{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T11:06:52Z","timestamp":1753873612670,"version":"3.41.2"},"reference-count":28,"publisher":"AIP Publishing","issue":"10","content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2016,3,14]]},"abstract":"<jats:p>The richly decorated foral charter attributed by D. Manuel I of Portugal, in 1515, to the village of Setubal, was studied using Energy Dispersive X-ray Fluorescence spectrometry and Raman micro-spectroscopy. An in situ characterization of the pigments used in the production of this masterpiece showed a very different pigment palette choice when compared to other similar Manueline charters. The red and green pigments are particularly puzzling, as the widely used mercury- and copper-based pigments, vermillion and malachite, respectively, were not found in the illuminated frontispiece. Instead, the cheaper lead-based pigment minium was used in the King's flag, while a mixture of copper sulfates was found for the green color, identified by means of micro-Raman spectroscopy. This result led to a new look at the conception that only one Royal workshop existed for the elaboration of Manueline foral charters.<\/jats:p>","DOI":"10.1063\/1.4943617","type":"journal-article","created":{"date-parts":[[2016,3,12]],"date-time":"2016-03-12T01:30:34Z","timestamp":1457746234000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":5,"title":["New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of \u03bc-Raman and X-ray fluorescence spectrometry"],"prefix":"10.1063","volume":"119","author":[{"given":"M.","family":"Guerra","sequence":"first","affiliation":[{"name":"LIBPhys-UNL 1 Laborat\u00f3rio de Instrumenta\u00e7\u00e3o, Engenharia Biom\u00e9dica e F\u00edsica da Radia\u00e7\u00e3o, , 2829-516 Caparica, Portugal"},{"name":"Universidade Nova de Lisboa 2 Departamento de F\u00edsica, Faculdade de Ci\u00eancias e Tecnologia, , 2829-516 Caparica, Portugal"}]},{"given":"M. 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