{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,25]],"date-time":"2026-01-25T13:54:55Z","timestamp":1769349295527,"version":"3.49.0"},"reference-count":33,"publisher":"AIP Publishing","issue":"4","funder":[{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001501","name":"University Grants Commission","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001501","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2017,1,28]]},"abstract":"<jats:p>We have synthesized SmCr0.85Mn0.15O3 (SCMO) chromites through the ceramic route. The compound crystallized into a distorted orthorhombic structure with the Pnma space group, which was confirmed from the Rietveld refinement of x-ray powder diffraction patterns. Neel temperature, noticed at 168\u2009K from the temperature variation of magnetisation, smaller than that reported for SmCrO3, indicated the influence of Mn3+ substitution on decreasing the antiferromagnetic ordering. A phenomenon of magnetization reversal was observed in the SCMO compound. At low magnetic fields, i.e., 500\u2009Oe, a single compensation temperature (defined as the temperature where magnetization became zero) around 106\u2009K was observed in the field cooled magnetization curve. However, with the application of higher magnetic fields, i.e., under an applied field of 1000\u2009Oe, a second compensation temperature was noticed around 8\u2009K. With a further increase in the magnetic field, the magnetization remained positive in both field cooled and zero field cooled protocols. A normal magnetocaloric effect was observed through an indirect method of field dependence of magnetisation measured in the temperature range of 2\u2013152\u2009K. The magnetic entropy change (\u2212\u0394S) of \u223c11.36\u2009J kg\u22121 K\u22121 along with the relative cooling power (RCP) of \u223c175.89\u2009J kg\u22121 was obtained in the temperature range of 10\u201320\u2009K for an applied field of 90\u2009kOe, and their values at 50\u2009kOe applied field were, respectively, almost twenty and forty times larger in magnitude in comparison to those for the SmCrO3 compound. The relatively large values of \u0394S and RCP make the studied compound a potential candidate for magnetic refrigeration applications at low temperatures.<\/jats:p>","DOI":"10.1063\/1.4974737","type":"journal-article","created":{"date-parts":[[2017,1,24]],"date-time":"2017-01-24T15:26:20Z","timestamp":1485271580000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":41,"title":["Magnetization reversal behavior and magnetocaloric effect in SmCr0.85Mn0.15O3 chromites"],"prefix":"10.1063","volume":"121","author":[{"given":"Surendra","family":"Kumar","sequence":"first","affiliation":[{"name":"Central University of Rajasthan 1 Department of Physics, , Bandarsindri, Ajmer 305817, Rajasthan, India"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0911-5683","authenticated-orcid":false,"given":"Indrani","family":"Coondoo","sequence":"additional","affiliation":[{"name":"University of Aveiro 2 Department of Physics & CICECO-Aveiro Institute of Materials, , 39810-193 Aveiro, Portugal"}]},{"given":"M.","family":"Vasundhara","sequence":"additional","affiliation":[{"name":"CSIR-National Institute for Interdisciplinary Science and Technology 3 Materials Science and Technology Division, , Industrial Estate, Trivandrum 695 019, India"}]},{"given":"Ajit K.","family":"Patra","sequence":"additional","affiliation":[{"name":"Central University of Rajasthan 1 Department of Physics, , Bandarsindri, Ajmer 305817, Rajasthan, India"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3432-7610","authenticated-orcid":false,"given":"Andrei L.","family":"Kholkin","sequence":"additional","affiliation":[{"name":"University of Aveiro 2 Department of Physics & CICECO-Aveiro Institute of Materials, , 39810-193 Aveiro, Portugal"},{"name":"Ural Federal University 4 School of Natural Sciences and Mathematics, , 620000 Ekaterinburg, Russia"}]},{"given":"Neeraj","family":"Panwar","sequence":"additional","affiliation":[{"name":"Central University of Rajasthan 1 Department of Physics, , Bandarsindri, Ajmer 305817, Rajasthan, India"}]}],"member":"317","published-online":{"date-parts":[[2017,1,24]]},"reference":[{"key":"2023062512473187700_c1","doi-asserted-by":"publisher","first-page":"3133","DOI":"10.1088\/0022-3719\/7\/17\/021","volume":"7","year":"1974","journal-title":"J. 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