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Apart from emphasizing the role of both cavity-system and intramolecular energy transfer to the observed enhancements, we highlight the complexity of the VSC mechanism in terms of the choice of the cavity frequency vis-\u00e0-vis the various molecular mode frequencies. Our work shows that, in principle, cavity quantum electrodynamics can reshape dynamical outcomes in reactions with complex potential energy landscapes.<\/jats:p>","DOI":"10.1063\/5.0353664","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T10:53:12Z","timestamp":1791456792000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":0,"title":["Vibrational strong coupling influences product selectivity in a model for post-transition-state bifurcation reactions"],"prefix":"10.1063","volume":"165","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2798-149X","authenticated-orcid":false,"given":"Subhadip","family":"Mondal","sequence":"first","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology , Kanpur, Uttar Pradesh 208016,","place":["India"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-1374-1651","authenticated-orcid":false,"given":"Atul","family":"Kumar","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology , Kanpur, Uttar Pradesh 208016,","place":["India"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4424-6745","authenticated-orcid":false,"given":"Srihari","family":"Keshavamurthy","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology , Kanpur, Uttar Pradesh 208016,","place":["India"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"317","published-online":{"date-parts":[[2026,10,8]]},"reference":[{"key":"2026100806530962600_c1","doi-asserted-by":"publisher","first-page":"11462","DOI":"10.1002\/anie.201605504","article-title":"Ground-state chemical reactivity under vibrational coupling to the vacuum electromagnetic field","volume":"55","year":"2016","journal-title":"Angew. 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