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Here, we introduce a wireless photocatalytic architecture for conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    and water into methanol and oxygen. The catalytic material consists of semiconducting nanowires decorated with core\u2013shell nanoparticles, with a copper-rhodium core and a chromium oxide shell. The Rh\/CrOOH interface provides a unidirectional channel for proton reduction, enabling hydrogen spillover at the core\u2013shell interface. The vectorial transfer of protons, electrons, and hydrogen atoms allows for switching the mechanism of CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction from a proton-coupled electron transfer pathway in aqueous solution to hydrogenation of CO\n                    <jats:sub>2<\/jats:sub>\n                    with a solar-to-methanol efficiency of 0.22%. The reported findings demonstrate a highly efficient, stable, and scalable wireless system for synthesis of methanol from CO\n                    <jats:sub>2<\/jats:sub>\n                    that could provide a viable path toward carbon neutrality and environmental sustainability.\n                  <\/jats:p>","DOI":"10.1073\/pnas.2408183121","type":"journal-article","created":{"date-parts":[[2024,8,22]],"date-time":"2024-08-22T13:43:41Z","timestamp":1724334221000},"update-policy":"https:\/\/doi.org\/10.1073\/pnas.cm10313","source":"Crossref","is-referenced-by-count":19,"title":["A synergetic cocatalyst for conversion of carbon dioxide, sunlight, and water into methanol"],"prefix":"10.1073","volume":"121","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4759-2061","authenticated-orcid":false,"given":"Zhengwei","family":"Ye","sequence":"first","affiliation":[{"name":"Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, MI 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