{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T18:24:06Z","timestamp":1791311046927,"version":"4.3.1"},"reference-count":25,"publisher":"National Academy of Sciences","issue":"33","content-domain":{"domain":["www.pnas.org"],"crossmark-restriction":true},"short-container-title":["Proc. Natl. Acad. Sci. U.S.A."],"published-print":{"date-parts":[[2008,8,19]]},"abstract":"<jats:p>Benchmarks have been established for the performance of six metal-organic frameworks (MOFs) and isoreticular MOFs (IRMOFs, which have the same underlying topology as MOF-5), MOF-5, IRMOF-3, MOF-74, MOF-177, MOF-199, and IRMOF-62, as selective adsorbents for eight harmful gases: sulfur dioxide, ammonia, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethylene oxide, and carbon monoxide. Kinetic breakthrough measurements are used to determine the calculated dynamic adsorption capacity of each \u201cbenchmark\u201d MOF for each gas. The capacity of each MOF is compared to that of a sample of Calgon BPL activated carbon. We find that pore functionality plays a dominant role in determining the dynamic adsorption performance of MOFs. MOFs featuring reactive functionality outperform BPL carbon in all but one case and exhibit high dynamic adsorption capacities up to 35% by weight.<\/jats:p>","DOI":"10.1073\/pnas.0804900105","type":"journal-article","created":{"date-parts":[[2008,8,18]],"date-time":"2008-08-18T21:09:09Z","timestamp":1219093749000},"page":"11623-11627","update-policy":"https:\/\/doi.org\/10.1073\/pnas.cm10313","source":"Crossref","is-referenced-by-count":928,"title":["Metal-organic frameworks with high capacity and selectivity for harmful gases"],"prefix":"10.1073","volume":"105","author":[{"given":"David","family":"Britt","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry, Center for Reticular Materials Research at California NanoSystems Institute, University of California, Los Angeles, CA 90095"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David","family":"Tranchemontagne","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Center for Reticular Materials Research at California NanoSystems Institute, University of California, Los Angeles, CA 90095"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Omar M.","family":"Yaghi","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Center for Reticular Materials Research at California NanoSystems Institute, University of California, Los Angeles, CA 90095"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"341","published-online":{"date-parts":[[2008,8,19]]},"reference":[{"key":"e_1_3_3_1_2","first-page":"96","volume-title":"Chemical Exposure Guidelines for Deployed Military Personnel","author":"McAtee M","year":"2003","unstructured":"M McAtee, et al. Chemical Exposure Guidelines for Deployed Military Personnel, eds V Hauschild, J Johnson (US Army Center for Health Promotion and Preventive Medicine, Aberdeen Proving Ground, MD), pp. 96\u2013113, Reference document 230. (2003)."},{"key":"e_1_3_3_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie070521w"},{"key":"e_1_3_3_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp072066n"},{"key":"e_1_3_3_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/0008-6223(92)90177-X"},{"key":"e_1_3_3_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/46248"},{"key":"e_1_3_3_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2004.03.034"},{"key":"e_1_3_3_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature01650"},{"key":"e_1_3_3_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar000034b"},{"key":"e_1_3_3_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature02311"},{"key":"e_1_3_3_10_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1067208"},{"key":"e_1_3_3_11_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1083440"},{"key":"e_1_3_3_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/la0355500"},{"key":"e_1_3_3_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja049408c"},{"key":"e_1_3_3_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462787"},{"key":"e_1_3_3_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0542690"},{"key":"e_1_3_3_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0570032"},{"key":"e_1_3_3_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/b703608f"},{"key":"e_1_3_3_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja076877g"},{"key":"e_1_3_3_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja076595g"},{"key":"e_1_3_3_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/0008-6223(93)90172-7"},{"key":"e_1_3_3_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja800669j"},{"key":"e_1_3_3_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja003159k"},{"key":"e_1_3_3_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja056639q"},{"key":"e_1_3_3_24_2","unstructured":"D Tranchemontagne The Synthesis and Investigation of Alkyne-Containing Isoreticular Metal\u2013Organic Frameworks for Hydrogen Storage and the Preliminary Investigation of Metal\u2013Organic Frameworks for Gas Separation Applications.  (Univ of California Los Angeles PhD thesis. (2007)."},{"key":"e_1_3_3_25_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.283.5405.1148"}],"container-title":["Proceedings of the National Academy of Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pnas.org\/doi\/pdf\/10.1073\/pnas.0804900105","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,4,12]],"date-time":"2022-04-12T17:22:44Z","timestamp":1649784164000},"score":1,"resource":{"primary":{"URL":"https:\/\/pnas.org\/doi\/full\/10.1073\/pnas.0804900105"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,8,19]]},"references-count":25,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2008,8,19]]}},"alternative-id":["10.1073\/pnas.0804900105"],"URL":"https:\/\/doi.org\/10.1073\/pnas.0804900105","relation":{},"ISSN":["0027-8424","1091-6490"],"issn-type":[{"value":"0027-8424","type":"print"},{"value":"1091-6490","type":"electronic"}],"subject":[],"published":{"date-parts":[[2008,8,19]]},"assertion":[{"value":"2008-05-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2008-08-19","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}