{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,6,11]],"date-time":"2025-06-11T04:08:27Z","timestamp":1749614907633,"version":"3.41.0"},"reference-count":72,"publisher":"IOP Publishing","issue":"25","license":[{"start":{"date-parts":[[2025,6,10]],"date-time":"2025-06-10T00:00:00Z","timestamp":1749513600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/page\/copyright"},{"start":{"date-parts":[[2025,6,10]],"date-time":"2025-06-10T00:00:00Z","timestamp":1749513600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/info\/page\/text-and-data-mining"}],"funder":[{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"crossref","award":["CRG\/2023\/003063"],"award-info":[{"award-number":["CRG\/2023\/003063"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iopscience.iop.org"],"crossmark-restriction":false},"short-container-title":["J. Phys.: Condens. Matter"],"published-print":{"date-parts":[[2025,6,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n               <jats:p>Frustrated magnets offer a unique playground for exploring emergent quantum phenomena. We report the synthesis, structural details, and magnetic properties of <jats:italic>S<\/jats:italic> = 1 frustrated system Ni<jats:sub>12<\/jats:sub>(HPO<jats:sub>4<\/jats:sub>)<jats:sub>6<\/jats:sub>(PO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(OH)<jats:sub>6<\/jats:sub> through magnetization and specific heat measurements along with the density functional theory (DFT) calculations. The titled compound hosts a three-dimensional frustrated spin-lattice wherein Ni<jats:sup>2+<\/jats:sup> (<jats:italic>S<\/jats:italic> = 1) magnetic moments constitute hexagonal rings. The DFT electronic structure calculation reveals that Ni<jats:sup>2+<\/jats:sup> moments in the hexagonal rings have alternate ferromagnetic (FM) and antiferromagnetic (AFM) interactions with considerable inter-hexagonal ring magnetic interactions. The magnetic susceptibility <jats:italic>\u03c7<\/jats:italic>(<jats:italic>T<\/jats:italic>) data follow Curie\u2013Weiss (CW) behavior at high temperatures with a large CW temperature of about \u2212250 K, implying the strong AFM interactions between the Ni<jats:sup>2+<\/jats:sup> (<jats:italic>S<\/jats:italic> = 1) magnetic moments. The <jats:italic>\u03c7<\/jats:italic>(<jats:italic>T<\/jats:italic>) and specific heat data show an anomaly at 61 K, indicating the presence of magnetic order. Alternative FM and AFM bonds in the hexagonal ring induce magnetic frustration, and the non-negligible inter-hexagonal ring interactions lead to the long-range magnetic order in the titled compound.<\/jats:p>","DOI":"10.1088\/1361-648x\/adde9e","type":"journal-article","created":{"date-parts":[[2025,5,29]],"date-time":"2025-05-29T22:53:56Z","timestamp":1748559236000},"page":"255801","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":0,"title":["Ni<sub>12<\/sub>(HPO<sub>4<\/sub>)<sub>6<\/sub>(PO<sub>4<\/sub>)<sub>2<\/sub>(OH)<sub>6<\/sub>: a compound with coupled frustrated hexagons of alternating ferromagnetic and antiferromagnetic interactions"],"prefix":"10.1088","volume":"37","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-0245-3752","authenticated-orcid":true,"given":"V K","family":"Sahu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"S","family":"Gayen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0531-9972","authenticated-orcid":false,"given":"K","family":"Boya","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G","family":"Pradhan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7419-4907","authenticated-orcid":false,"given":"V K","family":"Singh","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M","family":"Barik","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"P","family":"Khuntia","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5368-9866","authenticated-orcid":true,"given":"Y","family":"Bitla","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6675-3396","authenticated-orcid":true,"given":"S K","family":"Panda","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9769-1730","authenticated-orcid":true,"given":"B","family":"Koteswararao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"266","published-online":{"date-parts":[[2025,6,10]]},"reference":[{"key":"cmadde9ebib1","doi-asserted-by":"publisher","first-page":"199","DOI":"10.1038\/nature08917","article-title":"Spin liquids in frustrated magnets","volume":"464","author":"Balents","year":"2010","journal-title":"Nature"},{"key":"cmadde9ebib2","doi-asserted-by":"publisher","first-page":"453","DOI":"10.1146\/annurev.ms.24.080194.002321","article-title":"Strongly geometrically frustrated magnets","volume":"24","author":"Ramirez","year":"1994","journal-title":"Annu. Rev. Mater. Sci."