{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,15]],"date-time":"2025-12-15T13:56:40Z","timestamp":1765807000925,"version":"3.48.0"},"reference-count":43,"publisher":"CSIRO Publishing","issue":"9","license":[{"start":{"date-parts":[[2025,8,21]],"date-time":"2025-08-21T00:00:00Z","timestamp":1755734400000},"content-version":"vor","delay-in-days":5139,"URL":"https:\/\/doi.org\/10.1071\/journalslicense"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2011,9,16]]},"abstract":"<jats:p>Robust water oxidation catalysts using earth abundant metals are required as part of an overall scheme to convert sunlight into fuels. Here, we report the immobilization of [Mn4IVO5(terpy)4(H2O)2](ClO4)6 (terpy = 2,2';6',2''-terpyridine), [Mn4O6(tacn)4](ClO4)4 (tacn = 1,4,7-triazacyclononane), and manganese dioxide nanoparticles in Nafion on fluorine-doped tin oxide conducting glass electrodes. The electrodes are illuminated with white light in the presence of an applied potential and the resulting photocurrent is assigned to the oxidation of solvent water. Photodecomposition of the tetrameric complexes results in a material that is more active for light-driven electrooxidation of water. The reactivity, wavelength dependence, and stability of the compounds in Nafion under illumination are discussed.<\/jats:p>","DOI":"10.1071\/ch11178","type":"journal-article","created":{"date-parts":[[2011,9,16]],"date-time":"2011-09-16T08:05:37Z","timestamp":1316160337000},"page":"1221-1228","source":"Crossref","is-referenced-by-count":19,"title":["Photocatalytic Water Oxidation Using Manganese Compounds Immobilized in Nafion Polymer Membranes"],"prefix":"10.1071","volume":"64","author":[{"given":"Karin J.","family":"Young","sequence":"first","affiliation":[{"name":"ADepartment of Chemistry, Yale University, New Haven, CT 06520, USA."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yunlong","family":"Gao","sequence":"additional","affiliation":[{"name":"ADepartment of Chemistry, Yale University, New Haven, CT 06520, USA."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gary W.","family":"Brudvig","sequence":"additional","affiliation":[{"name":"ADepartment of Chemistry, Yale University, New Haven, CT 06520, USA."},{"name":"BCorresponding author. Email: gary.brudvig@yale.edu"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"67","published-online":{"date-parts":[[2011,7,27]]},"reference":[{"key":"2025121503211883400_R1","doi-asserted-by":"publisher","first-page":"15729","DOI":"10.1073\/PNAS.0603395103","volume":"103","author":"Lewis","year":"2006","journal-title":"Proc. Natl. Acad. Sci. USA"},{"key":"2025121503211883400_R2","doi-asserted-by":"publisher","first-page":"1524","DOI":"10.1126\/SCIENCE.283.5407.1524","volume":"283","author":"Limburg","year":"1999","journal-title":"Science"},{"key":"2025121503211883400_R3","doi-asserted-by":"publisher","first-page":"98","DOI":"10.1002\/ANIE.200352564","volume":"43","author":"Shimazaki","year":"2004","journal-title":"Angew. Chem. Int. Ed."},{"key":"2025121503211883400_R4","doi-asserted-by":"publisher","first-page":"7335","DOI":"10.1002\/ANIE.200801132","volume":"47","author":"Brimblecombe","year":"2008","journal-title":"Angew. Chem. Int. Ed."},{"key":"2025121503211883400_R5","doi-asserted-by":"publisher","first-page":"4249","DOI":"10.1039\/C0CC05522K","volume":"47","author":"Wasylenko","year":"2011","journal-title":"Chem. Commun."},{"key":"2025121503211883400_R6","doi-asserted-by":"publisher","first-page":"4029","DOI":"10.1021\/JA00378A053","volume":"104","author":"Gersten","year":"1982","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R7","doi-asserted-by":"publisher","first-page":"16462","DOI":"10.1021\/JA8059649","volume":"130","author":"Concepcion","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R8","doi-asserted-by":"publisher","first-page":"1824","DOI":"10.1021\/IC700911Y","volume":"47","author":"Romero","year":"2008","journal-title":"Inorg. Chem."