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The autocatalytic nature and complex reaction network make a mechanistic understanding very challenging and widely debated. Water is not only part of the overall conversion, it is also frequently used as diluent, influencing, in turn, activity, selectivity, and stability of the catalysts. Water directly and indirectly influences the processes that initiate the C\u2013C formation via adjusting the chemical potential of methanol and dimethyl ether, with the latter being more efficient to generate highly reactive C\n                    <jats:sub>1<\/jats:sub>\n                    species via hydride transfer. The insight shows paths to optimize the stability of catalysts and to tailor the product distribution for H-ZSM-5\u2013based catalysts.\n                  <\/jats:p>","DOI":"10.1073\/pnas.2103840119","type":"journal-article","created":{"date-parts":[[2022,1,19]],"date-time":"2022-01-19T17:20:39Z","timestamp":1642612839000},"update-policy":"https:\/\/doi.org\/10.1073\/pnas.cm10313","source":"Crossref","is-referenced-by-count":35,"title":["Mechanistic differences between methanol and dimethyl ether in zeolite-catalyzed hydrocarbon synthesis"],"prefix":"10.1073","volume":"119","author":[{"given":"Felix M.","family":"Kirchberger","sequence":"first","affiliation":[{"name":"Department of Chemistry and Catalysis Research Center, Technische Universit\u00e4t M\u00fcnchen, 85747 Garching, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8939-0233","authenticated-orcid":false,"given":"Yue","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Catalysis Research Center, Technische Universit\u00e4t M\u00fcnchen, 85747 Garching, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Philipp N.","family":"Plessow","sequence":"additional","affiliation":[{"name":"Institute of Catalysis Research and Technology, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2604-9235","authenticated-orcid":false,"given":"Markus","family":"Tonigold","sequence":"additional","affiliation":[{"name":"Clariant Produkte (Deutschland) GmbH, 83052 Bruckm\u00fchl, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6841-4232","authenticated-orcid":false,"given":"Felix","family":"Studt","sequence":"additional","affiliation":[{"name":"Institute of Catalysis Research and Technology, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen, Germany"},{"name":"Institute for Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3769-9623","authenticated-orcid":false,"given":"Maricruz","family":"Sanchez-Sanchez","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Catalysis Research Center, Technische Universit\u00e4t M\u00fcnchen, 85747 Garching, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Johannes A.","family":"Lercher","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Catalysis Research Center, Technische Universit\u00e4t M\u00fcnchen, 85747 Garching, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"341","published-online":{"date-parts":[[2022,1,19]]},"reference":[{"key":"e_1_3_4_1_2","first-page":"86","article-title":"Gasoline from methanol in one step","volume":"6","author":"Meisel S. 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