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The ab\u00a0initio energies are fitted using the double many-body expansion method, thus incorporating long-range energy terms that can accurately describe the electrostatic and dispersion interactions with physically motivated decaying functions. Together with the previously fitted lowest A\u20322 and A\u2032\u20322 states using the same theoretical framework, this constitutes a new set of PESs that are suitable to predict rate coefficients for all atom\u2013diatom reactions of the CNO system. We use this set of PESs to calculate thermal rate coefficients for the C(P3) + NO(\u03a02) reaction and compare the temperature dependence and product branching ratios with experimental results. The comparison between theory and experiment is shown to be improved over previous theoretical studies. We highlight the importance of the long-range interactions for low-temperature rate coefficients.<\/jats:p>","DOI":"10.1063\/5.0180918","type":"journal-article","created":{"date-parts":[[2023,12,6]],"date-time":"2023-12-06T10:49:17Z","timestamp":1701859757000},"update-policy":"https:\/\/doi.org\/10.1063\/aip-crossmark-policy-page","source":"Crossref","is-referenced-by-count":3,"title":["High-accuracy DMBE potential energy surface for CNO(A\u2032\u20324) and the rate coefficients for the C + NO reaction in the A\u20322, A\u2032\u20322, and A\u2032\u20324 states"],"prefix":"10.1063","volume":"159","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4995-0800","authenticated-orcid":false,"given":"M\u00e1rcio O.","family":"Alves","sequence":"first","affiliation":[{"name":"Centro Federal de Educa\u00e7\u00e3o Tecnol\u00f3gica de Minas Gerais, CEFET-MG 1 , Av. 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