},{"key":"2025121503211883400_R9","doi-asserted-by":"publisher","first-page":"11763","DOI":"10.1021\/IC8014817","volume":"47","author":"Tseng","year":"2008","journal-title":"Inorg. Chem."},{"key":"2025121503211883400_R10","doi-asserted-by":"publisher","first-page":"210","DOI":"10.1021\/JA074478F","volume":"130","author":"McDaniel","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R11","doi-asserted-by":"publisher","first-page":"8730","DOI":"10.1021\/JA901270F","volume":"131","author":"Hull","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R12","doi-asserted-by":"publisher","first-page":"7436","DOI":"10.1021\/JA101564F","volume":"132","author":"Sivula","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R13","doi-asserted-by":"publisher","first-page":"1072","DOI":"10.1126\/SCIENCE.1162018","volume":"321","author":"Kanan","year":"2008","journal-title":"Science"},{"key":"2025121503211883400_R14","doi-asserted-by":"publisher","first-page":"342","DOI":"10.1126\/SCIENCE.1185372","volume":"328","author":"Yin","year":"2010","journal-title":"Science"},{"key":"2025121503211883400_R15","doi-asserted-by":"publisher","first-page":"11467","DOI":"10.1021\/JA1055615","volume":"132","author":"Robinson","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R16","doi-asserted-by":"publisher","first-page":"13612","DOI":"10.1021\/JA104587V","volume":"132","author":"Gorlin","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R17","doi-asserted-by":"publisher","first-page":"2795","DOI":"10.1039\/F19888402795","volume":"84","author":"Harriman","year":"1988","journal-title":"J. Chem. Soc., Farad. Trans. 1"},{"key":"2025121503211883400_R18","doi-asserted-by":"publisher","first-page":"15578","DOI":"10.1021\/JA9063298","volume":"131","author":"Nakagawa","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R19","doi-asserted-by":"publisher","first-page":"16017","DOI":"10.1021\/JA104775J","volume":"132","author":"Blakemore","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R20","doi-asserted-by":"publisher","first-page":"94","DOI":"10.1039\/C0SC00418A","volume":"2","author":"Blakemore","year":"2011","journal-title":"Chem. Sci."},{"key":"2025121503211883400_R21","doi-asserted-by":"publisher","first-page":"4455","DOI":"10.1021\/CR0204294","volume":"106","author":"McEvoy","year":"2006","journal-title":"Chem. Rev."},{"key":"2025121503211883400_R22","doi-asserted-by":"publisher","first-page":"2983","DOI":"10.1016\/J.ICA.2007.02.020","volume":"360","author":"Tagore","year":"2007","journal-title":"Inorg. Chim. Acta"},{"key":"2025121503211883400_R23","doi-asserted-by":"publisher","first-page":"8084","DOI":"10.1021\/JA039780C","volume":"126","author":"Yagi","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R24","doi-asserted-by":"publisher","first-page":"10353","DOI":"10.1021\/JA0005587","volume":"122","author":"Ruettinger","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R25","doi-asserted-by":"publisher","first-page":"7269","DOI":"10.1021\/IC9006982","volume":"48","author":"Brimblecombe","year":"2009","journal-title":"Inorg. Chem."},{"key":"2025121503211883400_R26","doi-asserted-by":"crossref","first-page":"461","DOI":"10.1038\/nchem.1049","volume":"3","author":"Hocking","year":"2011","journal-title":"Nat. Chem."},{"key":"2025121503211883400_R27","doi-asserted-by":"publisher","first-page":"29","DOI":"10.1016\/S1381-1169(99)00241-1","volume":"151","author":"Yagi","year":"2000","journal-title":"J. Mol. Catal. Chem."},{"key":"2025121503211883400_R28","first-page":"190","author":"Hara","year":"2000","journal-title":"Chem. Comm."