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In this study, in order to increase the specific surface area, a novel coral-like 3D porous Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    nanostructure was first synthesized via a hydrothermal method. Subsequently, CdS quantum dots were deposited on the coral-like Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    substrate by a successive ionic layer adsorption and reaction method with 40, 80, and 120 cycles (named Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    \/CdS-40, Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    \/CdS-80, and Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    \/CdS-120) to modulate the band structures and optical absorption properties of the composites. The results show that Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    \/CdS-80 exhibits a continuous and dense CdS overlayer with effectively passivated surface states, delivering the optimal PEC performance (3625\n                    <jats:italic>\u03bc<\/jats:italic>\n                    A\u00b7cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at +1 V about 39 times that of the pure Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    ). This is because the Type-II heterojunction between CdS and Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    facilitates the separation of photogenerated carriers, and the high-quality CdS coating reduces the capture of photogenerated carriers by defects. When coupled with 304 stainless steel, Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    \/CdS-80 yields a photovoltage drop of 0.39 V and a net photocurrent density of 99.39\n                    <jats:italic>\u03bc<\/jats:italic>\n                    A\u00b7cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , significantly outperforming the Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    \/CdS-40 and Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    \/CdS-120 samples. This work provides experimental evidence for the development of superior Ta\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    -based photogenerated cathodic protection materials.\n                  <\/jats:p>","DOI":"10.1088\/1361-6528\/aeb1d9","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T22:47:42Z","timestamp":1791499662000},"page":"425701","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":0,"title":["Preparation of type-\u2161 heterojunction of Ta\n                    <sub>3<\/sub>\n                    N\n                    <sub>5<\/sub>\n                    \/CdS for enhanced photocathodic protection"],"prefix":"10.1088","volume":"37","author":[{"given":"Yanjin","family":"Zhang","sequence":"first","affiliation":[{"name":"University of Science and Technology Beijing"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8689-5615","authenticated-orcid":true,"given":"Zhiming","family":"Bai","sequence":"additional","affiliation":[{"name":"University of Science and Technology Beijing"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Liu","sequence":"additional","affiliation":[{"name":"University of Science and Technology Beijing"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"266","published-online":{"date-parts":[[2026,10,16]]},"reference":[{"key":"nanoaeb1d9bib1","doi-asserted-by":"publisher","first-page":"3401","DOI":"10.3390\/ma13153401","type":"journal-article","article-title":"Special issue: advanced coatings for corrosion protection","volume":"13","author":"F\u00fcrbeth","year":"2020","journal-title":"Materials"},{"key":"nanoaeb1d9bib2","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2022.128883","type":"journal-article","article-title":"Study on release and inhibition action of mixed ZAPP and 8-HQ corrosion inhibitors loaded in pH-sensitive microcapsules for Mg AZ31","volume":"644","author":"Ghamsarizade","year":"2022","journal-title":"Colloids Surf. 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