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Phys.: Condens. Matter"],"published-print":{"date-parts":[[2025,10,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n               <jats:p>Inverse oxide\/metal catalysts have proved to be excellent systems for the generation of methanol by CO<jats:sub>2<\/jats:sub> hydrogenation or the partial oxidation of methane. These systems can exhibit unique structural and chemical properties due to the nano size of the oxide component and strong oxide\u2013metal interactions. Recent studies for ZnO\/Cu, CeO<jats:sub>2<\/jats:sub>\/Cu, TiO<jats:sub>2\/<\/jats:sub>Cu, MgO\/Cu, In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\/Cu, and In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\/Au catalysts have shown large variations in the composition and morphology of the oxide overlayer as a function of temperature and chemical environment. These oxide\u2013metal interfaces are able to react with CO<jats:sub>2<\/jats:sub> and CH<jats:sub>4<\/jats:sub> at room temperature, and both reactants have a strong influence on the physical and chemical properties of the catalysts. Under reaction conditions, switches between oxide\u2013metal and metal\u2013metal interfaces can take in the catalyst surface. A dynamic behavior that can be linked to a high selectivity for methanol production over systems such as ZnO\/Cu, CeO<jats:sub>2<\/jats:sub>\/Cu and In<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\/Au. This type of correlation deserves additional systematic studies since it could be a powerful tool for designing highly efficient catalysts for methanol synthesis.<\/jats:p>","DOI":"10.1088\/1361-648x\/ae0bdb","type":"journal-article","created":{"date-parts":[[2025,9,25]],"date-time":"2025-09-25T22:56:14Z","timestamp":1758840974000},"page":"403005","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":4,"title":["Novel inverse oxide\/metal catalysts for methanol synthesis: impact of oxide\u2013metal interactions and reversible morphological changes"],"prefix":"10.1088","volume":"37","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5680-4214","authenticated-orcid":true,"given":"Jos\u00e9 A","family":"Rodriguez","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"266","published-online":{"date-parts":[[2025,10,7]]},"reference":[{"key":"cmae0bdbbib1","doi-asserted-by":"publisher","first-page":"6330","DOI":"10.1002\/cssc.202001518","type":"journal-article","volume":"13","author":"Frei","year":"2020","journal-title":"Chem. 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