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Species-resolved phase space shifting constitutes a gauge transformation, which we analyze using Noether\u2019s theorem and shifting differential operators that encapsulate the gauge invariance. The approach yields exact equilibrium sum rules for general mixtures. Species-resolved gauge correlation functions for the force\u2013force and force\u2013gradient pair correlation structure emerge on the two-body level. Exact 3g-sum rules relate these correlation functions to the spatial Hessian of the partial pair distribution functions. General observables are associated with hyperforce densities that measure the covariance of the given observable with the interparticle, external, and diffusive partial force density observables. Exact hyperforce and Lie algebra sum rules interrelate these correlation functions with each other. The practical accessibility of the framework is demonstrated for binary Lennard-Jones mixtures using both adaptive Brownian dynamics and grand canonical Monte Carlo simulations. In particular, we investigate the force\u2013force pair correlation structure of the Kob\u2013Andersen bulk liquid and we show results for representative hyperforce correlation functions in the symmetrical mixture of Wilding et\u00a0al. confined between two asymmetric planar parallel walls.<\/jats:p>","DOI":"10.1063\/5.0303764","type":"journal-article","created":{"date-parts":[[2026,1,23]],"date-time":"2026-01-23T11:19:27Z","timestamp":1769167167000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":8,"title":["Gauge invariance and hyperforce correlation theory for equilibrium fluid mixtures"],"prefix":"10.1063","volume":"164","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-8689-2121","authenticated-orcid":false,"given":"Joshua","family":"Matthes","sequence":"first","affiliation":[{"name":"Theoretische Physik II, Physikalisches Institut, Universit\u00e4t Bayreuth 1 , D-95447 Bayreuth,","place":["Germany"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-4991-9898","authenticated-orcid":false,"given":"Silas","family":"Robitschko","sequence":"additional","affiliation":[{"name":"Theoretische Physik II, Physikalisches Institut, Universit\u00e4t Bayreuth 1 , D-95447 Bayreuth,","place":["Germany"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-2490-7562","authenticated-orcid":false,"given":"Johanna","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Theoretische Physik II, Physikalisches Institut, Universit\u00e4t Bayreuth 1 , D-95447 Bayreuth,","place":["Germany"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4012-9170","authenticated-orcid":false,"given":"Sophie","family":"Hermann","sequence":"additional","affiliation":[{"name":"CNRS, Sorbonne Universit\u00e9, Physicochimie des Electrolytes et Nanosyst\u00e8mes Interfaciaux 2 , F-75005 Paris,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3605-329X","authenticated-orcid":false,"given":"Florian","family":"Samm\u00fcller","sequence":"additional","affiliation":[{"name":"Theoretische Physik II, Physikalisches Institut, Universit\u00e4t Bayreuth 1 , D-95447 Bayreuth,","place":["Germany"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5015-2972","authenticated-orcid":false,"given":"Matthias","family":"Schmidt","sequence":"additional","affiliation":[{"name":"Theoretische Physik II, Physikalisches Institut, Universit\u00e4t Bayreuth 1 , D-95447 Bayreuth,","place":["Germany"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2026,1,23]]},"reference":[{"issue":"2","key":"2026012306192383500_c1","doi-asserted-by":"publisher","first-page":"38","DOI":"10.1063\/pt.3.4135","article-title":"From simple liquids to colloids and soft matter","volume":"72","year":"2019","journal-title":"Phys. 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