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The GSH-Ag NPs were expediently obtained by reducing AgNO\n                    <jats:sub>3<\/jats:sub>\n                    with NaBH\n                    <jats:sub>4<\/jats:sub>\n                    and modified with glutathione based on the Ag\u2013S bond. The rapid discrimination for pyrimethanil from other pesticides exhibited the high selectivity of GSH-Ag NPs, then the selectivity was proved by\n                    <jats:sup>1<\/jats:sup>\n                    H NMR, FT-IR and computational simulation. Based on the good properties of localized surface plasmon resonance, the selective recognition was transformed to visible optical signal in colorimetric test. Additionally the quantitative detection was achieved with good sensitivity and could be applied to analyze practical samples. The experimental results have shown a good linear relationship with pyrimethanil concentration ranging from 10\n                    <jats:italic>\u03bc<\/jats:italic>\n                    M to 1 mM and a low detection limit of 3.87\n                    <jats:italic>\u03bc<\/jats:italic>\n                    M.\n                  <\/jats:p>","DOI":"10.1088\/1361-6528\/aafb97","type":"journal-article","created":{"date-parts":[[2019,1,2]],"date-time":"2019-01-02T17:15:26Z","timestamp":1546449326000},"page":"115502","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":3,"title":["Glutathione modified Ag nanoparticles as efficient detector for pyrimethanil"],"prefix":"10.1088","volume":"30","author":[{"given":"Siyun","family":"Zhang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ren","family":"Hu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6498-2918","authenticated-orcid":false,"given":"Haibing","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"266","published-online":{"date-parts":[[2019,1,23]]},"reference":[{"key":"nanoaafb97bib1","doi-asserted-by":"publisher","first-page":"6385","DOI":"10.1039\/C5AY01478F","type":"journal-article","volume":"7","author":"Wang","year":"2015","journal-title":"Anal. 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All rights, including for text and data mining, AI training, and similar technologies, are reserved.","name":"copyright_information","label":"Copyright Information"},{"value":"2018-11-02","name":"date_received","label":"Date Received","group":{"name":"publication_dates","label":"Publication dates"}},{"value":"2019-01-02","name":"date_accepted","label":"Date Accepted","group":{"name":"publication_dates","label":"Publication dates"}},{"value":"2019-01-23","name":"date_epub","label":"Online publication date","group":{"name":"publication_dates","label":"Publication dates"}}]}}