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Highly stable materials under extreme conditions are typically considered for technological applications, and high-pressure researchers always try to find such materials to build a world of strong and stable materials science. In this context, we are inclined to investigate the corundum-type structure of \u03b1-Cr2O3 NPs under dynamic acoustic shock conditions and compare it with previously reported \u03b1-Fe2O3 NPs. From the structural point of view, under acoustic shock conditions, \u03b1-Cr2O3 NPs remain the same with the R3-c space group even at the 200-shocked condition, whereas in \u03b1-Fe2O3, the \u03b1-Fe2O3 (R3-c)-to-Fe3O4 (Fd-3m) transition is observed. For both these oxides, supporting evidence for the results is also presented via vibrational, optical, magnetic, thermal, electrical, and electrochemical properties. In addition, a possible mechanism is proposed, implementing a thermal conductivity-driven superheating approach to justify the stability order for both oxides. According to the observed static compression results and the current acoustic shock wave-induced results of these two oxides, the structural stability order is \u03b1-Cr2O3&amp;gt;\u03b1-Fe2O3. Due to the impressive results of structural stability under static and dynamic shock conditions, \u03b1-Cr2O3 is a more suitable candidate for extreme conditions such as aerospace and defense applications.<\/jats:p>","DOI":"10.1063\/5.0332828","type":"journal-article","created":{"date-parts":[[2026,5,22]],"date-time":"2026-05-22T10:13:02Z","timestamp":1779444782000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":3,"title":["Acoustic shock wave impact on stability aspects of crystal structure\u2013functional properties\u2014A case study of corundum-type structure of \u03b1-Cr2O3 nanoparticles"],"prefix":"10.1063","volume":"164","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3640-2031","authenticated-orcid":false,"given":"Sivakumar","family":"Aswathappa","sequence":"first","affiliation":[{"name":"School of Physics and Electronic Science, Guizhou Normal University 1 , Guiyang 550025,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9081-765X","authenticated-orcid":false,"given":"Lidong","family":"Dai","sequence":"additional","affiliation":[{"name":"School of Physics and Electronic Science, Guizhou Normal University 1 , Guiyang 550025,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2014-0268","authenticated-orcid":false,"given":"Sahaya Jude","family":"Dhas Sathiyadhas","sequence":"additional","affiliation":[{"name":"Department of Physics, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences (SIMATS), Saveetha University 2 , Chennai, Tamil Nadu 602105,","place":["India"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3754-4223","authenticated-orcid":false,"given":"Raju Suresh","family":"Kumar","sequence":"additional","affiliation":[{"name":"Department of Chemistry, College of Science, King Saud University 3 , P.O. Box 2455, Riyadh 11451,","place":["Saudi Arabia"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cathrin Lims","family":"Selvakumar","sequence":"additional","affiliation":[{"name":"4 Centre for Applied Nanomaterials, Chennai Institute of Technology, Chennai 600 069, Tamil Nadu, India"},{"name":"5 Department of Chemistry, National Sun Yat-sen University, Kaohsiung 804201, Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haiying","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Physics and Electronic Science, Guizhou Normal University 1 , Guiyang 550025,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1035-1141","authenticated-orcid":false,"given":"Bing","family":"Lv","sequence":"additional","affiliation":[{"name":"School of Physics and Electronic Science, Guizhou Normal University 1 , Guiyang 550025,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuefei","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Physics and Electronic Science, Guizhou Normal University 1 , Guiyang 550025,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziqiang","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Physics and Electronic Science, Guizhou Normal University 1 , Guiyang 550025,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8636-6366","authenticated-orcid":false,"given":"Abdulrahman I.","family":"Almansour","sequence":"additional","affiliation":[{"name":"Department of Chemistry, College of Science, King Saud University 3 , P.O. 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