{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T20:00:51Z","timestamp":1760472051761,"version":"3.41.2"},"reference-count":35,"publisher":"AIP Publishing","issue":"1","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2012,1,1]]},"abstract":"<jats:p>X-ray diffraction and magnetization measurements of the Bi0.9Sm0.1Fe1\u2212yMnyO3 and Bi0.86Sm0.14Fe1\u2212zMnzO3 (y\u2009\u2264\u20090.4, z\u2009\u2264\u20090.3) series were carried out in order to follow the effect of Mn doping on the room temperature crystal structure and magnetic properties of Sm-substituted BiFeO3. Initially polar rhombohedral Bi0.9Sm0.1FeO3 compound (space group R3c) was shown to undergo the Mn-substitution driven structural transformation into the orthorhombic Pnam phase at y\u2009\u223c\u20090.2. Further increasing of the Mn content stabilizes the modified structural phase demonstrating the features of incommensurability. In the Bi0.86Sm0.14Fe1\u2212zMnzO3 series, the initially dominant antipolar orthorhombic Pnam phase transforms toward the nonpolar Pnma structure (z\u2009\u223c\u20090.3). Changes of the main magnetic state (from mixed antiferromagnetic\/weak ferromagnetic to weak ferromagnetic) were found to correlate with the rhombohedral-to-orthorhombic transition; however, within the compositional range of the orthorhombically distorted compounds, the room temperature spontaneous magnetization rapidly decreases with increasing Mn content.<\/jats:p>","DOI":"10.1063\/1.3676205","type":"journal-article","created":{"date-parts":[[2012,1,13]],"date-time":"2012-01-13T03:27:17Z","timestamp":1326425237000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":29,"title":["Mn substitution-driven structural and magnetic phase evolution in Bi1\u2212xSmxFeO3 multiferroics"],"prefix":"10.1063","volume":"111","author":[{"given":"V. A.","family":"Khomchenko","sequence":"first","affiliation":[{"name":"University of Coimbra 1 CEMDRX\/Department of Physics, Faculty of Sciences and Technology, , 3004-516 Coimbra, Portugal"}]},{"given":"I. O.","family":"Troyanchuk","sequence":"additional","affiliation":[{"name":"SSPA \u201cScientific-Practical Materials Research Centre of NAS of Belarus 2 ,\u201d P. Brovka str. 19, 220072 Minsk, Belarus"}]},{"given":"M. I.","family":"Kovetskaya","sequence":"additional","affiliation":[{"name":"SSPA \u201cScientific-Practical Materials Research Centre of NAS of Belarus 2 ,\u201d P. Brovka str. 19, 220072 Minsk, Belarus"}]},{"given":"J. A.","family":"Paix\u00e3o","sequence":"additional","affiliation":[{"name":"University of Coimbra 1 CEMDRX\/Department of Physics, Faculty of Sciences and Technology, , 3004-516 Coimbra, Portugal"}]}],"member":"317","published-online":{"date-parts":[[2012,1,12]]},"reference":[{"key":"2023080123355752100_c1","doi-asserted-by":"publisher","first-page":"R123","DOI":"10.1088\/0022-3727\/38\/8\/R01","volume":"38","year":"2005","journal-title":"J. Phys. D: Appl. Phys."},{"key":"2023080123355752100_c2","doi-asserted-by":"publisher","first-page":"303201","DOI":"10.1088\/0953-8984\/21\/30\/303201","volume":"21","year":"2009","journal-title":"J. Phys.: Condens. Matter"},{"key":"2023080123355752100_c3","doi-asserted-by":"publisher","first-page":"698","DOI":"10.1107\/S0108768190006887","volume":"46","year":"1990","journal-title":"Acta Crystallogr., Sect. B: Struct. Sci."