},{"key":"cmadde9ebib3","doi-asserted-by":"publisher","first-page":"24","DOI":"10.1063\/1.2186278","article-title":"Geometrical frustration","volume":"59","author":"Moessner","year":"2006","journal-title":"Phys. Today"},{"volume":"vol 164","year":"2011","author":"Lacroix","key":"cmadde9ebib4"},{"key":"cmadde9ebib5","doi-asserted-by":"publisher","first-page":"153","DOI":"10.1016\/0025-5408(73)90167-0","article-title":"Resonating valence bonds: a new kind of insulator?","volume":"8","author":"Anderson","year":"1973","journal-title":"Mater. Res. Bull."},{"key":"cmadde9ebib6","doi-asserted-by":"publisher","DOI":"10.1103\/RevModPhys.89.025003","article-title":"Quantum spin liquid states","volume":"89","author":"Zhou","year":"2017","journal-title":"Rev. Mod. Phys."},{"key":"cmadde9ebib7","doi-asserted-by":"publisher","first-page":"1495","DOI":"10.1126\/science.1064761","article-title":"Spin ice state in frustrated magnetic pyrochlore materials","volume":"294","author":"Bramwell","year":"2001","journal-title":"Science"},{"key":"cmadde9ebib8","doi-asserted-by":"publisher","first-page":"264","DOI":"10.1038\/s42254-019-0038-2","article-title":"Concept and realization of Kitaev quantum spin liquids","volume":"1","author":"Takagi","year":"2019","journal-title":"Nat. Rev. Phys."},{"key":"cmadde9ebib9","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.physrep.2023.09.008","article-title":"Experimental signatures of quantum and topological states in frustrated magnetism","volume":"1041","author":"Khatua","year":"2023","journal-title":"Phys. Rep."},{"key":"cmadde9ebib10","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.98.107204","article-title":"Spin dynamics of the spin- 1\/2 kagome lattice antiferromagnet ZnCu3(OH)6Cl2","volume":"98","author":"Helton","year":"2007","journal-title":"Phys. Rev. Lett."},{"key":"cmadde9ebib11","doi-asserted-by":"publisher","first-page":"406","DOI":"10.1038\/nature11659","article-title":"Fractionalized excitations in the spin-liquid state of a kagome-lattice antiferromagnet","volume":"492","author":"Han","year":"2012","journal-title":"Nature"},{"key":"cmadde9ebib12","doi-asserted-by":"publisher","first-page":"469","DOI":"10.1038\/s41567-020-0792-1","article-title":"Gapless ground state in the archetypal quantum kagome antiferromagnet ZnCu3(OH)6Cl2","volume":"16","author":"Khuntia","year":"2020","journal-title":"Nat. Phys."},{"key":"cmadde9ebib13","doi-asserted-by":"publisher","first-page":"276","DOI":"10.1126\/science.abc6363","article-title":"Gapped magnetic ground state in quantum spin liquid candidate \u03ba- (BEDT\u2212TTF)2Cu2(CN)3","volume":"372","author":"Miksch","year":"2021","journal-title":"Science"},{"key":"cmadde9ebib14","doi-asserted-by":"publisher","DOI":"10.1038\/srep16419","article-title":"Gapless quantum spin liquid ground state in the two-dimensional spin- 12 triangular antiferromagnet YbMgGaO4","volume":"5","author":"Li","year":"2015","journal-title":"Sci. Rep."},{"key":"cmadde9ebib15","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.100.144432","article-title":"Gapless spin-liquid state in the structurally disorder-free triangular antiferromagnet NaYbO2","volume":"100","author":"Ding","year":"2019","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib16","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.99.180401","article-title":"Field-induced instability of the quantum spin liquid ground state in the Jeff= triangular-lattice compound NaYbO2","volume":"99","author":"Ranjith","year":"2019","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib17","doi-asserted-by":"publisher","first-page":"1058","DOI":"10.1038\/s41567-019-0594-5","article-title":"Field-tunable quantum disordered ground state in the triangular-lattice antiferromagnet NaYbO2","volume":"15","author":"Bordelon","year":"2019","journal-title":"Nat. Phys."