{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T01:12:09Z","timestamp":1791940329528,"version":"4.3.4"},"reference-count":38,"publisher":"National Academy of Sciences","issue":"42","content-domain":{"domain":["www.pnas.org"],"crossmark-restriction":true},"short-container-title":["Proc. Natl. Acad. Sci. U.S.A."],"published-print":{"date-parts":[[2016,10,18]]},"abstract":"<jats:title>Significance<\/jats:title>\n                  <jats:p>\n                    Climate models indicate the importance of dimethyl sulfide (DMS) oxidation in new aerosol particle formation and the activation of cloud condensation nuclei over oceans. These effects contribute to strong natural negative radiative forcing and substantially influence the Earth\u2019s climate. However, the DMS oxidation pathway is not well-represented, because earlier model studies only parameterized gas-phase DMS oxidation and neglected multiphase chemistry. Here, we performed the most comprehensive current mechanistic studies on multiphase DMS oxidation. The studies imply that neglecting multiphase chemistry leads to significant overestimation of SO\n                    <jats:sub>2<\/jats:sub>\n                    production and subsequent new particle formation. These findings show that an advanced treatment of multiphase DMS chemistry is necessary to improve marine atmospheric chemistry and climate model predictions.\n                  <\/jats:p>","DOI":"10.1073\/pnas.1606320113","type":"journal-article","created":{"date-parts":[[2016,9,29]],"date-time":"2016-09-29T22:58:55Z","timestamp":1475189935000},"page":"11776-11781","update-policy":"https:\/\/doi.org\/10.1073\/pnas.cm10313","source":"Crossref","is-referenced-by-count":229,"title":["An advanced modeling study on the impacts and atmospheric implications of multiphase dimethyl sulfide chemistry"],"prefix":"10.1073","volume":"113","author":[{"given":"Erik Hans","family":"Hoffmann","sequence":"first","affiliation":[{"name":"Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), D-04318 Leipzig, Germany;"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andreas","family":"Tilgner","sequence":"additional","affiliation":[{"name":"Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), D-04318 Leipzig, Germany;"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roland","family":"Schr\u00f6dner","sequence":"additional","affiliation":[{"name":"Modeling of Atmospheric Processes Department (MAPD), Leibniz Institute for Tropospheric Research (TROPOS), D-04318 Leipzig, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Br\u00e4uer","sequence":"additional","affiliation":[{"name":"Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), D-04318 Leipzig, Germany;"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ralf","family":"Wolke","sequence":"additional","affiliation":[{"name":"Modeling of Atmospheric Processes Department (MAPD), Leibniz Institute for Tropospheric Research (TROPOS), D-04318 Leipzig, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hartmut","family":"Herrmann","sequence":"additional","affiliation":[{"name":"Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research (TROPOS), D-04318 Leipzig, Germany;"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"341","published-online":{"date-parts":[[2016,9,29]]},"reference":[{"key":"e_1_3_3_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00089"},{"key":"e_1_3_3_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-4203(90)90059-L"},{"key":"e_1_3_3_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/326655a0"},{"key":"e_1_3_3_4_2","volume-title":"Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change","author":"Myhre G","year":"2013","unstructured":"G Myhre, , Anthropogenic and natural radiative forcing. Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, eds TF Stocker, (Cambridge Univ Press, Cambridge, United Kingdom, 2013)."},{"key":"e_1_3_3_5_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-4-589-2004"},{"key":"e_1_3_3_6_2","volume-title":"World Ocean Review 2010: Living with the Oceans","author":"Bosch T","year":"2010","unstructured":"T Bosch, World Ocean Review 2010: Living with the Oceans (Mare, Hamburg, Germany, 2010)."