},{"key":"2023080123355752100_c4","doi-asserted-by":"publisher","first-page":"022907","DOI":"10.1063\/1.2753390","volume":"91","year":"2007","journal-title":"Appl. Phys. Lett."},{"key":"2023080123355752100_c5","doi-asserted-by":"publisher","first-page":"845","DOI":"10.3367\/UFNe.0179.200908i.0897","volume":"52","year":"2009","journal-title":"Phys. Usp."},{"key":"2023080123355752100_c6","doi-asserted-by":"publisher","first-page":"4835","DOI":"10.1088\/0022-3719\/15\/23\/020","volume":"15","year":"1982","journal-title":"J. Phys. C"},{"key":"2023080123355752100_c7","doi-asserted-by":"publisher","first-page":"491","DOI":"10.1016\/0375-9601(91)90467-M","volume":"158","year":"1991","journal-title":"Phys. Lett. A"},{"key":"2023080123355752100_c8","doi-asserted-by":"publisher","first-page":"285","DOI":"10.1021\/cm1030975","volume":"23","year":"2011","journal-title":"Chem. Mater."},{"key":"2023080123355752100_c9","doi-asserted-by":"publisher","first-page":"054109","DOI":"10.1103\/PhysRevB.83.054109","volume":"83","year":"2011","journal-title":"Phys. Rev. B"},{"key":"2023080123355752100_c10","doi-asserted-by":"publisher","first-page":"5102","DOI":"10.1007\/s10853-009-3545-1","volume":"44","year":"2009","journal-title":"J. Mater. Sci."},{"key":"2023080123355752100_c11","doi-asserted-by":"publisher","first-page":"1578","DOI":"10.1007\/s10853-011-6040-4","volume":"47","year":"2012","journal-title":"J. Mater. Sci."},{"key":"2023080123355752100_c12","doi-asserted-by":"publisher","first-page":"2166","DOI":"10.1021\/cm1036925","volume":"23","year":"2011","journal-title":"Chem. Mater."},{"key":"2023080123355752100_c13","doi-asserted-by":"publisher","first-page":"152902","DOI":"10.1063\/1.3481065","volume":"97","year":"2010","journal-title":"Appl. Phys. Lett."},{"key":"2023080123355752100_c14","doi-asserted-by":"publisher","first-page":"1970","DOI":"10.1016\/j.matlet.2011.04.009","volume":"65","year":"2011","journal-title":"Mater. Lett."},{"key":"2023080123355752100_c15","doi-asserted-by":"publisher","first-page":"1492","DOI":"10.1016\/j.physb.2011.01.055","volume":"406","year":"2011","journal-title":"Physica B"},{"key":"2023080123355752100_c16","doi-asserted-by":"publisher","first-page":"238","DOI":"10.1002\/crat.201100040","volume":"46","year":"2011","journal-title":"Cryst. Res. Technol."},{"key":"2023080123355752100_c17","doi-asserted-by":"publisher","first-page":"185406","DOI":"10.1088\/0022-3727\/44\/18\/185406","volume":"44","year":"2011","journal-title":"J. Phys. D: Appl. Phys."},{"key":"2023080123355752100_c18","doi-asserted-by":"publisher","first-page":"5176","DOI":"10.1021\/cm9021084","volume":"21","year":"2009","journal-title":"Chem. Mater."},{"key":"2023080123355752100_c19","doi-asserted-by":"publisher","first-page":"67","DOI":"10.1080\/00150190903001706","volume":"391","year":"2009","journal-title":"Ferroelectrics"},{"key":"2023080123355752100_c20","doi-asserted-by":"publisher","first-page":"3462","DOI":"10.1039\/c0dt01754j","volume":"40","year":"2011","journal-title":"Dalton Trans."},{"key":"2023080123355752100_c21","doi-asserted-by":"publisher","first-page":"756","DOI":"10.1107\/S0567739475001635","volume":"31","year":"1975","journal-title":"Acta Crystallogr., Sect. A: Cryst Phys., Diffr., Theor. Gen. Crystallogr."},{"key":"2023080123355752100_c22","doi-asserted-by":"publisher","first-page":"238","DOI":"10.1016\/j.scriptamat.2009.11.005","volume":"62","year":"2010","journal-title":"Scr. Mater."