},{"key":"cmadde9ebib18","doi-asserted-by":"publisher","first-page":"13","DOI":"10.1007\/s44214-022-00011-z","article-title":"Magnetic field effects on the quantum spin liquid behaviors of NaYbS2","volume":"1","author":"Wu","year":"2022","journal-title":"Quantum Front."},{"key":"cmadde9ebib19","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.119.157201","article-title":"Disorder-induced mimicry of a spin liquid in YbMgGaO4","volume":"119","author":"Zhu","year":"2017","journal-title":"Phys. Rev. Lett."},{"key":"cmadde9ebib20","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevX.8.031028","article-title":"Valence bonds in random quantum magnets: theory and application to YbMgGaO4","volume":"8","author":"Kimchi","year":"2018","journal-title":"Phys. Rev. X"},{"key":"cmadde9ebib21","doi-asserted-by":"publisher","first-page":"6617","DOI":"10.1021\/acs.chemmater.2c01576","article-title":"Quantum effect on the ground state of the triple-perovskite Ba3MNb2O9 (M = Co, Ni and Mn) with triangular-lattice","volume":"34","author":"Jiao","year":"2022","journal-title":"Chem. Mater."},{"key":"cmadde9ebib22","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.77.054429","article-title":"Spin dynamics and spin freezing behavior in the two-dimensional antiferromagnet NiGa2S4 revealed by Ga-NMR, NQR and \u03bcSR measurements","volume":"77","author":"Takeya","year":"2008","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib23","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.107.197204","article-title":"High-pressure sequence of B3NiSb2O9 structural phases: New S\u2009=\u20091 quantum spin liquids based on Ni2+","volume":"107","author":"Cheng","year":"2011","journal-title":"Phys. Rev. Lett."},{"key":"cmadde9ebib24","doi-asserted-by":"publisher","first-page":"897","DOI":"10.1139\/p78-120","article-title":"The ground state of two quantum models of magnetism","volume":"56","author":"Oitmaa","year":"1978","journal-title":"Can. J. Phys."},{"key":"cmadde9ebib25","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.44.11869","article-title":"Second-order spin-wave results for the quantum XXZ and XY models with anisotropy","volume":"44","author":"Weihong","year":"1991","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib26","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.96.214428","article-title":"Investigation of the spin-1 honeycomb antiferromagnet BaNi2V2O8 with easy-plane anisotropy","volume":"96","author":"Klyushina","year":"2017","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib27","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.87.024415","article-title":"Exotic disordered phases in the quantum J1-J2 model on the honeycomb lattice","volume":"87","author":"Zhang","year":"2013","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib28","doi-asserted-by":"publisher","first-page":"241","DOI":"10.1007\/s100510170273","article-title":"An investigation of the quantum J1-J2-J3 model on the honeycomb lattice","volume":"20","author":"Fouet","year":"2001","journal-title":"Eur. Phys. J. B"},{"key":"cmadde9ebib29","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.97.134409","article-title":"Short-range order in the quantum XXZ honeycomb lattice material BaCo2(PO4)2","volume":"97","author":"Nair","year":"2018","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib30","doi-asserted-by":"publisher","first-page":"2","DOI":"10.1016\/j.aop.2005.10.005","article-title":"Anyons in an exactly solved model and beyond","volume":"321","author":"Kitaev","year":"2006","journal-title":"Ann. Phys., NY"},{"key":"cmadde9ebib31","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.102.017205","article-title":"Mott insulators in the strong spin-orbit coupling limit: From Heisenberg to a quantum compass and Kitaev models","volume":"102","author":"Jackeli","year":"2009","journal-title":"Phys. Rev. Lett."},{"key":"cmadde9ebib32","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.105.027204","article-title":"Kitaev-Heisenberg model on a honeycomb lattice: Possible exotic phases in iridium oxides A2IrO3","volume":"105","author":"Chaloupka","year":"2010","journal-title":"Phys. Rev. Lett."