{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,9]],"date-time":"2025-11-09T10:52:53Z","timestamp":1762685573678,"version":"3.41.2"},"reference-count":25,"publisher":"AIP Publishing","issue":"12","funder":[{"DOI":"10.13039\/501100014809","name":"Chevreul Institute","doi-asserted-by":"crossref","award":["FR 2638"],"award-info":[{"award-number":["FR 2638"]}],"id":[{"id":"10.13039\/501100014809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/100016881","name":"JECS Trust","doi-asserted-by":"crossref","award":["201478"],"award-info":[{"award-number":["201478"]}],"id":[{"id":"10.13039\/100016881","id-type":"DOI","asserted-by":"crossref"}]},{"name":"UA | Centro de Investiga\u00e7\u00e3o em Materiais Cer\u00e2micos e Comp\u00f3sitos","award":["POCI-01-0145-FEDER-007679"],"award-info":[{"award-number":["POCI-01-0145-FEDER-007679"]}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2016,9,28]]},"abstract":"<jats:p>In this paper, we derive a new model to determine the distribution of silicate units in binary glasses (or liquids). The model is based on statistical mechanics and assumes grand canonical ensemble of silicate units which exchange energy and network modifiers from the reservoir. This model complements experimental techniques, which measure short range order in glasses such as nuclear magnetic resonance (NMR) spectroscopy. The model has potential in calculating the amounts of liquid-liquid phase segregation and crystal nucleation, and it can be easily extended to more complicated compositions. The structural relaxation of the glass as probed by NMR spectroscopy is also reported, where the model could find its usefulness.<\/jats:p>","DOI":"10.1063\/1.4963341","type":"journal-article","created":{"date-parts":[[2016,9,29]],"date-time":"2016-09-29T17:01:23Z","timestamp":1475168483000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":7,"title":["Statistics of silicate units in binary glasses"],"prefix":"10.1063","volume":"145","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4266-6092","authenticated-orcid":false,"given":"Anuraag","family":"Gaddam","sequence":"first","affiliation":[{"name":"University of Aveiro 1 Department of Materials and Ceramics Engineering, CICECO, , 3810-193 Aveiro, Portugal"}]},{"given":"Lionel","family":"Montagne","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Artois 2 Universit\u00e9 Lille, CNRS, Centrale Lille, ENSCL, , UMR 8181, UCCS\u2013Unit\u00e9 de Catalyse et Chimie du Solide, F-59000 Lille, France"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7520-2809","authenticated-orcid":false,"given":"Jos\u00e9 M. F.","family":"Ferreira","sequence":"additional","affiliation":[{"name":"University of Aveiro 1 Department of Materials and Ceramics Engineering, CICECO, , 3810-193 Aveiro, Portugal"}]}],"member":"317","published-online":{"date-parts":[[2016,9,29]]},"reference":[{"key":"2023063022005283700_c1","doi-asserted-by":"publisher","first-page":"3841","DOI":"10.1021\/ja01349a006","volume":"54","year":"1932","journal-title":"J. Am. Chem. Soc."},{"key":"2023063022005283700_c2","doi-asserted-by":"publisher","first-page":"17","DOI":"10.1016\/j.jnoncrysol.2013.02.024","volume":"368","year":"2013","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c3","doi-asserted-by":"publisher","first-page":"170","DOI":"10.1016\/j.jnoncrysol.2010.09.031","volume":"357","year":"2011","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c4","first-page":"78","volume":"28","year":"1987","journal-title":"Phys. Chem. Glasses"},{"key":"2023063022005283700_c5","doi-asserted-by":"publisher","first-page":"2659","DOI":"10.1016\/0016-7037(88)90034-8","volume":"52","year":"1988","journal-title":"Geochim. Cosmochim. Acta"},{"key":"2023063022005283700_c6","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/0022-3093(94)90029-9","volume":"171","year":"1994","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c7","doi-asserted-by":"publisher","first-page":"249","DOI":"10.1016\/0022-3093(94)90538-X","volume":"177","year":"1994","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c8","doi-asserted-by":"publisher","first-page":"239","DOI":"10.1016\/0022-3093(95)00593-5","volume":"196","year":"1996","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c9","doi-asserted-by":"publisher","first-page":"164","DOI":"10.1016\/S0022-3093(03)00332-6","volume":"325","year":"2003","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c10","doi-asserted-by":"publisher","first-page":"12A522","DOI":"10.1063\/1.4773356","volume":"138","year":"2013","journal-title":"J. Chem. Phys."