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Natl. Acad. Sci. U.S.A."],"published-print":{"date-parts":[[2022,5,31]]},"abstract":"<jats:title>Significance<\/jats:title>\n                  <jats:p>\n                    The intrinsic sluggish kinetics of organodisulfides has hindered its further application in large-scale energy storage. In this work, we propose a unique redox mediator (carbon disulfide [CS\n                    <jats:sub>2<\/jats:sub>\n                    ]) involving reversible C-S bond formation\/breakage, which accelerates the reaction kinetics of organodisulfides by reducing about one-third of the energy barrier of sulfur\u2013sulfur bond breakage. The strategy described here supplies a perspective for enhancing the electrochemical behavior of organodisulfides and greatly facilitates the development of organodisulfides in large-scale energy storage applications.\n                  <\/jats:p>","DOI":"10.1073\/pnas.2202449119","type":"journal-article","created":{"date-parts":[[2022,5,27]],"date-time":"2022-05-27T13:51:13Z","timestamp":1653659473000},"update-policy":"https:\/\/doi.org\/10.1073\/pnas.cm10313","source":"Crossref","is-referenced-by-count":13,"title":["Carbon disulfide: A redox mediator for organodisulfides in redox flow batteries"],"prefix":"10.1073","volume":"119","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9121-9256","authenticated-orcid":false,"given":"Qiliang","family":"Chen","sequence":"first","affiliation":[{"name":"College of Chemistry, Zhengzhou University, Zhengzhou 450001, P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3746-9884","authenticated-orcid":false,"given":"Yongzhu","family":"Fu","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University, Zhengzhou 450001, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"341","published-online":{"date-parts":[[2022,5,27]]},"reference":[{"key":"e_1_3_4_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-020-0160-9"},{"key":"e_1_3_4_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00231"},{"key":"e_1_3_4_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0MH01364A"},{"key":"e_1_3_4_4_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.2096706"},{"key":"e_1_3_4_5_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.2097478"},{"key":"e_1_3_4_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201902223"},{"key":"e_1_3_4_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202100824"},{"key":"e_1_3_4_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c02188"},{"key":"e_1_3_4_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201701294"},{"key":"e_1_3_4_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-23521-1"},{"key":"e_1_3_4_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC04076A"},{"key":"e_1_3_4_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA01273G"},{"key":"e_1_3_4_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603897"},{"key":"e_1_3_4_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500720t"},{"key":"e_1_3_4_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.abd9795"},{"key":"e_1_3_4_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00599"},{"key":"e_1_3_4_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.05.010"},{"key":"e_1_3_4_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00569E"},{"key":"e_1_3_4_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA01973B"},{"key":"e_1_3_4_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2017.12.025"},{"key":"e_1_3_4_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.6b00533"},{"key":"e_1_3_4_22_2","first-page":"e2104036","article-title":"Smart flow electrosynthesis and application of organodisulfides in redox flow batteries","volume":"9","author":"Chen Q.","year":"2022","unstructured":"Q. 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