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Within this structure, the NiTe\n                    <jats:sub>2<\/jats:sub>\n                    nanocrystals formed via the confined growth of NiTe\n                    <jats:sub>2<\/jats:sub>\n                    nanoparticles. The morphology and structure of the NiTe\n                    <jats:sub>2<\/jats:sub>\n                    @PG composite was examined by scanning electron microscopy, transmission electron microscopy, and x-ray diffraction, while the interfacial interaction between NiTe\n                    <jats:sub>2<\/jats:sub>\n                    and graphene was investigated by x-ray photoelectron spectroscopy and Raman spectroscopy. When evaluated as an anode material for lithium-ion batteries, the NiTe\n                    <jats:sub>2<\/jats:sub>\n                    @PG electrode delivered an initial reversible capacity of 875.7 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at a current density of 100 mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Furthermore, it exhibited outstanding long-term cyclability, retaining specific capacities of 243.5 and 135 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 10 000 cycles at high current densities of 2 and 5 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , respectively. This remarkable electrochemical performance was attributed to the unique architecture of NiTe\n                    <jats:sub>2<\/jats:sub>\n                    @PG and the robust covalent bonding at the graphene\/NiTe\n                    <jats:sub>2<\/jats:sub>\n                    interface. The porous graphene scaffold serves not only as a conductive substrate for the growth of NiTe\n                    <jats:sub>2<\/jats:sub>\n                    nanocrystals but also facilitates electron transport. Concurrently, its porous network shortened the diffusion path for Li\n                    <jats:sup>+<\/jats:sup>\n                    ions and enhanced electrolyte permeability. Moreover, the formation of C\u2013Te\u2013Ni covalent bonds between graphene and NiTe\n                    <jats:sub>2<\/jats:sub>\n                    played a crucial role in maintaining the structural integrity of the electrode during cycling.\n                  <\/jats:p>","DOI":"10.1088\/1361-6528\/ae490c","type":"journal-article","created":{"date-parts":[[2026,2,23]],"date-time":"2026-02-23T22:47:48Z","timestamp":1771886868000},"page":"095601","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":0,"title":["Flexible electrode of NiTe\n                    <sub>2<\/sub>\n                    \/porous graphene film as binder-free anode for lithium-ion batteries"],"prefix":"10.1088","volume":"37","author":[{"given":"Ruidi","family":"Wu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yan","family":"Gao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhiguo","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hongkun","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8737-9516","authenticated-orcid":true,"given":"Xiaoting","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rui","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"266","published-online":{"date-parts":[[2026,3,3]]},"reference":[{"key":"nanoae490cbib1","doi-asserted-by":"publisher","first-page":"52","DOI":"10.1002\/anie.200602373","type":"journal-article","volume":"46","author":"Armaroli","year":"2007","journal-title":"Angew. 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All rights, including for text and data mining, AI training, and similar technologies, are reserved.","name":"copyright_information","label":"Copyright Information"},{"value":"2025-12-29","name":"date_received","label":"Date Received","group":{"name":"publication_dates","label":"Publication dates"}},{"value":"2026-02-23","name":"date_accepted","label":"Date Accepted","group":{"name":"publication_dates","label":"Publication dates"}},{"value":"2026-03-03","name":"date_epub","label":"Online publication date","group":{"name":"publication_dates","label":"Publication dates"}}]}}