},{"key":"e_1_3_3_7_2","doi-asserted-by":"publisher","DOI":"10.1139\/f04-045"},{"key":"e_1_3_3_8_2","doi-asserted-by":"publisher","DOI":"10.1029\/96JD01221"},{"key":"e_1_3_3_9_2","first-page":"1056","article-title":"The contribution of ocean-leaving DMS to the global atmospheric burdens of DMS, MSA, SO2, and NSS SO4\n                  2-","volume":"17","author":"Gondwe M","year":"2003","unstructured":"M Gondwe, M Krol, W Gieskes, W Klaassen, H de Baar, The contribution of ocean-leaving DMS to the global atmospheric burdens of DMS, MSA, SO2, and NSS SO42-. Global Biogeochem Cycles 17, 1056 (2003).","journal-title":"Global Biogeochem Cycles"},{"key":"e_1_3_3_10_2","doi-asserted-by":"publisher","DOI":"10.1029\/2000JD000089"},{"key":"e_1_3_3_11_2","doi-asserted-by":"publisher","DOI":"10.5194\/bg-3-29-2006"},{"key":"e_1_3_3_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/2014JD022687"},{"key":"e_1_3_3_13_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-10-7425-2010"},{"key":"e_1_3_3_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020529"},{"key":"e_1_3_3_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.atmosenv.2009.02.043"},{"key":"e_1_3_3_16_2","doi-asserted-by":"publisher","DOI":"10.1029\/2001JD000843"},{"key":"e_1_3_3_17_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-14-12023-2014"},{"key":"e_1_3_3_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CP00838G"},{"key":"e_1_3_3_19_2","volume-title":"Zonal Average Cloud Characteristics for Global Atmospheric Chemistry Modelling","author":"Lelieveld J","year":"1989","unstructured":"J Lelieveld, PJ Crutzen, H Rodhe Zonal Average Cloud Characteristics for Global Atmospheric Chemistry Modelling (Department of Meteorology, University of Stockholm, Stockholm, 1989)."},{"key":"e_1_3_3_20_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1006154618511"},{"key":"e_1_3_3_21_2","doi-asserted-by":"publisher","DOI":"10.1029\/2005JD006326"},{"key":"e_1_3_3_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.atmosenv.2007.04.039"},{"key":"e_1_3_3_23_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-14-12209-2014"},{"key":"e_1_3_3_24_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10874-013-9249-6"},{"key":"e_1_3_3_25_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-3-161-2003"},{"key":"e_1_3_3_26_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-3-181-2003"},{"key":"e_1_3_3_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.atmosenv.2005.02.038"},{"key":"e_1_3_3_28_2","doi-asserted-by":"publisher","DOI":"10.1029\/2010GB003850"},{"key":"e_1_3_3_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/asl2.539"},{"key":"e_1_3_3_30_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10874-013-9267-4"},{"key":"e_1_3_3_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/b009631h"},{"key":"e_1_3_3_32_2","volume-title":"Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change","author":"Boucher O","year":"2013","unstructured":"O Boucher, , Clouds and aerosols. Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, eds TF Stocker, (Cambridge Univ Press, Cambridge, United Kingdom, 2013)."},{"key":"e_1_3_3_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr5006638"},{"key":"e_1_3_3_34_2","doi-asserted-by":"publisher","DOI":"10.1038\/srep13055"},{"key":"e_1_3_3_35_2","doi-asserted-by":"publisher","DOI":"10.1016\/0169-8095(94)00098-X"},{"key":"e_1_3_3_36_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.atmosenv.2011.10.060"},{"key":"e_1_3_3_37_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-70627-1_16"},{"key":"e_1_3_3_38_2","doi-asserted-by":"publisher","DOI":"10.1029\/2002JD002202"}],"container-title":["Proceedings of the National Academy of Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pnas.org\/doi\/pdf\/10.1073\/pnas.1606320113","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,4,13]],"date-time":"2022-04-13T01:27:49Z","timestamp":1649813269000},"score":1,"resource":{"primary":{"URL":"https:\/\/pnas.org\/doi\/full\/10.1073\/pnas.1606320113"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,9,29]]},"references-count":38,"journal-issue":{"issue":"42","published-print":{"date-parts":[[2016,10,18]]}},"alternative-id":["10.1073\/pnas.1606320113"],"URL":"https:\/\/doi.org\/10.1073\/pnas.1606320113","relation":{},"ISSN":["0027-8424","1091-6490"],"issn-type":[{"value":"0027-8424","type":"print"},{"value":"1091-6490","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,9,29]]},"assertion":[{"value":"2016-09-29","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}