{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,10]],"date-time":"2025-12-10T08:36:46Z","timestamp":1765355806700,"version":"3.41.2"},"reference-count":50,"publisher":"AIP Publishing","issue":"16","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2014,4,28]]},"abstract":"<jats:p>Crystal structure, microstructure, local ferroelectric, and magnetic properties of the Bi0.9Nd0.1Fe1\u2212xTixO3 samples have been investigated at room temperature to reveal the effect of Ti4+ doping on the multiferroic behavior of the lanthanide-modified compound representing a polar (space group R3c) antiferromagnetic phase of the Bi1\u2212xLnxFeO3 perovskites. Ti doping results in a gradual suppression of the rhombohedral distortions, however, symmetry of the crystal structure remains the same in the entire concentration range allowing the single-phase perovskites to be obtained (x\u2009\u2264\u20090.08). The doping tends to reduce existing lone-pair cation-driven polar displacements, thus giving rise to a decrease of the ferroelectric polarization in the Bi0.9Nd0.1Fe1\u2212xTixO3 (x\u21920.08) series. A drastic (from \u223c10\u2009\u03bcm for x\u2009=\u20090 to \u223c1\u2009\u03bcm for 0.02\u2009\u2264\u2009x\u2009\u2264\u20090.08) decrease of the average grain size induced by the doping is accompanied by the formation of a ferroelectric domain structure with the average domain width of \u223c40\u2009nm. Finally, the doping was shown to induce an antiferromagnetic to weak ferromagnetic transformation. The maximum remanent magnetization observed in the Bi0.9Nd0.1Fe1\u2212xTixO3 series at x\u2009\u223c\u20090.05 coincides with the locked magnetization releasing upon the magnetic field-induced suppression of the magnetic cycloid in pure BiFeO3.<\/jats:p>","DOI":"10.1063\/1.4873121","type":"journal-article","created":{"date-parts":[[2014,4,23]],"date-time":"2014-04-23T11:25:19Z","timestamp":1398252319000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":23,"title":["Weak ferromagnetism and nanodimensional ferroelectric domain structure stabilized in the polar phase of Bi1\u2212xNdxFeO3 multiferroics via Ti doping"],"prefix":"10.1063","volume":"115","author":[{"given":"V. A.","family":"Khomchenko","sequence":"first","affiliation":[{"name":"University of Coimbra 1 CEMDRX\/Department of Physics, , P-3004-516 Coimbra, Portugal"}]},{"given":"L. C. J.","family":"Pereira","sequence":"additional","affiliation":[{"name":"Instituto Superior T\u00e9cnico, Universidade T\u00e9cnica de Lisboa\/CFMCUL 2 Unidade de Ci\u00eancias Qu\u00edmicas e Radiofarmac\u00eauticas, IST\/CTN, , P-2686-953 Sacav\u00e9m, Portugal"}]},{"given":"J. A.","family":"Paix\u00e3o","sequence":"additional","affiliation":[{"name":"University of Coimbra 1 CEMDRX\/Department of Physics, , P-3004-516 Coimbra, Portugal"}]}],"member":"317","published-online":{"date-parts":[[2014,4,22]]},"reference":[{"key":"2023070503433479900_c1","doi-asserted-by":"publisher","first-page":"759","DOI":"10.1038\/nature05023","volume":"442","year":"2006","journal-title":"Nature"},{"key":"2023070503433479900_c2","doi-asserted-by":"publisher","first-page":"13","DOI":"10.1038\/nmat1804","volume":"6","year":"2007","journal-title":"Nature Mater."},{"key":"2023070503433479900_c3","doi-asserted-by":"publisher","first-page":"21","DOI":"10.1038\/nmat1805","volume":"6","year":"2007","journal-title":"Nature Mater."},{"key":"2023070503433479900_c4","doi-asserted-by":"publisher","first-page":"321","DOI":"10.1080\/00018730902920554","volume":"58","year":"2009","journal-title":"Adv. Phys."},{"key":"2023070503433479900_c5","doi-asserted-by":"publisher","first-page":"2463","DOI":"10.1002\/adma.200802849","volume":"21","year":"2009","journal-title":"Adv. Mater."},{"key":"2023070503433479900_c6","doi-asserted-by":"publisher","first-page":"698","DOI":"10.1107\/S0108768190006887","volume":"46","year":"1990","journal-title":"Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem."},{"key":"2023070503433479900_c7","doi-asserted-by":"publisher","first-page":"537","DOI":"10.1107\/S0108768107023956","volume":"63","year":"2007","journal-title":"Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem."},{"key":"2023070503433479900_c8","doi-asserted-by":"publisher","first-page":"022907","DOI":"10.1063\/1.2753390","volume":"91","year":"2007","journal-title":"Appl. Phys. Lett."