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However, two major limitations of CTC are their low absorption coefficient and harsh preparation. In this study, Ce3+ with 4f\u20135d orbital coupling was used to dope CTC, enabling the excitation band to shift from UV-B to UV-A and elevating the photoluminescence quantum yield from 33.52% to 96.43%. In addition, cerium-sensitized CTC microcrystals (MCs) with different dopant ratios were obtained to study the energy transfer process from Ce3+ to Tb3+, which were prepared via a simple monosolvent ethanol-assisted recrystallization method at room temperature. Finally, we used cerium-sensitized CTC MCs with excellent stability to fabricate the white light-emitting diodes. This work not only offers a deep understanding of competitive energy transfer in zero-dimensional lanthanide-based metal halides, but also presents a direct ambient synthesis strategy of highly emissive and robustly stable phosphor for white light illumination.<\/jats:p>","DOI":"10.1063\/5.0342541","type":"journal-article","created":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T10:37:01Z","timestamp":1784716621000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":0,"title":["Direct ambient synthesis of cerium-sensitized Cs3TbCl6 microcrystals with near-unity photoluminescence quantum yield and robust stability for white lighting"],"prefix":"10.1063","volume":"165","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-7826-4200","authenticated-orcid":false,"given":"Yanqing","family":"Zu","sequence":"first","affiliation":[{"name":"Institute of Physics & Optoelectronics Technology, Baoji University of Arts and Sciences 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