{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,22]],"date-time":"2026-04-22T05:35:06Z","timestamp":1776836106598,"version":"3.51.2"},"reference-count":44,"publisher":"AIP Publishing","issue":"1","funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia (Portuguese Science and Technology Foundation)","doi-asserted-by":"publisher","award":["PEst-OE\/QUI\/UI0313\/2014"],"award-info":[{"award-number":["PEst-OE\/QUI\/UI0313\/2014"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia (Portuguese Science and Technology Foundation)","doi-asserted-by":"publisher","award":["PTDC\/AAG-MAA\/4657\/2012"],"award-info":[{"award-number":["PTDC\/AAG-MAA\/4657\/2012"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia (Portuguese Science and Technology Foundation)","doi-asserted-by":"publisher","award":["PTDC\/CEQ-COM3249\/2012"],"award-info":[{"award-number":["PTDC\/CEQ-COM3249\/2012"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2015,7,7]]},"abstract":"<jats:p>An ab initio quantum dynamics study has been performed to explore the structural rearrangement of ground state CH4+ in subfemtosecond resolved photodynamics. The method utilizes time-dependent wave-packet propagation on the X\u02dc2T2 electronic manifold of the title cation in full dimensionality, including nonadiabatic coupling of the three electronic sheets. Good agreement is obtained with recent experiments [Baker et al., Science 312, 424 (2006)] which use high-order harmonic generation to probe the attosecond proton dynamics. The novel results provide direct theoretical support of the observations while unravelling the underlying details. With the geometrical changes obtained by calculating the expectation values of the nuclear coordinates as a function of time, the structural evolution is predicted to begin through activation of the totally symmetric a1 and doubly degenerate e modes. While the former retains the original Td symmetry of the cation, the Jahn-Teller active e mode conducts it to a D2d structure. At \u223c1.85 fs, the intermediate D2d structure is further predicted to rearrange to local C2v minimum geometry via Jahn-Teller active bending vibrations of t2 symmetry.<\/jats:p>","DOI":"10.1063\/1.4922906","type":"journal-article","created":{"date-parts":[[2015,7,6]],"date-time":"2015-07-06T17:22:06Z","timestamp":1436203326000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":19,"title":["Structural evolution of the methane cation in subfemtosecond photodynamics"],"prefix":"10.1063","volume":"143","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3060-795X","authenticated-orcid":false,"given":"T.","family":"Mondal","sequence":"first","affiliation":[{"name":"Birla Institute of Technology and Science 1 Department of Chemistry, , Pilani - K. K. Birla Goa Campus, Zuarinagar, Goa 403 726, India"}]},{"given":"A. J. 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