{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,18]],"date-time":"2025-10-18T15:05:56Z","timestamp":1760799956116,"version":"3.41.2"},"reference-count":65,"publisher":"AIP Publishing","issue":"4","funder":[{"DOI":"10.13039\/501100002428","name":"Austrian Science Fund","doi-asserted-by":"publisher","award":["M 1650-N27","M 2150-N36","P 26253-N27"],"award-info":[{"award-number":["M 1650-N27","M 2150-N36","P 26253-N27"]}],"id":[{"id":"10.13039\/501100002428","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010665","name":"H2020 Marie Sk\u0142odowska-Curie Actions","doi-asserted-by":"publisher","award":["702298- DELTAS","H2020-MCSA-ITN-2014, Grant No. 642774"],"award-info":[{"award-number":["702298- DELTAS","H2020-MCSA-ITN-2014, Grant No. 642774"]}],"id":[{"id":"10.13039\/100010665","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["pubs.aip.org"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2017,1,28]]},"abstract":"<jats:p>A re-entrant gas-liquid spinodal was proposed as a possible explanation of the apparent divergence of the compressibility and specific heat off supercooling water. Such a counter-intuitive possibility, e.g., a liquid that becomes unstable to gas-like fluctuations on cooling at positive pressure, has never been observed, neither in real substances nor in off-lattice simulations. More recently, such a re-entrant scenario has been dismissed on the premise that the re-entrant spinodal would collide with the gas-liquid coexisting curve (binodal) in the pressure-temperature plane. Here we study, numerically and analytically, two previously introduced one-component patchy particle models that both show (i) a re-entrant limit of stability of the liquid phase and (ii) a re-entrant binodal, providing a neat in silico (and in charta) realization of such unconventional thermodynamic scenario.<\/jats:p>","DOI":"10.1063\/1.4974830","type":"journal-article","created":{"date-parts":[[2017,1,27]],"date-time":"2017-01-27T16:29:54Z","timestamp":1485534594000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":25,"title":["Communication: Re-entrant limits of stability of the liquid phase and the Speedy scenario in colloidal model systems"],"prefix":"10.1063","volume":"146","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5017-2829","authenticated-orcid":false,"given":"Lorenzo","family":"Rovigatti","sequence":"first","affiliation":[{"name":"Rudolf Peierls Centre for Theoretical Physics 1 , 1 Keble Road, Oxford OX1 3NP, United Kingdom"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3844-6406","authenticated-orcid":false,"given":"Valentino","family":"Bianco","sequence":"additional","affiliation":[{"name":"University of Vienna 2 Faculty of Physics, , Boltzmanngasse 5, A-1090 Vienna, Austria"}]},{"given":"Jos\u00e9 Maria","family":"Tavares","sequence":"additional","affiliation":[{"name":"Instituto Superior de Engenharia de Lisboa-ISEL 3 , Rua Conselheiro Em\u00eddio Navarro 1, P-1950-062 Lisbon, Portugal and Centro de F\u00edsica Te\u00f3rica e Computacional, , Campo Grande, P-1749-016 Lisbon, Portugal"},{"name":"Universidade de Lisboa 3 , Rua Conselheiro Em\u00eddio Navarro 1, P-1950-062 Lisbon, Portugal and Centro de F\u00edsica Te\u00f3rica e Computacional, , Campo Grande, P-1749-016 Lisbon, Portugal"}]},{"given":"Francesco","family":"Sciortino","sequence":"additional","affiliation":[{"name":"Sapienza-Universit\u00e1 di Roma 4 Dipartimento di Fisica, , Piazzale A. Moro 5, 00185 Roma, Italy and , Via dei Taurini 19, 00185 Roma, Italy"},{"name":"Istituto Sistemi Complessi (CNR-ISC) 4 Dipartimento di Fisica, , Piazzale A. Moro 5, 00185 Roma, Italy and , Via dei Taurini 19, 00185 Roma, Italy"}]}],"member":"317","published-online":{"date-parts":[[2017,1,27]]},"reference":[{"key":"2023062606015554200_c1","doi-asserted-by":"publisher","first-page":"4008","DOI":"10.1063\/1.438021","volume":"70","year":"1979","journal-title":"J. Chem. Phys."},{"key":"2023062606015554200_c2","doi-asserted-by":"publisher","first-page":"998","DOI":"10.1021\/j100395a032","volume":"86","year":"1982","journal-title":"J. Phys. Chem."},{"volume-title":"Metastable Liquids: Concepts and Principles","year":"1996","key":"2023062606015554200_c3"},{"key":"2023062606015554200_c4","doi-asserted-by":"publisher","first-page":"1632","DOI":"10.1103\/PhysRevLett.73.1632","volume":"73","year":"1994","journal-title":"Phys. Rev. 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