{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,10]],"date-time":"2026-06-10T15:49:43Z","timestamp":1781106583489,"version":"3.54.1"},"reference-count":51,"publisher":"National Academy of Sciences","issue":"17","content-domain":{"domain":["www.pnas.org"],"crossmark-restriction":true},"short-container-title":["Proc. Natl. Acad. Sci. U.S.A."],"published-print":{"date-parts":[[2007,4,24]]},"abstract":"<jats:p>\n                    The photochemical reaction of Tp\u2032Rh(L)(\u03b7\n                    <jats:sup>2<\/jats:sup>\n                    -PhN=L) [Tp\u2032 = tris-(3,5-dimethyl pyrazolyl)borate, L = CNCH\n                    <jats:sub>2<\/jats:sub>\n                    CMe\n                    <jats:sub>3<\/jats:sub>\n                    ] to form the coordinatively unsaturated reactive fragment, [Tp\u2032Rh(L)], in the presence of alkylnitriles has been studied. The [Tp\u2032Rh(L)] complex has been shown to selectively activate the primary C\n                    <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"cjs0807.gif\"\/>\n                    H terminus of acetonitrile, propionitrile, butyronitrile, and valeronitrile. The resulting hydrides showed uncharacteristic stability in the presence of C\n                    <jats:sub>6<\/jats:sub>\n                    D\n                    <jats:sub>6<\/jats:sub>\n                    and their rates of reductive elimination were monitored by\n                    <jats:sup>1<\/jats:sup>\n                    H NMR spectroscopy. Competition reactions permit the establishment of the relative stabilities of the activation products.\n                  <\/jats:p>","DOI":"10.1073\/pnas.0609726104","type":"journal-article","created":{"date-parts":[[2007,3,23]],"date-time":"2007-03-23T20:38:21Z","timestamp":1174682301000},"page":"6957-6962","update-policy":"https:\/\/doi.org\/10.1073\/pnas.cm10313","source":"Crossref","is-referenced-by-count":39,"title":["The activation of alkyl cyanides using a rhodiumtrispyrazolylborate complex"],"prefix":"10.1073","volume":"104","author":[{"given":"Andrew J.","family":"Vetter","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, NY 14627"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ryan D.","family":"Rieth","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, NY 14627"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"William 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