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A 2 \u00d7 2 diabatic representation of the potential energy surface is suggested for N3(2A\u2032), which, combined with the two previously reported adiabatic forms for 2A\u2033 and another for 4A\u2033, completes the set of five global potentials required to study the title collisional processes. The trajectory results provide the first N(2D)+N2 rate constants, and allow a comparison with the ones for N(4S)+N2. Nonadiabatic effects are estimated by surface hopping, and the geometrical phase effect assessed by following the trajectories that encircle the crossing seam.<\/jats:p>","DOI":"10.1063\/1.4737858","type":"journal-article","created":{"date-parts":[[2012,8,2]],"date-time":"2012-08-02T01:02:32Z","timestamp":1343869352000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":29,"title":["N(4<i>S<\/i>\u2009\/2<i>D<\/i>)+N2: Accurate <i>ab initio<\/i>-based DMBE potential energy surfaces and surface-hopping dynamics"],"prefix":"10.1063","volume":"137","author":[{"given":"B. R. L.","family":"Galv\u00e3o","sequence":"first","affiliation":[{"name":"Universidade de Coimbra Departamento de Qu\u00edmica, , 3004-535 Coimbra, Portugal"}]},{"given":"P. J. S. B.","family":"Caridade","sequence":"additional","affiliation":[{"name":"Universidade de Coimbra Departamento de Qu\u00edmica, , 3004-535 Coimbra, Portugal"}]},{"given":"A. J. 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