{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,3]],"date-time":"2026-11-03T23:25:12Z","timestamp":1793748312116,"version":"4.6.1"},"reference-count":37,"publisher":"National Academy of Sciences","issue":"20","license":[{"start":{"date-parts":[[2022,5,9]],"date-time":"2022-05-09T00:00:00Z","timestamp":1652054400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"name":"National Key Research and Development Program of China","award":["2019YFA0705700"],"award-info":[{"award-number":["2019YFA0705700"]}]},{"DOI":"10.13039\/501100001809","name":"Joint Funds of National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["U21A20174"],"award-info":[{"award-number":["U21A20174"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["www.pnas.org"],"crossmark-restriction":true},"short-container-title":["Proc. Natl. Acad. Sci. U.S.A."],"published-print":{"date-parts":[[2022,5,17]]},"abstract":"<jats:title>Significance<\/jats:title>\n                  <jats:p>\n                    In recent years, lithium-ion batteries (LIBs) have been widely applied in electric vehicles as energy storage devices. However, it is a great challenge to deal with the large number of spent LIBs. In this work, we employ a rapid thermal radiation method to convert the spent LIBs into highly efficient bifunctional NiMnCo-activated carbon (NiMnCo-AC) catalysts for zinc-air batteries (ZABs). The obtained NiMnCo-AC catalyst shows excellent electrochemical performance in ZABs due to the unique core-shell structure, with face-centered cubic Ni in the core and spinel NiMnCoO\n                    <jats:sub>4<\/jats:sub>\n                    in the shell. This work provides an economical and environment-friendly approach to recycling the spent LIBs and converting them into novel energy storage devices.\n                  <\/jats:p>","DOI":"10.1073\/pnas.2202202119","type":"journal-article","created":{"date-parts":[[2022,5,9]],"date-time":"2022-05-09T15:03:16Z","timestamp":1652108596000},"update-policy":"https:\/\/doi.org\/10.1073\/pnas.cm10313","source":"Crossref","is-referenced-by-count":203,"title":["Recycling spent LiNi\n                    <sub>1-x-y<\/sub>\n                    Mn\n                    <sub>x<\/sub>\n                    Co\n                    <sub>y<\/sub>\n                    O\n                    <sub>2<\/sub>\n                    cathodes to bifunctional NiMnCo catalysts for zinc-air batteries"],"prefix":"10.1073","volume":"119","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6662-659X","authenticated-orcid":false,"given":"Miaolun","family":"Jiao","sequence":"first","affiliation":[{"name":"Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenliang","family":"Ye","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Tsinghua University, Beijing 100084, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhibo","family":"Liu","sequence":"additional","affiliation":[{"name":"Shenyang National Laboratory for Materials Science, Institute of Metal Research Chinese Academy of Sciences, Shenyang 110016, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2307-0450","authenticated-orcid":false,"given":"Xiongwei","family":"Zhong","sequence":"additional","affiliation":[{"name":"Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junxiong","family":"Wang","sequence":"additional","affiliation":[{"name":"Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuang","family":"Li","sequence":"additional","affiliation":[{"name":"Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lixin","family":"Dai","sequence":"additional","affiliation":[{"name":"Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3629-5686","authenticated-orcid":false,"given":"Guangmin","family":"Zhou","sequence":"additional","affiliation":[{"name":"Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui-Ming","family":"Cheng","sequence":"additional","affiliation":[{"name":"Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China"},{"name":"Shenyang National Laboratory for Materials Science, Institute of Metal Research Chinese Academy of Sciences, Shenyang 110016, China"},{"name":"Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"341","published-online":{"date-parts":[[2022,5,9]]},"reference":[{"key":"e_1_3_4_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00535"},{"key":"e_1_3_4_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1682-5"},{"key":"e_1_3_4_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.eng.2018.05.018"},{"key":"e_1_3_4_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202007090"},{"key":"e_1_3_4_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.wasman.2021.02.039"},{"key":"e_1_3_4_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00297E"},{"key":"e_1_3_4_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2021.130944"},{"key":"e_1_3_4_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201900454"},{"key":"e_1_3_4_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2015.02.064"},{"key":"e_1_3_4_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.09.014"},{"key":"e_1_3_4_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/sus2.16"},{"key":"e_1_3_4_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b00590"},{"key":"e_1_3_4_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.resconrec.2020.105142"},{"key":"e_1_3_4_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/cey2.29"},{"key":"e_1_3_4_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0368-4"},{"key":"e_1_3_4_16_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40843-021-1682-0"},{"key":"e_1_3_4_17_2","doi-asserted-by":"publisher","DOI":"10.20964\/2020.07.67"},{"key":"e_1_3_4_18_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00807-8"},{"key":"e_1_3_4_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202000868"},{"key":"e_1_3_4_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2019.226761"},{"key":"e_1_3_4_21_2","doi-asserted-by":"publisher","DOI":"10.3390\/met8050321"},{"key":"e_1_3_4_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.resconrec.2020.105219"},{"key":"e_1_3_4_23_2","doi-asserted-by":"publisher","DOI":"10.3390\/ma13030801"},{"key":"e_1_3_4_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2021.229622"},{"key":"e_1_3_4_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2020.228936"},{"key":"e_1_3_4_26_2","doi-asserted-by":"publisher","DOI":"10.1080\/10643389.2018.1540760"},{"key":"e_1_3_4_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.7b03811"},{"key":"e_1_3_4_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9RA06686A"},{"key":"e_1_3_4_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.124211"},{"key":"e_1_3_4_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2021.102690"},{"key":"e_1_3_4_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5EE01290B"},{"key":"e_1_3_4_32_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00578-1"},{"key":"e_1_3_4_33_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5345"},{"key":"e_1_3_4_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02622"},{"key":"e_1_3_4_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b00119"},{"key":"e_1_3_4_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b00928"},{"key":"e_1_3_4_37_2","doi-asserted-by":"publisher","DOI":"10.1016\/0927-0256(96)00008-0"}],"container-title":["Proceedings of the National Academy of Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pnas.org\/doi\/pdf\/10.1073\/pnas.2202202119","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,5,9]],"date-time":"2022-05-09T15:04:47Z","timestamp":1652108687000},"score":1,"resource":{"primary":{"URL":"https:\/\/pnas.org\/doi\/full\/10.1073\/pnas.2202202119"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,5,9]]},"references-count":37,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2022,5,17]]}},"alternative-id":["10.1073\/pnas.2202202119"],"URL":"https:\/\/doi.org\/10.1073\/pnas.2202202119","relation":{},"ISSN":["0027-8424","1091-6490"],"issn-type":[{"value":"0027-8424","type":"print"},{"value":"1091-6490","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,5,9]]},"assertion":[{"value":"2022-02-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-03-28","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-05-09","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e2202202119"}}