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Here, we present direct measurements of the vertical fluxes of a reactant\u2212product pair using eddy covariance coupled with chemical ionization time-of-flight mass spectrometry to directly assess the role of the ocean surface in the exchange of reactive nitrogen and halogens. Our observations suggest that the ocean surface plays a critical role in controlling the lifetime of N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    , a primary nocturnal reservoir for tropospheric reactive nitrogen.\n                  <\/jats:p>","DOI":"10.1073\/pnas.1318694111","type":"journal-article","created":{"date-parts":[[2014,3,3]],"date-time":"2014-03-03T21:26:27Z","timestamp":1393881987000},"page":"3943-3948","update-policy":"https:\/\/doi.org\/10.1073\/pnas.cm10313","source":"Crossref","is-referenced-by-count":50,"title":["A controlling role for the air\u2212sea interface in the chemical processing of reactive nitrogen in the coastal marine boundary layer"],"prefix":"10.1073","volume":"111","author":[{"given":"Michelle J.","family":"Kim","sequence":"first","affiliation":[{"name":"Scripps Institution of Oceanography and"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Delphine K.","family":"Farmer","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Colorado State University, Fort Collins, CO 80523"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timothy H.","family":"Bertram","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093; and"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"341","published-online":{"date-parts":[[2014,3,3]]},"reference":[{"key":"e_1_3_3_1_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-9-5043-2009"},{"key":"e_1_3_3_2_2","doi-asserted-by":"publisher","DOI":"10.1029\/96JD03057"},{"key":"e_1_3_3_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/337241a0"},{"key":"e_1_3_3_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/ngeo177"},{"key":"e_1_3_3_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature08905"},{"key":"e_1_3_3_6_2","doi-asserted-by":"publisher","DOI":"10.1029\/2006JD007252"},{"key":"e_1_3_3_7_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-11-4929-2011"},{"key":"e_1_3_3_8_2","volume-title":"Coastal Waters of the World: Trends, Threats, and Strategies","author":"Hinrichsen D","year":"1998","unstructured":"D Hinrichsen Coastal Waters of the World: Trends, Threats, and Strategies (Island Press, Washington, DC, 1998)."},{"key":"e_1_3_3_9_2","doi-asserted-by":"crossref","unstructured":"NL Wagner et al. 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