{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,20]],"date-time":"2025-09-20T19:24:39Z","timestamp":1758396279618},"reference-count":32,"publisher":"AIP Publishing","issue":"19","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2003,11,15]]},"abstract":"<jats:p>The interaction of free electrons with the potent greenhouse molecule SF5CF3 is studied under different degrees of aggregation: single molecules at collision free conditions, clusters within a supersonic molecular beam and condensed molecules. Electron collisions with single molecules are dominated by SF5\u2212 formation produced via dissociative electron attachment (DEA) within a resonance located below 2 eV. In clusters, undissociated parent anions SF5CF3\u2212 (and larger complexes containing undissociated anions) are observed in addition to the fragment ions. This indicates that (i) SF5CF3 possesses a positive adiabatic electron affinity and (b) low energy attachment is partly channeled into nondissociative processes when the molecule is coupled to an environment. Electron impact to condensed phase SF5CF3 exhibits a remarkably strong F\u2212 desorption signal appearing from a pronounced resonance located at 11 eV while in the gas phase at 11 eV only a weak DEA signal is observed. Electron induced desorption from sub-monolayers of SF5CF3 on an amorphous H2O ice surface is found to be more efficient compared to desorption of SF5CF3 from a Xe surface. The implications of these results for the heterogeneous photochemistry of SF5CF3 adsorbed on ice or dust particles in the Earth\u2019s atmosphere are discussed.<\/jats:p>","DOI":"10.1063\/1.1617978","type":"journal-article","created":{"date-parts":[[2003,10,31]],"date-time":"2003-10-31T00:54:00Z","timestamp":1067561640000},"page":"10396-10403","update-policy":"http:\/\/dx.doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":14,"title":["Low energy electron interaction with free and bound SF5CF3: Negative ion formation from single molecules, clusters and nanofilms"],"prefix":"10.1063","volume":"119","author":[{"given":"Richard","family":"Balog","sequence":"first","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institut f\u00fcr Chemie\u2014Physikalische und Theoretische Chemie, Takustrasse 3, D-14195\u2009Berlin"}]},{"given":"Michal","family":"Stano","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institut f\u00fcr Chemie\u2014Physikalische und Theoretische Chemie, Takustrasse 3, D-14195\u2009Berlin"}]},{"given":"Paulo","family":"Lim\u00e3o-Vieira","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institut f\u00fcr Chemie\u2014Physikalische und Theoretische Chemie, Takustrasse 3, D-14195\u2009Berlin"}]},{"given":"Constanze","family":"K\u00f6nig","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institut f\u00fcr Chemie\u2014Physikalische und Theoretische Chemie, Takustrasse 3, D-14195\u2009Berlin"}]},{"given":"Ilko","family":"Bald","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institut f\u00fcr Chemie\u2014Physikalische und Theoretische Chemie, Takustrasse 3, D-14195\u2009Berlin"}]},{"given":"Nigel J.","family":"Mason","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institut f\u00fcr Chemie\u2014Physikalische und Theoretische Chemie, Takustrasse 3, D-14195\u2009Berlin"}]},{"given":"Eugen","family":"Illenberger","sequence":"additional","affiliation":[{"name":"Freie Universit\u00e4t Berlin, Institut f\u00fcr Chemie\u2014Physikalische und Theoretische Chemie, Takustrasse 3, D-14195\u2009Berlin"}]}],"member":"317","reference":[{"key":"2024021020441709100_r1","doi-asserted-by":"crossref","first-page":"611","DOI":"10.1126\/science.289.5479.611","volume":"289","year":"2000","journal-title":"Science"},{"key":"2024021020441709100_r2","first-page":"i","volume":"206","year":"2001","journal-title":"Int. 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