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Differential scanning calorimetry, Raman spectroscopy, quasielastic neutron scattering, 1H spin\u2013lattice relaxation, and pulsed-field-gradient nuclear magnetic resonance (NMR) were combined to probe thermal behavior, hydrogen-bond structure, local mobility, and translational transport over complementary time and length scales. The calorimetric results show that LiCl\u2009\u00b7\u20096H2O remains glass-forming under confinement, while its thermal signature of the glass transition becomes slightly broader and shifts upward relative to the bulk. Raman spectra in the O\u2013H stretching region indicate that the concentrated LiCl solution possesses a weakened and less tetrahedrally connected hydrogen-bond network compared with bulk water. On the sub-nanosecond timescale, elastic fixed-window analysis reveals reduced mean-squared displacements under confinement, demonstrating suppressed motional amplitudes inside the pores. Inelastic fixed-window neutron scattering scans analyzed within a jump-diffusion framework yield lower effective translational diffusion coefficients and longer residence times for the confined liquid, indicating that confinement mainly hinders translational escape from transient local environments. 1H relaxometry further shows that confinement broadens the distribution of local proton fluctuation times, while PFG-NMR confirms that the measured long-range water mobility in bulk LiCl\u2009\u00b7\u20096H2O solution is reduced relative to bulk water. While the present data do not resolve distinct interfacial and pore-centered populations in confined LiCl\u2009\u00b7\u20096H2O, its dynamics are markedly altered across timescales, from the glassy to the liquid state, resulting in slower, spatially constrained, and more heterogeneous motions.<\/jats:p>","DOI":"10.1063\/5.0340804","type":"journal-article","created":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T10:36:49Z","timestamp":1784716609000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":1,"title":["Glassy dynamics of LiCl\u2009\u00b7\u20096H2O solution in nanoporous media"],"prefix":"10.1063","volume":"165","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6389-8802","authenticated-orcid":false,"given":"Armin","family":"Mozhdehei","sequence":"first","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-5614-1018","authenticated-orcid":false,"given":"Mohammad Nadim","family":"Kamar","sequence":"additional","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5508-9645","authenticated-orcid":false,"given":"Ronan","family":"Lefort","sequence":"additional","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1627-0334","authenticated-orcid":false,"given":"Alain","family":"Moreac","sequence":"additional","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-3508-6324","authenticated-orcid":false,"given":"Arnaud","family":"Le Pottier","sequence":"additional","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7053-3441","authenticated-orcid":false,"given":"Agathe","family":"Belime","sequence":"additional","affiliation":[{"name":"Institut Laue-Langevin 2 , F-38042 Grenoble,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8784-3021","authenticated-orcid":false,"given":"Denis","family":"Morineau","sequence":"additional","affiliation":[{"name":"Institute of Physics of Rennes, CNRS-University of Rennes, UMR 6251 1 , F-35042 Rennes,","place":["France"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2026,7,22]]},"reference":[{"key":"2026072206364012700_c1","doi-asserted-by":"publisher","first-page":"115915","DOI":"10.1016\/j.molliq.2021.115915","article-title":"Structural relaxation in the aqueous solution LiCl\u2009\u00b7\u20096D2O by quasielastic neutron scattering","volume":"332","year":"2021","journal-title":"J.\u00a0Mol. 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