},{"key":"2023070503433479900_c9","doi-asserted-by":"publisher","first-page":"224412","DOI":"10.1103\/PhysRevB.74.224412","volume":"74","year":"2006","journal-title":"Phys. Rev. B"},{"key":"2023070503433479900_c10","doi-asserted-by":"publisher","first-page":"564","DOI":"10.1103\/PhysRev.100.564","volume":"100","year":"1955","journal-title":"Phys. Rev."},{"key":"2023070503433479900_c11","doi-asserted-by":"publisher","first-page":"87","DOI":"10.1016\/0022-3697(59)90061-7","volume":"10","year":"1959","journal-title":"J. Phys. Chem. Solids"},{"key":"2023070503433479900_c12","doi-asserted-by":"publisher","first-page":"419","DOI":"10.1140\/epjb\/e2009-00281-5","volume":"71","year":"2009","journal-title":"Eur. Phys. J. B"},{"key":"2023070503433479900_c13","doi-asserted-by":"publisher","first-page":"4835","DOI":"10.1088\/0022-3719\/15\/23\/020","volume":"15","year":"1982","journal-title":"J. Phys. C"},{"key":"2023070503433479900_c14","doi-asserted-by":"publisher","first-page":"241","DOI":"10.1016\/0022-3697(58)90076-3","volume":"4","year":"1958","journal-title":"J. Phys. Chem. Solids"},{"key":"2023070503433479900_c15","doi-asserted-by":"publisher","first-page":"91","DOI":"10.1103\/PhysRev.120.91","volume":"120","year":"1960","journal-title":"Phys. Rev."},{"key":"2023070503433479900_c16","doi-asserted-by":"publisher","first-page":"571","DOI":"10.1134\/1.1787107","volume":"79","year":"2004","journal-title":"JETP Lett."},{"key":"2023070503433479900_c17","doi-asserted-by":"publisher","first-page":"134417","DOI":"10.1103\/PhysRevB.80.134417","volume":"80","year":"2009","journal-title":"Phys. Rev. B"},{"key":"2023070503433479900_c18","doi-asserted-by":"publisher","first-page":"014407","DOI":"10.1103\/PhysRevB.86.014407","volume":"86","year":"2012","journal-title":"Phys. Rev. B"},{"key":"2023070503433479900_c19","doi-asserted-by":"publisher","first-page":"054109","DOI":"10.1103\/PhysRevB.83.054109","volume":"83","year":"2011","journal-title":"Phys. Rev. B"},{"key":"2023070503433479900_c20","doi-asserted-by":"publisher","first-page":"185406","DOI":"10.1088\/0022-3727\/44\/18\/185406","volume":"44","year":"2011","journal-title":"J. Phys. D: Appl. Phys."},{"key":"2023070503433479900_c21","doi-asserted-by":"publisher","first-page":"034102","DOI":"10.1063\/1.4862433","volume":"115","year":"2014","journal-title":"J. Appl. Phys."},{"key":"2023070503433479900_c22","doi-asserted-by":"publisher","first-page":"3852","DOI":"10.1007\/s10853-013-7186-z","volume":"48","year":"2013","journal-title":"J. Mater. Sci."},{"key":"2023070503433479900_c23","doi-asserted-by":"publisher","first-page":"1533","DOI":"10.1021\/cm303743h","volume":"25","year":"2013","journal-title":"Chem. Mater"},{"key":"2023070503433479900_c24","doi-asserted-by":"publisher","first-page":"021102","DOI":"10.1063\/1.4818002","volume":"1","year":"2013","journal-title":"APL Mater."},{"key":"2023070503433479900_c25","doi-asserted-by":"publisher","first-page":"683","DOI":"10.1002\/adfm.201201835","volume":"23","year":"2013","journal-title":"Adv. Funct. Mater."},{"key":"2023070503433479900_c26","doi-asserted-by":"publisher","first-page":"182902","DOI":"10.1063\/1.4705431","volume":"100","year":"2012","journal-title":"Appl. Phys. Lett."},{"key":"2023070503433479900_c27","doi-asserted-by":"publisher","first-page":"3737","DOI":"10.1002\/adfm.201100191","volume":"21","year":"2011","journal-title":"Adv. Funct. Mater."},{"key":"2023070503433479900_c28","doi-asserted-by":"publisher","first-page":"285","DOI":"10.1021\/cm1030975","volume":"23","year":"2011","journal-title":"Chem. Mater."},{"key":"2023070503433479900_c29","doi-asserted-by":"publisher","first-page":"2166","DOI":"10.1021\/cm1036925","volume":"23","year":"2011","journal-title":"Chem. Mater."},{"key":"2023070503433479900_c30","doi-asserted-by":"publisher","first-page":"09NE08","DOI":"10.7567\/JJAP.50.09NE08","volume":"50","year":"2011","journal-title":"Jpn. J. Appl. Phys., Part 1"},{"key":"2023070503433479900_c31","doi-asserted-by":"publisher","first-page":"1108","DOI":"10.1002\/adfm.200902017","volume":"20","year":"2010","journal-title":"Adv. Funct. Mater."},{"key":"2023070503433479900_c32","doi-asserted-by":"publisher","first-page":"55","DOI":"10.1016\/0921-4526(93)90108-I","volume":"192","year":"1993","journal-title":"Physica B"},{"key":"2023070503433479900_c33","doi-asserted-by":"publisher","first-page":"756","DOI":"10.1107\/S0567739475001635","volume":"31","year":"1975","journal-title":"Acta Crystallogr., Sect. A: Found. Crystallogr."