the presence of an external laser field. A total of 230\u2009000 quasi-classical trajectory surface-hopping calculations were performed with SHARC using recently reported diabatic potential energy matrices, dipole matrices, and spin\u2013orbit coupling matrices, which were fitted using neural networks. With the field off, 0.04% of trajectories with a total energy of 8.4\u00a0eV yielded triplet NH. With an electric field strength of 0.02 Ha\/ea0, over 0.3% of trajectories yielded triplet NH (an eightfold increase), and this value was even larger for higher field strengths.<\/jats:p>","DOI":"10.1063\/5.0284970","type":"journal-article","created":{"date-parts":[[2025,8,27]],"date-time":"2025-08-27T10:27:49Z","timestamp":1756290469000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":2,"title":["Intersystem crossing in the molecular channel of ammonia photodissociation manipulated by an external laser field"],"prefix":"10.1063","volume":"163","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2389-2801","authenticated-orcid":false,"given":"Chris","family":"Avanessian","sequence":"first","affiliation":[{"name":"Department of Chemistry, Johns Hopkins University , Baltimore, Maryland 21218,","place":["USA"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2025,8,27]]},"reference":[{"issue":"20","key":"2025082706274229200_c1","doi-asserted-by":"publisher","first-page":"457","DOI":"10.1002\/andp.19273892002","article-title":"Zur quantentheorie der molekeln","volume":"389","year":"1927","journal-title":"Ann. 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