{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,8]],"date-time":"2026-11-08T19:01:26Z","timestamp":1794164486149,"version":"4.8.0"},"reference-count":333,"publisher":"IOP Publishing","issue":"6","license":[{"start":{"date-parts":[[2024,5,16]],"date-time":"2024-05-16T00:00:00Z","timestamp":1715817600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/page\/copyright"},{"start":{"date-parts":[[2024,5,16]],"date-time":"2024-05-16T00:00:00Z","timestamp":1715817600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/info\/page\/text-and-data-mining"}],"content-domain":{"domain":["iopscience.iop.org"],"crossmark-restriction":false},"short-container-title":["Rep. Prog. Phys."],"published-print":{"date-parts":[[2024,6,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    In actinide systems, the 5\n                    <jats:italic>f<\/jats:italic>\n                    electrons experience a uniquely delicate balance of effects and interactions having similar energy scales, which are often difficult to properly disentangle. This interplay of factors such as the dual nature of 5\n                    <jats:italic>f<\/jats:italic>\n                    -states, strong electronic correlations, and strong spin\u2013orbit coupling results in electronically unusual and intriguing behavior such as multi-k antiferromagnetic ordering, multipolar ordering, Mott-physics, mixed valence configurations, and more. Despite the inherent allure of their exotic properties, the exploratory science of even the more basic, binary systems like the actinide oxides has been limited due to their toxicity, radioactivity, and reactivity. In this article, we provide an overview of the available synthesis techniques for selected binary actinide oxides, including the actinide dioxides, sesquioxides, and a selection of higher oxides. For these oxides, we also review and evaluate the current state of knowledge of their crystal structures and magnetic properties. In many aspects, substantial knowledge gaps exist in the current body of research on actinide oxides related to understanding their electronic ground states. Bridging these gaps is vital for improving not only a fundamental understanding of these systems but also of future nuclear technologies. To this end, we note the experimental techniques and necessary future investigations which may aid in better elucidating the nature of these fascinating systems.\n                  <\/jats:p>","DOI":"10.1088\/1361-6633\/ad38cb","type":"journal-article","created":{"date-parts":[[2024,3,28]],"date-time":"2024-03-28T18:21:40Z","timestamp":1711650100000},"page":"066501","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":22,"title":["Crystal structure and magnetism of actinide oxides: a review"],"prefix":"10.1088","volume":"87","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5280-9117","authenticated-orcid":true,"given":"Binod K","family":"Rai","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4064-4647","authenticated-orcid":true,"given":"Alex","family":"Breta\u00f1a","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gregory","family":"Morrison","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6398-5271","authenticated-orcid":true,"given":"Rosalie","family":"Greer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8681-6857","authenticated-orcid":true,"given":"Krzysztof","family":"Gofryk","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7351-9098","authenticated-orcid":false,"given":"Hans-Conrad","family":"zur Loye","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"266","published-online":{"date-parts":[[2024,5,16]]},"reference":[{"key":"ropad38cbbib1","doi-asserted-by":"publisher","first-page":"807","DOI":"10.1103\/RevModPhys.81.807","article-title":"Multipolar interactions in f-electron systems: the paradigm of actinide dioxides","volume":"81","author":"Santini","year":"2009","journal-title":"Rev. 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