},{"key":"2025121503211883400_R29","doi-asserted-by":"publisher","first-page":"4535","DOI":"10.1021\/CR0207123","volume":"104","author":"Mauritz","year":"2004","journal-title":"Chem. Rev."},{"key":"2025121503211883400_R30","doi-asserted-by":"publisher","first-page":"7345","DOI":"10.1021\/JA037389L","volume":"126","author":"Chen","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R31","doi-asserted-by":"publisher","first-page":"328","DOI":"10.1002\/ANIE.198303281","volume":"22","author":"Wieghardt","year":"1983","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"2025121503211883400_R32","doi-asserted-by":"publisher","first-page":"113","DOI":"10.1016\/S1381-1169(03)00406-0","volume":"203","author":"Wieprecht","year":"2003","journal-title":"J. Mol. Catal. Chem."},{"key":"2025121503211883400_R33","doi-asserted-by":"publisher","first-page":"3396","DOI":"10.1021\/IC00215A020","volume":"24","author":"Mohr","year":"1985","journal-title":"Inorg. Chem."},{"key":"2025121503211883400_R34","doi-asserted-by":"publisher","first-page":"9457","DOI":"10.1021\/JA061348I","volume":"128","author":"Tagore","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R35","doi-asserted-by":"publisher","first-page":"2193","DOI":"10.1021\/IC061968K","volume":"46","author":"Tagore","year":"2007","journal-title":"Inorg. Chem."},{"key":"2025121503211883400_R36","doi-asserted-by":"publisher","first-page":"39","DOI":"10.1016\/J.MEMSCI.2003.12.008","volume":"233","author":"Liang","year":"2004","journal-title":"J. Membr. Sci."},{"key":"2025121503211883400_R37","doi-asserted-by":"publisher","first-page":"325","DOI":"10.1016\/0013-4686(77)85081-0","volume":"22","author":"Morita","year":"1977","journal-title":"Electrochim. Acta"},{"key":"2025121503211883400_R38","doi-asserted-by":"publisher","first-page":"8306","DOI":"10.1021\/IC8008915","volume":"47","author":"Hill","year":"2008","journal-title":"Inorg. Chem."},{"key":"2025121503211883400_R39","doi-asserted-by":"publisher","first-page":"799","DOI":"10.1016\/0371-1951(64)80079-5","volume":"20","author":"McDevitt","year":"1964","journal-title":"Spectrochimica Acta"},{"key":"2025121503211883400_R40","doi-asserted-by":"publisher","first-page":"260","DOI":"10.1002\/ZAAC.19713840311","volume":"384","author":"Kolta","year":"1971","journal-title":"Z. Anorg. Allg. Chem."},{"key":"2025121503211883400_R41","doi-asserted-by":"publisher","first-page":"3428","DOI":"10.1021\/JA076130Q","volume":"130","author":"Sproviero","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R42","doi-asserted-by":"publisher","first-page":"2392","DOI":"10.1021\/JA00085A019","volume":"116","author":"Gamelin","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"2025121503211883400_R43","doi-asserted-by":"publisher","first-page":"A80","DOI":"10.1149\/1.2404775","volume":"154","author":"Devaraj","year":"2007","journal-title":"J. Electrochem. Soc."}],"container-title":["Australian Journal of Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/connectsci.au\/ch\/article-pdf\/64\/9\/1221\/959725\/ch11178.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/connectsci.au\/ch\/article-pdf\/64\/9\/1221\/959725\/ch11178.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,15]],"date-time":"2025-12-15T08:21:24Z","timestamp":1765786884000},"score":1,"resource":{"primary":{"URL":"https:\/\/connectsci.au\/ch\/article\/64\/9\/1221\/120009\/Photocatalytic-Water-Oxidation-Using-Manganese"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2011,7,27]]},"references-count":43,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2011,9,16]]}},"URL":"https:\/\/doi.org\/10.1071\/ch11178","relation":{},"ISSN":["0004-9425","1445-0038"],"issn-type":[{"type":"print","value":"0004-9425"},{"type":"electronic","value":"1445-0038"}],"subject":[],"published":{"date-parts":[[2011,7,27]]}}}