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In this study, we examined the effects of nanoconfinement on both the structure and molecular dynamics of the prototypical DES ethaline (a mixture of choline chloride and ethylene glycol) when confined within the cylindrical mesopores of SBA-15 (Dp \u2248 8.1\u00a0nm) and MCM-41 (Dp \u2248 3.5\u00a0nm) silicas, using neutron diffraction and quasielastic neutron scattering. It demonstrates that ethaline remains structurally homogeneous under confinement, showing no evidence of core\u2013shell segregation within the pore cross section. The molecular dynamics of the confined ethaline preserve the key characteristics observed in its bulk state. Translational diffusion follows a jump-diffusion mechanism, with diffusion coefficients that remain remarkably close to the bulk values, showing only a modest reduction in MCM-41. A more pronounced increase in the residence time \u03c40 between translational molecular jumps is observed. It corresponds to roughly a factor of 3\u20138 under confinement in SBA-15 and reaches up to a tenfold enhancement in MCM-41 relative to bulk. Similarly, the characteristic relaxation time, \u03c4L, associated with the localized in-cage motion of ethaline, increases by \u223c20% in SBA-15 and up to 50% in MCM-41. However, the molecular trajectories, modeled from the elastic incoherent structure factor, remain largely preserved under confinement, showing only a marginal reduction in intra-basin motional amplitudes.<\/jats:p>","DOI":"10.1063\/5.0340802","type":"journal-article","created":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T11:24:06Z","timestamp":1784805846000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":0,"title":["Ethaline deep eutectic solvent under nanoconfinement: Unveiling structural and dynamical changes"],"prefix":"10.1063","volume":"165","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-5614-1018","authenticated-orcid":false,"given":"Mohammad Nadim","family":"Kamar","sequence":"first","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6389-8802","authenticated-orcid":false,"given":"Armin","family":"Mozhdehei","sequence":"additional","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5508-9645","authenticated-orcid":false,"given":"Ronan","family":"Lefort","sequence":"additional","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1627-0334","authenticated-orcid":false,"given":"Alain","family":"Mor\u00e9ac","sequence":"additional","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2806-8130","authenticated-orcid":false,"given":"Jacques","family":"Ollivier","sequence":"additional","affiliation":[{"name":"Institut Laue-Langevin 2 , 71 Avenue des Martyrs, F-38000 Grenoble,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6069-7573","authenticated-orcid":false,"given":"Markus","family":"Appel","sequence":"additional","affiliation":[{"name":"Institut Laue-Langevin 2 , 71 Avenue des Martyrs, F-38000 Grenoble,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3608-9222","authenticated-orcid":false,"given":"Viviana","family":"Cristiglio","sequence":"additional","affiliation":[{"name":"Institut Laue-Langevin 2 , 71 Avenue des Martyrs, F-38000 Grenoble,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8784-3021","authenticated-orcid":false,"given":"Denis","family":"Morineau","sequence":"additional","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2026,7,23]]},"reference":[{"issue":"1","key":"2026072307240071800_c1","doi-asserted-by":"publisher","first-page":"70","DOI":"10.1039\/b210714g","article-title":"Novel solvent properties of choline chloride\/urea mixtures","volume":"39","year":"2003","journal-title":"Chem. 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