},{"key":"2023063022005283700_c11","doi-asserted-by":"publisher","first-page":"53","DOI":"10.1016\/S0022-3093(01)00827-4","volume":"293\u2013295","year":"2001","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c12","doi-asserted-by":"publisher","first-page":"2173","DOI":"10.1016\/j.jnoncrysol.2006.01.036","volume":"352","year":"2006","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c13","doi-asserted-by":"publisher","first-page":"177","DOI":"10.1039\/c2pc90006h","volume":"108","year":"2012","journal-title":"Annu. Rep., Sect. C: Phys. Chem."},{"key":"2023063022005283700_c14","doi-asserted-by":"publisher","first-page":"3173","DOI":"10.1103\/PhysRevB.11.3173","volume":"11","year":"1975","journal-title":"Phys. Rev. B"},{"volume-title":"Problems in Thermodynamics and Statistical Physics","year":"1989","author":"Landsberg","key":"2023063022005283700_c15"},{"key":"2023063022005283700_c16","doi-asserted-by":"publisher","first-page":"37","DOI":"10.1016\/j.jnoncrysol.2014.02.015","volume":"390","year":"2014","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c17","doi-asserted-by":"publisher","first-page":"259","DOI":"10.1038\/35065704","volume":"410","year":"2001","journal-title":"Nature"},{"key":"2023063022005283700_c18","doi-asserted-by":"publisher","first-page":"P05015","DOI":"10.1088\/1742-5468\/2005\/05\/P05015","volume":"2005","journal-title":"J. Stat. Mech.: Theory Exp."},{"key":"2023063022005283700_c19","doi-asserted-by":"publisher","first-page":"41","DOI":"10.1016\/j.jnoncrysol.2014.04.009","volume":"396\u2013397","year":"2014","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c20","doi-asserted-by":"publisher","first-page":"154","DOI":"10.1016\/j.jnoncrysol.2014.06.014","volume":"407","year":"2015","journal-title":"J. Non. Cryst. Solids"},{"key":"2023063022005283700_c21","doi-asserted-by":"publisher","first-page":"184511","DOI":"10.1063\/1.2731774","volume":"126","year":"2007","journal-title":"J. Chem. Phys."},{"volume-title":"Fundamentals of Applied Probability Theory","year":"1988","key":"2023063022005283700_c22"},{"key":"2023063022005283700_c23","doi-asserted-by":"publisher","first-page":"669","DOI":"10.1080\/00018738200101438","volume":"31","year":"1982","journal-title":"Adv. Phys."},{"volume-title":"Introduction to the Thermodynamics of Materials","year":"2003","edition":"4th ed.","key":"2023063022005283700_c24"},{"key":"2023063022005283700_c25","doi-asserted-by":"publisher","first-page":"70","DOI":"10.1002\/mrc.984","volume":"40","year":"2002","journal-title":"Magn. Reson. Chem."}],"container-title":["The Journal of Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/1.4963341\/15520434\/124505_1_online.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.aip.org\/aip\/jcp\/article-pdf\/doi\/10.1063\/1.4963341\/15520434\/124505_1_online.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,6,30]],"date-time":"2023-06-30T22:01:06Z","timestamp":1688162466000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.aip.org\/jcp\/article\/145\/12\/124505\/290880\/Statistics-of-silicate-units-in-binary-glasses"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,9,28]]},"references-count":25,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2016,9,28]]}},"URL":"https:\/\/doi.org\/10.1063\/1.4963341","relation":{},"ISSN":["0021-9606","1089-7690"],"issn-type":[{"type":"print","value":"0021-9606"},{"type":"electronic","value":"1089-7690"}],"subject":[],"published-other":{"date-parts":[[2016,9,28]]},"published":{"date-parts":[[2016,9,28]]},"article-number":"124505"}}