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While the poor conductivity of sulfur, the volume effect and \u2018shuttle effect\u2019 during charge and discharge, and slow redox kinetics of polysulfide intermediates still limit the practical application. To solve these problems, we synthesize a valid 3D hybrid material (Co\n                    <jats:sub>9<\/jats:sub>\n                    S\n                    <jats:sub>8<\/jats:sub>\n                    @N-CHS) of nanosized Co\n                    <jats:sub>9<\/jats:sub>\n                    S\n                    <jats:sub>8<\/jats:sub>\n                    evenly distributed on N-doped carbon hollow spheres with strong chemical coupling by\n                    <jats:italic>in situ<\/jats:italic>\n                    carbonization of Co(NO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    @resorcinol\/formaldehyde and sulfidation. It presents a high electronic conductivity, absorbing chemical adsorption capability to polysulfides and can catalyze the sulfur redox processes. Compared with S\/AC and S\/N-CHS electrodes, S\/Co\n                    <jats:sub>9<\/jats:sub>\n                    S\n                    <jats:sub>8<\/jats:sub>\n                    @N-CHS electrodes achieve an excellent initial discharge specific capacity of 1337 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 C and a long cycle life with an ultralow capacity decay of 0.027% per cycle over 1000 cycles at 1.0 C and the coulombic efficiency is above 99%. Consequently, it is an effective sulfur host material for high performance Li-S batteries.\n                  <\/jats:p>","DOI":"10.1088\/1361-6528\/ab4841","type":"journal-article","created":{"date-parts":[[2019,9,26]],"date-time":"2019-09-26T21:34:32Z","timestamp":1569533672000},"page":"035404","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":21,"title":["3D hybrid of Co\n                    <sub>9<\/sub>\n                    S\n                    <sub>8<\/sub>\n                    and N-doped carbon hollow spheres as effective hosts for Li-S batteries"],"prefix":"10.1088","volume":"31","author":[{"given":"Weijuan","family":"Lin","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9938-4475","authenticated-orcid":false,"given":"Guoqiang","family":"He","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingheng","family":"Huang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiyong","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"266","published-online":{"date-parts":[[2019,10,21]]},"reference":[{"key":"nanoab4841bib1","doi-asserted-by":"publisher","first-page":"3018","DOI":"10.1039\/c2cs35256g","type":"journal-article","volume":"42","author":"Yang","year":"2013","journal-title":"Chem. 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All rights, including for text and data mining, AI training, and similar technologies, are reserved.","name":"copyright_information","label":"Copyright Information"},{"value":"2019-06-13","name":"date_received","label":"Date Received","group":{"name":"publication_dates","label":"Publication dates"}},{"value":"2019-09-26","name":"date_accepted","label":"Date Accepted","group":{"name":"publication_dates","label":"Publication dates"}},{"value":"2019-10-21","name":"date_epub","label":"Online publication date","group":{"name":"publication_dates","label":"Publication dates"}}]}}