{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,28]],"date-time":"2025-09-28T12:46:44Z","timestamp":1759063604373},"reference-count":43,"publisher":"AIP Publishing","issue":"23","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2004,6,15]]},"abstract":"<jats:p>The vacuum ultraviolet (VUV) absorption spectrum (3.50\u201310.33 eV, 350\u2013120 nm) of gaseous 2-vinyl furan has been measured for the first time using both synchrotron radiation source and electron energy loss spectroscopies with absolute cross section determinations. The He\u200aI photoelectron spectrum obtained at higher resolution than previously has been interpreted with the aid of semiempirical molecular orbital calculations. Three excited states of type \u03c0\u03c0*1 are found responsible for an intense and structured first band observed between 4.2 and 5.8 eV (295\u2013214 nm). Three triplet states were detected for the first time at about 2.46, 3.35, and 3.8 eV (477, 370, and 328 nm) which are, from the calculations, assigned as \u03c0\u03c0*3. Some partial Rydberg series, linked to IE1 and IE2 are identified. The VUV absorption spectrum bears little resemblance to that of the parent compound, furan. The electronically excited molecule is found akin to a linear polyene.<\/jats:p>","DOI":"10.1063\/1.1738642","type":"journal-article","created":{"date-parts":[[2004,5,21]],"date-time":"2004-05-21T22:01:20Z","timestamp":1085176880000},"page":"10972-10982","update-policy":"http:\/\/dx.doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":4,"title":["On the valence shell electronic spectroscopy of 2-vinyl furan"],"prefix":"10.1063","volume":"120","author":[{"given":"A.","family":"Giuliani","sequence":"first","affiliation":[{"name":"Laboratoire de Spectroscopie d\u2019Electrons Diffus\u00e9s, Universit\u00e9 de Li\u00e8ge, Institut de Chimie, B\u00e2t. B6c, B-4000\u2009Sart-Tilman Li\u00e8ge, Belgium"}]},{"given":"I. C.","family":"Walker","sequence":"additional","affiliation":[{"name":"School of Engineering and Physical Sciences, Heriot-Watt University, Riccarton, Edinburgh\u2009EH144AS, United Kingdom"}]},{"given":"J.","family":"Delwiche","sequence":"additional","affiliation":[{"name":"Thermodynamique et Spectroscopie, Universit\u00e9 de Li\u00e8ge, Institut de Chimie, B\u00e2t. B6c, B-4000\u2009Sart-Tilman Li\u00e8ge, Belgium"}]},{"given":"S. V.","family":"Hoffmann","sequence":"additional","affiliation":[{"name":"Institute for Storage Ring Facilities, University of \u00c5rhus, Ny Munkegade, DK-8000\u2009\u00c5rhus C, Denmark"}]},{"given":"C.","family":"Kech","sequence":"additional","affiliation":[{"name":"Centre de Recherche du Cyclotron, Universit\u00e9 de Li\u00e8ge, B\u00e2t. B30, All\u00e9e du 6 ao\u00fbt, B-4000\u2009Sart-Tilman Li\u00e8ge, Belgium"}]},{"given":"P.","family":"Lim\u00e3o-Vieira","sequence":"additional","affiliation":[{"name":"Department of Physics and Astronomy, University College London, Gower Street, London\u2009WC1\u2009E6BT, United Kingdom"}]},{"given":"N. J.","family":"Mason","sequence":"additional","affiliation":[{"name":"Department of Physics and Astronomy, University College London, Gower Street, London\u2009WC1\u2009E6BT, United Kingdom"}]},{"given":"M.-J.","family":"Hubin-Franskin","sequence":"additional","affiliation":[{"name":"Laboratoire de Spectroscopie d\u2019Electrons Diffus\u00e9s, Universit\u00e9 de Li\u00e8ge, Institut de Chimie, B\u00e2t. 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Phys."},{"key":"2024020704460530200_r6","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/0301-0104(94)00386-O","volume":"192","year":"1995","journal-title":"Chem. Phys."},{"key":"2024020704460530200_r7","doi-asserted-by":"crossref","first-page":"3839","DOI":"10.1021\/ma951522f","volume":"29","year":"1996","journal-title":"Macromolecules"},{"key":"2024020704460530200_r8","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/S1383-5718(98)00141-7","volume":"420","year":"1998","journal-title":"Mutat Res."},{"key":"2024020704460530200_r9","doi-asserted-by":"crossref","first-page":"406","DOI":"10.1016\/j.cplett.2003.08.063","volume":"379","year":"2003","journal-title":"Chem. Phys. Lett."},{"key":"2024020704460530200_r10","doi-asserted-by":"crossref","first-page":"3216","DOI":"10.1139\/v76-459","volume":"54","year":"1976","journal-title":"Can. J. Chem."},{"key":"2024020704460530200_r11","doi-asserted-by":"crossref","first-page":"3981","DOI":"10.1021\/ja00481a001","volume":"100","year":"1978","journal-title":"J. Am. Chem. Soc."},{"key":"2024020704460530200_r12","first-page":"197","volume":"21","year":"1980","journal-title":"Zh. Strukt. Khim."},{"key":"2024020704460530200_r13","first-page":"281","volume":"56","year":"1983","journal-title":"Croat. Chem. Acta"},{"key":"2024020704460530200_r14","doi-asserted-by":"crossref","first-page":"1291","DOI":"10.1016\/S0040-4020(01)92999-0","volume":"26","year":"1970","journal-title":"Tetrahedron"},{"key":"2024020704460530200_r15","doi-asserted-by":"crossref","first-page":"1303","DOI":"10.1016\/S0040-4020(01)93000-5","volume":"26","year":"1970","journal-title":"Tetrahedron"},{"key":"2024020704460530200_r16","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1016\/0368-2048(72)85012-6","volume":"1","year":"1972","journal-title":"J. Electron Spectrosc. Relat. 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