{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,17]],"date-time":"2026-02-17T05:28:35Z","timestamp":1771306115133,"version":"3.50.1"},"reference-count":103,"publisher":"Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii","issue":"1","license":[{"start":{"date-parts":[[2019,1,1]],"date-time":"2019-01-01T00:00:00Z","timestamp":1546300800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/page\/copyright"},{"start":{"date-parts":[[2019,1,1]],"date-time":"2019-01-01T00:00:00Z","timestamp":1546300800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/info\/page\/text-and-data-mining"}],"content-domain":{"domain":["iopscience.iop.org"],"crossmark-restriction":false},"short-container-title":["Russ. Chem. Rev."],"published-print":{"date-parts":[[2019,1,1]]},"abstract":"<jats:p>\n                  <jats:inline-formula>\n                     <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"rc4840c.gif\" xlink:type=\"simple\"\/>\n                  <\/jats:inline-formula>\n               <\/jats:p>\n               <jats:p>The review integrates and systematically describes data on the methods of synthesis, reactivity and biological activity of 3-nitro-2<jats:italic>H<\/jats:italic>-chromenes published over the last five years and data on 3-nitro-4<jats:italic>H<\/jats:italic>-chromenes and related 3-nitro-4<jats:italic>H<\/jats:italic>-pyrans published over the whole investigation period. Nucleophilic addition, including asymmetric synthesis, cycloaddition and redox reactions involving the C=C double bond and the nitro group of 3-nitro-2<jats:italic>H<\/jats:italic>-chromenes, are considered. The transformations of new and poorly investigated 3-nitro-4<jats:italic>H<\/jats:italic>-chromenes include reactions of 4-sulfanyl-substituted 3-nitro-4<jats:italic>H<\/jats:italic>-chromenes with nucleophiles, reactions of the nitroenamine moiety and removal of the alkylsulfanyl group using reductive processes. Reaction mechanisms and stereochemistry of the reaction products are discussed.<\/jats:p>\n               <jats:p>The bibliography includes 103 references.<\/jats:p>","DOI":"10.1070\/rcr4840","type":"journal-article","created":{"date-parts":[[2018,8,31]],"date-time":"2018-08-31T11:45:19Z","timestamp":1535715919000},"page":"27-58","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":42,"title":["Recent advances in the chemistry of 3-nitro-2H- and 3-nitro-4H-chromenes"],"prefix":"10.59761","volume":"88","author":[{"given":"Vladislav Yu.","family":"Korotaev","sequence":"first","affiliation":[]},{"given":"Igor B.","family":"Kutyashev","sequence":"additional","affiliation":[]},{"given":"Alexey Yu.","family":"Barkov","sequence":"additional","affiliation":[]},{"given":"Vyacheslav Ya.","family":"Sosnovskikh","sequence":"additional","affiliation":[]}],"member":"38825","reference":[{"key":"rcr_88_1_27_bib1","first-page":"11","volume":"31","author":"Schweizer","year":"1977"},{"key":"rcr_88_1_27_bib2","doi-asserted-by":"crossref","first-page":"893","DOI":"10.1021\/cr020033s","volume":"103","author":"Horton","year":"2003","journal-title":"Chem. 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