},{"key":"2023080123355752100_c23","doi-asserted-by":"publisher","first-page":"54","DOI":"10.1134\/S1063776106070077","volume":"103","year":"2006","journal-title":"J. Exp. Theor. Phys."},{"key":"2023080123355752100_c24","doi-asserted-by":"publisher","first-page":"100","DOI":"10.1006\/jssc.1994.1141","volume":"110","year":"1994","journal-title":"J. Solid State Chem."},{"key":"2023080123355752100_c25","doi-asserted-by":"publisher","first-page":"751","DOI":"10.1107\/S0567739476001551","volume":"32","year":"1976","journal-title":"Acta Crystallogr., Sect. A: Cryst Phys., Diffr., Theor. Gen. Crystallogr."},{"key":"2023080123355752100_c26","doi-asserted-by":"publisher","first-page":"8137","DOI":"10.1021\/ja102014n","volume":"132","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2023080123355752100_c27","doi-asserted-by":"publisher","first-page":"14S","DOI":"10.1063\/1.1984590","volume":"31","year":"1960","journal-title":"J. Appl. Phys."},{"key":"2023080123355752100_c28","doi-asserted-by":"publisher","first-page":"1177","DOI":"10.1016\/j.jmmm.2006.10.287","volume":"310","year":"2007","journal-title":"J. Magn. Magn. Mater."},{"key":"2023080123355752100_c29","doi-asserted-by":"publisher","first-page":"4505","DOI":"10.1021\/cm201774y","volume":"23","year":"2011","journal-title":"Chem. Mater."},{"key":"2023080123355752100_c30","doi-asserted-by":"publisher","first-page":"060401","DOI":"10.1103\/PhysRevB.71.060401","volume":"71","year":"2005","journal-title":"Phys. Rev. B"},{"key":"2023080123355752100_c31","doi-asserted-by":"publisher","first-page":"134417","DOI":"10.1103\/PhysRevB.80.134417","volume":"80","year":"2009","journal-title":"Phys. Rev. B"},{"key":"2023080123355752100_c32","doi-asserted-by":"publisher","first-page":"1019","DOI":"10.1080\/01411590601067235","volume":"79","year":"2006","journal-title":"Phase Transitions"},{"key":"2023080123355752100_c33","doi-asserted-by":"publisher","first-page":"094108","DOI":"10.1103\/PhysRevB.84.094108","volume":"84","year":"2011","journal-title":"Phys. Rev. B"},{"key":"2023080123355752100_c34","doi-asserted-by":"publisher","first-page":"241","DOI":"10.1016\/0022-3697(58)90076-3","volume":"4","year":"1958","journal-title":"J. Phys. Chem. Solids"},{"key":"2023080123355752100_c35","doi-asserted-by":"publisher","first-page":"91","DOI":"10.1103\/PhysRev.120.91","volume":"120","year":"1960","journal-title":"Phys. Rev."}],"container-title":["Journal of Applied Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/jap\/article-pdf\/doi\/10.1063\/1.3676205\/14104261\/014110_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/jap\/article-pdf\/doi\/10.1063\/1.3676205\/14104261\/014110_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,1]],"date-time":"2023-08-01T23:36:06Z","timestamp":1690932966000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/jap\/article\/111\/1\/014110\/926834\/Mn-substitution-driven-structural-and-magnetic"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,1,1]]},"references-count":35,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2012,1,1]]}},"URL":"https:\/\/doi.org\/10.1063\/1.3676205","relation":{},"ISSN":["0021-8979","1089-7550"],"issn-type":[{"type":"print","value":"0021-8979"},{"type":"electronic","value":"1089-7550"}],"subject":[],"published-other":{"date-parts":[[2012,1,1]]},"published":{"date-parts":[[2012,1,1]]},"article-number":"014110"}}