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By explicitly evaluating the nuclear kinetic energy operator, we analyze cavity-induced modifications of DBOC within a quantum electrodynamics configuration\u2013interaction framework built on quantum electrodynamics Hartree\u2013Fock (QED-HF) and strong-coupling quantum electrodynamics Hartree\u2013Fock (SC-QED-HF) reference states. The analysis covers a diverse set of atomic and molecular systems, including He, H\u2212, Be, H2, LiH, HF, ammonia (NH3), and formaldehyde (CH2O). We show that the presence of the cavity leads to shifts in molecular dissociation energies on the order of a few inverse centimeters. For several atomic systems, the inclusion of the DBOC yields a pronounced effect, with the correction magnitude reaching the experimental resolution. These findings reveal finite nuclear mass effects as an essential component of nuclear dynamics in cavity QED and suggest their relevance for precision analysis in strongly coupled light\u2013matter systems.<\/jats:p>","DOI":"10.1063\/5.0349306","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T12:14:03Z","timestamp":1790079243000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":0,"title":["Non-adiabatic effects induced by strong light\u2013matter coupling in cavity QED"],"prefix":"10.1063","volume":"165","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8468-0901","authenticated-orcid":false,"given":"T.","family":"Zalialiutdinov","sequence":"first","affiliation":[{"name":"Department of Physics, St. Petersburg State University 1 , Petrodvorets, Oulianovskaya 1, 198504 St. Petersburg,","place":["Russia"]},{"name":"Petersburg Nuclear Physics Institute Named After B.P. Konstantinov of National Research Centre \u201cKurchatov Institut,\u201d St. Petersburg 2 , Gatchina 188300,","place":["Russia"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0634-0906","authenticated-orcid":false,"given":"D.","family":"Solovyev","sequence":"additional","affiliation":[{"name":"Department of Physics, St. Petersburg State University 1 , Petrodvorets, Oulianovskaya 1, 198504 St. Petersburg,","place":["Russia"]},{"name":"Petersburg Nuclear Physics Institute Named After B.P. Konstantinov of National Research Centre \u201cKurchatov Institut,\u201d St. Petersburg 2 , Gatchina 188300,","place":["Russia"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J. J.","family":"Lopez-Rodriguez","sequence":"additional","affiliation":[{"name":"Department of Physics, St. Petersburg State University 1 , Petrodvorets, Oulianovskaya 1, 198504 St. Petersburg,","place":["Russia"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0160-125X","authenticated-orcid":false,"given":"A.","family":"Anikin","sequence":"additional","affiliation":[{"name":"Department of Physics, St. Petersburg State University 1 , Petrodvorets, Oulianovskaya 1, 198504 St. Petersburg,","place":["Russia"]},{"name":"D. I. Mendeleev Institute for Metrology 3 , St. Petersburg 190005,","place":["Russia"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4629-138X","authenticated-orcid":false,"given":"A.","family":"Kotov","sequence":"additional","affiliation":[{"name":"Department of Physics, St. Petersburg State University 1 , Petrodvorets, Oulianovskaya 1, 198504 St. Petersburg,","place":["Russia"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2026,9,22]]},"reference":[{"key":"2026092208135615700_c1","doi-asserted-by":"publisher","first-page":"1592","DOI":"10.1002\/anie.201107033","article-title":"Modifying chemical landscapes by coupling to vacuum fields","volume":"51","year":"2012","journal-title":"Angew. Chem., Int. 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