{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,25]],"date-time":"2026-03-25T16:44:33Z","timestamp":1774457073474,"version":"3.50.1"},"reference-count":18,"publisher":"AIP Publishing","issue":"12","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2015,12,1]]},"abstract":"<jats:p>The crystal structure and magnetic properties of the stoichiometric compounds La1\u22122xSr2xMn1\u2212xSbxO3 (0.1 \u2264 x \u2264 0.2) with manganese ions in the 3+ oxidation state are studied. These compounds exhibit rhombohedral structure at room temperatures, which transforms upon cooling into an orthorhombic structure without any signature of orbital ordering. The compounds with x \u2264 0.2 reveal a ferromagnetic ordering; their magnetization decreases with increasing the concentration of substitution ions. It is suggested that the observed ferromagnetism originates from the breakdown of orbital ordering and significant hybridization between the eg orbitals of Mn3+ and 2p orbitals of oxygen.<\/jats:p>","DOI":"10.1063\/1.4937365","type":"journal-article","created":{"date-parts":[[2015,12,31]],"date-time":"2015-12-31T18:04:57Z","timestamp":1451585097000},"page":"1006-1010","update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure and magnetic exchange in La1\u22122<i>x<\/i>Sr2<i>x<\/i>Mn1\u2212<i>x<\/i>Sb<i>x<\/i>O3 (<i>x<\/i> \u2264 0.2) solid solutions"],"prefix":"10.1063","volume":"41","author":[{"given":"D. V.","family":"Karpinsky","sequence":"first","affiliation":[{"name":"National Research University of Electronic Technology MIET , Zelenograd, Russia and , Minsk, Belarus"},{"name":"Scientific and Practical Materials Research Centre of the National Academy of Sciences of Belarus , Zelenograd, Russia and , Minsk, Belarus"}]},{"given":"I. O.","family":"Troyanchuk","sequence":"additional","affiliation":[{"name":"National Research University of Electronic Technology MIET , Zelenograd, Russia and , Minsk, Belarus"},{"name":"Scientific and Practical Materials Research Centre of the National Academy of Sciences of Belarus , Zelenograd, Russia and , Minsk, Belarus"}]},{"given":"M. V.","family":"Silibin","sequence":"additional","affiliation":[{"name":"National Research University of Electronic Technology MIET , Zelenograd, Russia"}]},{"given":"S. A.","family":"Gavrilov","sequence":"additional","affiliation":[{"name":"National Research University of Electronic Technology MIET , Zelenograd, Russia"}]},{"given":"M. V.","family":"Bushinsky","sequence":"additional","affiliation":[{"name":"Scientific and Practical Materials Research Centre of the National Academy of Sciences of Belarus , Minsk, Belarus"}]},{"given":"V.","family":"Sikolenko","sequence":"additional","affiliation":[{"name":"Joint Institute for Nuclear Research , Dubna, Russia"}]},{"given":"V.","family":"Sirenko","sequence":"additional","affiliation":[{"name":"B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine , 47 Lenin Ave., Kharkov 61103, Ukraine"}]},{"given":"D.","family":"Tebbens","sequence":"additional","affiliation":[{"name":"Helmholtz Zentrum Berlin for Materials and Energy , Berlin, Germany"}]}],"member":"317","reference":[{"key":"2023062814312672200_c1","doi-asserted-by":"publisher","first-page":"403","DOI":"10.1103\/PhysRev.82.403","volume":"82","year":"1951","journal-title":"Phys. Rev."},{"key":"2023062814312672200_c2","doi-asserted-by":"publisher","first-page":"127202","DOI":"10.1103\/PhysRevLett.98.127202","volume":"98","year":"2007","journal-title":"Phys. Rev. Lett."},{"key":"2023062814312672200_c3","doi-asserted-by":"publisher","first-page":"R3189","DOI":"10.1103\/PhysRevB.57.R3189","volume":"57","year":"1998","journal-title":"Phys. Rev. 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