},{"key":"cmadde9ebib33","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.82.064412","article-title":"Antiferromagnetic mott insulating state in single crystals of the honeycomb lattice material Na2IrO3","volume":"82","author":"Singh","year":"2010","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib34","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.90.041112","article-title":"\u03b1\u2212RuCl3: a spin-orbit assisted mott insulator on a honeycomb lattice","volume":"90","author":"Plumb","year":"2014","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib35","doi-asserted-by":"crossref","first-page":"733","DOI":"10.1038\/nmat4604","article-title":"Proximate Kitaev quantum spin liquid behaviour in a honeycomb magnet","volume":"15","author":"Banerjee","year":"2016","journal-title":"Nat. Mater."},{"key":"cmadde9ebib36","doi-asserted-by":"publisher","first-page":"1079","DOI":"10.1038\/nphys4264","article-title":"Majorana fermions in the Kitaev quantum spin system \u03b1-RuCl3","volume":"13","author":"Do","year":"2017","journal-title":"Nat. Phys."},{"key":"cmadde9ebib37","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.102.224429","article-title":"Kitaev interactions in the Co honeycomb antiferromagnets Na3Co2SbO6 and Na2Co2TeO6","volume":"102","author":"Songvilay","year":"2020","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib38","doi-asserted-by":"publisher","DOI":"10.1088\/1361-648X\/ac2644","article-title":"Antiferromagnetic kitaev interaction in jeff = 1\/2 cobalt honeycomb materials Na3Co2SbO6 and Na2Co2TeO6","volume":"34","author":"Kim","year":"2021","journal-title":"J. Phys.: Condens. Matter"},{"key":"cmadde9ebib39","doi-asserted-by":"publisher","DOI":"10.59717\/j.xinn-mater.2024.100082","article-title":"Evidence for field induced quantum spin liquid behavior in a spin-1\/2 honeycomb magnet","volume":"2","author":"Lin","year":"2024","journal-title":"Inn. Mater."},{"key":"cmadde9ebib40","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevMaterials.3.074405","article-title":"Magnetic order in single crystals of Na3Co2SbO6 with a honeycomb arrangement of 3d7Co2+ ions","volume":"3","author":"Yan","year":"2019","journal-title":"Phys. Rev. Mater."},{"key":"cmadde9ebib41","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.104.134425","article-title":"XY magnetism, Kitaev exchange and long-range frustration in the Jeff=12 honeycomb cobaltates","volume":"104","author":"Das","year":"2021","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib42","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevResearch.5.013022","article-title":"Zigzag magnetic order and possible Kitaev interactions in the spin-1 honeycomb lattice KNiAsO4","volume":"5","author":"Taddei","year":"2023","journal-title":"Phys. Rev. Res."},{"key":"cmadde9ebib43","doi-asserted-by":"publisher","first-page":"A1133","DOI":"10.1103\/PhysRev.140.A1133","article-title":"Self-consistent equations including exchange and correlation effects","volume":"140","author":"Kohn","year":"1965","journal-title":"Phys. Rev."},{"key":"cmadde9ebib44","doi-asserted-by":"publisher","first-page":"B864","DOI":"10.1103\/PhysRev.136.B864","article-title":"Inhomogeneous electron gas","volume":"136","author":"Hohenberg","year":"1964","journal-title":"Phys. Rev."},{"key":"cmadde9ebib45","doi-asserted-by":"publisher","first-page":"1758","DOI":"10.1103\/PhysRevB.59.1758","article-title":"From ultrasoft pseudopotentials to the projector augmented-wave method","volume":"59","author":"Kresse","year":"1999","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib46","doi-asserted-by":"publisher","first-page":"558","DOI":"10.1103\/PhysRevB.47.558","article-title":"Ab initio molecular dynamics for liquid metals","volume":"47","author":"Kresse","year":"1993","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib47","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.11169","article-title":"Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set","volume":"54","author":"Kresse","year":"1996","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib48","doi-asserted-by":"publisher","first-page":"1505","DOI":"10.1103\/PhysRevB.57.1505","article-title":"Electron-energy-loss spectra and the structural stability of nickel oxide: an LSDA+U study","volume":"57","author":"Dudarev","year":"1998","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib49","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.96.045137","article-title":"Pressure