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The cusp barrier height is half the electronic coupling, as expected from the equality found for the frequencies of the reactant well and barrier top in this process. Coupling to solvent polarization modes can control the friction effect on the reactive mode. A two-dimensional reaction surface explains the photophysical features detected in the radiationless decay and a state energy diagram is proposed for rhodamine-3B.<\/jats:p>","DOI":"10.1063\/1.1676124","type":"journal-article","created":{"date-parts":[[2004,4,12]],"date-time":"2004-04-12T22:24:51Z","timestamp":1081808691000},"page":"8095-8106","update-policy":"http:\/\/dx.doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":4,"title":["Activated radiationless decay of rhodamine-3B: Nonequilibrium polarization effects in viscous solvents"],"prefix":"10.1063","volume":"120","author":[{"given":"Jos\u00e9 A. 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