},{"key":"2023070503433479900_c34","doi-asserted-by":"publisher","first-page":"751","DOI":"10.1107\/S0567739476001551","volume":"32","year":"1976","journal-title":"Acta Crystallogr., Sect. A: Found. Crystallogr."},{"key":"2023070503433479900_c35","doi-asserted-by":"publisher","first-page":"6779","DOI":"10.1039\/c3cp50236h","volume":"15","year":"2013","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2023070503433479900_c36","doi-asserted-by":"publisher","first-page":"064105","DOI":"10.1103\/PhysRevB.73.064105","volume":"73","year":"2006","journal-title":"Phys. Rev. B"},{"key":"2023070503433479900_c37","doi-asserted-by":"publisher","first-page":"094111","DOI":"10.1103\/PhysRevB.83.094111","volume":"83","year":"2011","journal-title":"Phys. Rev. B"},{"key":"2023070503433479900_c38","doi-asserted-by":"publisher","first-page":"027602","DOI":"10.1103\/PhysRevLett.102.027602","volume":"102","year":"2009","journal-title":"Phys. Rev. Lett."},{"key":"2023070503433479900_c39","doi-asserted-by":"publisher","first-page":"135902","DOI":"10.1088\/0953-8984\/25\/13\/135902","volume":"25","year":"2013","journal-title":"J. Phys.: Condens. Matter"},{"key":"2023070503433479900_c40","doi-asserted-by":"publisher","first-page":"2497","DOI":"10.1002\/adma.201204584","volume":"25","year":"2013","journal-title":"Adv. Mater."},{"key":"2023070503433479900_c41","doi-asserted-by":"publisher","first-page":"062903","DOI":"10.1063\/1.1862336","volume":"86","year":"2005","journal-title":"Appl. Phys. Lett."},{"key":"2023070503433479900_c42","doi-asserted-by":"publisher","first-page":"233","DOI":"10.1016\/j.spmi.2014.01.003","volume":"67","year":"2014","journal-title":"Superlattices Microstruct."},{"key":"2023070503433479900_c43","doi-asserted-by":"publisher","first-page":"1578","DOI":"10.1007\/s10853-011-6040-4","volume":"47","year":"2012","journal-title":"J. Mater. Sci."},{"key":"2023070503433479900_c44","doi-asserted-by":"publisher","first-page":"020103","DOI":"10.1103\/PhysRevB.81.020103","volume":"81","year":"2010","journal-title":"Phys. Rev. B"},{"key":"2023070503433479900_c45","doi-asserted-by":"publisher","first-page":"4436","DOI":"10.1021\/cm402962q","volume":"25","year":"2013","journal-title":"Chem. Mater."},{"key":"2023070503433479900_c46","doi-asserted-by":"publisher","first-page":"045302","DOI":"10.1088\/0022-3727\/45\/4\/045302","volume":"45","year":"2012","journal-title":"J. Phys. D: Appl. Phys."},{"key":"2023070503433479900_c47","doi-asserted-by":"publisher","first-page":"214112","DOI":"10.1063\/1.4810764","volume":"113","year":"2013","journal-title":"J. Appl. Phys."},{"key":"2023070503433479900_c48","doi-asserted-by":"publisher","first-page":"355701","DOI":"10.1088\/0957-4484\/24\/35\/355701","volume":"24","year":"2013","journal-title":"Nanotechnology"},{"key":"2023070503433479900_c49","doi-asserted-by":"publisher","first-page":"7209","DOI":"10.1021\/jp110128t","volume":"115","year":"2011","journal-title":"J. Phys. Chem. C"},{"key":"2023070503433479900_c50","doi-asserted-by":"publisher","first-page":"094413","DOI":"10.1103\/PhysRevB.86.094413","volume":"86","year":"2012","journal-title":"Phys. Rev. B"}],"container-title":["Journal of Applied Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/jap\/article-pdf\/doi\/10.1063\/1.4873121\/15136113\/164101_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/jap\/article-pdf\/doi\/10.1063\/1.4873121\/15136113\/164101_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,7,5]],"date-time":"2023-07-05T18:21:18Z","timestamp":1688581278000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/jap\/article\/115\/16\/164101\/372789\/Weak-ferromagnetism-and-nanodimensional"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,4,22]]},"references-count":50,"journal-issue":{"issue":"16","published-print":{"date-parts":[[2014,4,28]]}},"URL":"https:\/\/doi.org\/10.1063\/1.4873121","relation":{},"ISSN":["0021-8979","1089-7550"],"issn-type":[{"type":"print","value":"0021-8979"},{"type":"electronic","value":"1089-7550"}],"subject":[],"published-other":{"date-parts":[[2014,4,28]]},"published":{"date-parts":[[2014,4,22]]},"article-number":"164101"}}