dependence of dynamically screened coulomb interactions in NiO: effective hubbard, hund, intershell and intersite components","volume":"96","author":"Panda","year":"2017","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib50","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.49.16223","article-title":"Improved tetrahedron method for Brillouin-zone integrations","volume":"49","author":"Bl\u00f6chl","year":"1994","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib51","doi-asserted-by":"publisher","first-page":"1087","DOI":"10.1063\/1.1699114","article-title":"Equation of state calculations by fast computing machines","volume":"21","author":"Metropolis","year":"1953","journal-title":"J. Chem. Phys."},{"key":"cmadde9ebib52","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/20\/31\/315203","article-title":"A method for atomistic spin dynamics simulations: implementation and examples","volume":"20","author":"Skubic","year":"2008","journal-title":"J. Phys.: Condens. Matter"},{"key":"cmadde9ebib53","doi-asserted-by":"publisher","first-page":"55","DOI":"10.1016\/0921-4526(93)90108-I","article-title":"Recent advances in magnetic structure determination by neutron powder diffraction","volume":"192","author":"Rodr\u00edguez-Carvajal","year":"1993","journal-title":"Physica B"},{"key":"cmadde9ebib54","doi-asserted-by":"publisher","first-page":"4879","DOI":"10.1021\/acs.inorgchem.1c03597","article-title":"Nonstoichiometric ellenbergerite-type phosphates: hydrothermal synthesis, crystal chemistry and magnetic behavior","volume":"61","author":"Shvanskaya","year":"2022","journal-title":"Inorg. Chem."},{"article-title":"Ni12(HPO4)6PO4)2(OH)6 P63mc related to COD 4313804 and to COD 1000115 and dumortierite","year":"2016","author":"Le Bail","key":"cmadde9ebib55"},{"key":"cmadde9ebib56","doi-asserted-by":"publisher","first-page":"92","DOI":"10.1016\/j.solidstatesciences.2014.11.014","article-title":"Polar space group and complex magnetism in Ni11(HPO3)8(OH)6: towards a new multiferroic material?","volume":"39","author":"Poienar","year":"2015","journal-title":"Solid State Sci."},{"key":"cmadde9ebib57","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c00872","article-title":"Synthesis, structures and magnetic investigations of nickel phosphates: Ni2(PO4)(OH), Ni7(PO4)3(HPO4)(OH)3 and NaNiPO4 including potential haldane behavior","volume":"63","author":"Williams","year":"2024","journal-title":"Inorg. Chem."},{"key":"cmadde9ebib58","doi-asserted-by":"publisher","first-page":"865","DOI":"10.1103\/PhysRevB.39.865","article-title":"Tight-binding approach to the orbital magnetic moment and magnetocrystalline anisotropy of transition-metal monolayers","volume":"39","author":"Bruno","year":"1989","journal-title":"Phys. Rev. B"},{"year":"1963","author":"Goodenough","key":"cmadde9ebib59"},{"key":"cmadde9ebib60","doi-asserted-by":"publisher","first-page":"87","DOI":"10.1016\/0022-3697(59)90061-7","article-title":"Superexchange interaction and symmetry properties of electron orbitals","volume":"10","author":"Kanamori","year":"1959","journal-title":"J. Phys. Chem. Solids"},{"key":"cmadde9ebib61","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.95.180407","article-title":"Bose-Einstein condensation of triplons in the S = 1 tetramer antiferromagnet K2Ni2(MoO4)3: a compound close to a quantum critical point","volume":"95","author":"Koteswararao","year":"2017","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib62","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevMaterials.7.074403","article-title":"Neutron scattering and muon-spin spectroscopy studies of the magnetic triangular-lattice compounds A2La2NiW2O12(A=Sr,Ba)","volume":"7","author":"Yu","year":"2023","journal-title":"Phys. Rev. Mater."},{"key":"cmadde9ebib63","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevMaterials.3.094402","article-title":"Structural and magnetic properties of the Ni5Ti(O2BO3)2 ludwigite","volume":"3","author":"Heringer","year":"2019","journal-title":"Phys. Rev. Mater."},{"year":"2013","author":"Selwood","key":"cmadde9ebib64"},{"year":"2005","author":"Kittel","key":"cmadde9ebib65"},{"year":"2001","author":"Blundell","key":"cmadde9ebib66"},{"key":"cmadde9ebib67","doi-asserted-by":"publisher","first-page":"1697","DOI":"10.1126\/science.1114727","article-title":"Spin disorder on a triangular lattice","volume":"309","author":"Nakatsuji","year":"2005","journal-title":"Science"},{"key":"cmadde9ebib68","doi-asserted-by":"publisher","first-page":"54","DOI":"10.1038\/s41567-018-0317-3","article-title":"Continuum of quantum fluctuations in a three-dimensional S = 1 Heisenberg magnet","volume":"15","author":"Plumb","year":"2019","journal-title":"Nat. Phys."},{"key":"cmadde9ebib69","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.127.157204","article-title":"Magnetic field induced quantum spin liquid in the two coupled trillium lattices of K2Ni2(SO4)3","volume":"127","author":"\u017divkovi\u0107","year":"2021","journal-title":"Phys. Rev. Lett."},{"key":"cmadde9ebib70","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.117.237203","article-title":"Magnetic excitations and electronic interactions in Sr2CuTeO6: a spin- 1\/2 square lattice heisenberg antiferromagnet","volume":"117","author":"Babkevich","year":"2016","journal-title":"Phys. Rev. Lett."},{"key":"cmadde9ebib71","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.78.064422","article-title":"Magnetic properties of BaCdVO(PO4)2: a strongly frustrated spin- 12 square lattice close to the quantum critical regime","volume":"78","author":"Nath","year":"2008","journal-title":"Phys. Rev. B"},{"key":"cmadde9ebib72","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.79.214417","article-title":"Extension of the spin- 12 frustrated square lattice model: the case of layered vanadium phosphates","volume":"79","author":"Tsirlin","year":"2009","journal-title":"Phys. Rev. B"}],"container-title":["Journal of Physics: Condensed Matter"],"original-title":[],"link":[{"URL":"https:\/\/iopscience.iop.org\/article\/10.1088\/1361-648X\/adde9e","content-type":"text\/html","content-version":"am","intended-application":"text-mining"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1088\/1361-648X\/adde9e\/pdf","content-type":"application\/pdf","content-version":"am","intended-application":"text-mining"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1088\/1361-648X\/adde9e","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1088\/1361-648X\/adde9e\/pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1088\/1361-648X\/adde9e\/pdf","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1088\/1361-648X\/adde9e\/pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1088\/1361-648X\/adde9e\/pdf","content-type":"application\/pdf","content-version":"am","intended-application":"similarity-checking"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1088\/1361-648X\/adde9e\/pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,6,10]],"date-time":"2025-06-10T11:36:04Z","timestamp":1749555364000},"score":1,"resource":{"primary":{"URL":"https:\/\/iopscience.iop.org\/article\/10.1088\/1361-648X\/adde9e"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,10]]},"references-count":72,"journal-issue":{"issue":"25","published-online":{"date-parts":[[2025,6,10]]},"published-print":{"date-parts":[[2025,6,23]]}},"URL":"https:\/\/doi.org\/10.1088\/1361-648x\/adde9e","relation":{},"ISSN":["0953-8984","1361-648X"],"issn-type":[{"type":"print","value":"0953-8984"},{"type":"electronic","value":"1361-648X"}],"subject":[],"published":{"date-parts":[[2025,6,10]]},"assertion":[{"value":"Ni12(HPO4)6(PO4)2(OH)6: a compound with coupled frustrated hexagons of alternating ferromagnetic and antiferromagnetic interactions","name":"article_title","label":"Article Title"},{"value":"Journal of Physics: Condensed Matter","name":"journal_title","label":"Journal Title"},{"value":"paper","name":"article_type","label":"Article Type"},{"value":"\u00a9 2025 IOP Publishing Ltd. All rights, including for text and data mining, AI training, and similar technologies, are reserved.","name":"copyright_information","label":"Copyright Information"},{"value":"2025-01-01","name":"date_received","label":"Date Received","group":{"name":"publication_dates","label":"Publication dates"}},{"value":"2025-05-29","name":"date_accepted","label":"Date Accepted","group":{"name":"publication_dates","label":"Publication dates"}},{"value":"2025-06-10","name":"date_epub","label":"Online publication date","group":{"name":"publication_dates","label":"Publication dates"}}]}}