{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,19]],"date-time":"2026-02-19T03:47:45Z","timestamp":1771472865873,"version":"3.50.1"},"reference-count":124,"publisher":"IOP Publishing","issue":"11","license":[{"start":{"date-parts":[[2024,11,15]],"date-time":"2024-11-15T00:00:00Z","timestamp":1731628800000},"content-version":"vor","delay-in-days":14,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2024,11,15]],"date-time":"2024-11-15T00:00:00Z","timestamp":1731628800000},"content-version":"tdm","delay-in-days":14,"URL":"https:\/\/iopscience.iop.org\/info\/page\/text-and-data-mining"}],"funder":[{"name":"DFG, German Research Foundation","award":["327886311"],"award-info":[{"award-number":["327886311"]}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"crossref"}]},{"name":"FCT","award":["LA\/P\/0061\/202"],"award-info":[{"award-number":["LA\/P\/0061\/202"]}]}],"content-domain":{"domain":["iopscience.iop.org"],"crossmark-restriction":false},"short-container-title":["Plasma Sources Sci. Technol."],"published-print":{"date-parts":[[2024,11,1]]},"abstract":"Abstract<\/jats:title>\n A Direct current (DC) nanosecond (ns)-pulsed plasma jet fed with N2<\/jats:sub> at near atmospheric pressure (\n \n \n \n 20<\/mml:mn>\n \n 000<\/mml:mn>\n <\/mml:mrow>\n <\/mml:math>\n <\/jats:inline-formula> Pa) is studied using a transient zero-dimensional (0-D) model coupled with a two-term Boltzmann equation solver. Good agreement is observed between the simulated and measured plasma properties: including the electron density and the ratios of the N\n \n \n \n \n \n 2<\/mml:mn>\n <\/mml:msub>\n (<\/mml:mo>\n v<\/mml:mi>\n =<\/mml:mo>\n 1<\/mml:mn>\n ,<\/mml:mo>\n 2<\/mml:mn>\n ,<\/mml:mo>\n 3<\/mml:mn>\n ,<\/mml:mo>\n 4<\/mml:mn>\n )<\/mml:mo>\n <\/mml:mrow>\n <\/mml:math>\n <\/jats:inline-formula> densities to the gas density. A variety of theoretical approaches are considered to determine the Vibrational-Vibrational (V-V) and Vibrational-Translational (V-T) rate coefficients. For the V-V kinetics, the simple form of an Harmonic Oscillator (sfHO), the Schwartz-Slawsky-Herzfeld (SSH) and the Forced Harmonic Oscillator (FHO) approaches are used. The SSH approach used in this study is an improved version based on the pure SSH approach. For the V-T kinetics, the sfHO, a fit function of the Semi-Classical (ffSC) calculations and a fit function of the Quasi-Classical Trajectory (ffQCT) calculations are used. The influence of these different approaches on the calculated temporal evolution profiles of the vibrational distribution functions (VDFs) within one pulse modulation cycle is revealed. It is observed that the use of these different approaches does not strongly affect the densities of the low vibrational levels (v<\/jats:italic>\u2009<\u20095), whereas larger influences on the higher level densities are found. In addition, it is found that the simulated evolution of the VDFs are sensitive to the probabilities of the neutral wall reaction \n \n \n \n \n \n N<\/mml:mi>\n <\/mml:mrow>\n 2<\/mml:mn>\n <\/mml:msub>\n (<\/mml:mo>\n v<\/mml:mi>\n )<\/mml:mo>\n +<\/mml:mo>\n \n wall<\/mml:mi>\n <\/mml:mrow>\n \u2192<\/mml:mo>\n \n \n N<\/mml:mi>\n <\/mml:mrow>\n 2<\/mml:mn>\n <\/mml:msub>\n (<\/mml:mo>\n v<\/mml:mi>\n \u2212<\/mml:mo>\n 1<\/mml:mn>\n )<\/mml:mo>\n <\/mml:mrow>\n <\/mml:math>\n <\/jats:inline-formula> in the range of \n \n \n \n 1<\/mml:mn>\n \u00d7<\/mml:mo>\n \n 10<\/mml:mn>\n \n \u2212<\/mml:mo>\n 2<\/mml:mn>\n <\/mml:mrow>\n <\/mml:msup>\n <\/mml:mrow>\n <\/mml:math>\n <\/jats:inline-formula> to \n \n \n \n 1<\/mml:mn>\n \u00d7<\/mml:mo>\n \n 10<\/mml:mn>\n \n \u2212<\/mml:mo>\n 4<\/mml:mn>\n <\/mml:mrow>\n <\/mml:msup>\n <\/mml:mrow>\n <\/mml:math>\n <\/jats:inline-formula>. A further analysis of the wall quenching probabilities of \n \n \n \n \n \n N<\/mml:mi>\n <\/mml:mrow>\n 2<\/mml:mn>\n <\/mml:msub>\n (<\/mml:mo>\n 0<\/mml:mn>\n <<\/mml:mo>\n v<\/mml:mi>\n <<\/mml:mo>\n 58<\/mml:mn>\n )<\/mml:mo>\n <\/mml:mrow>\n <\/mml:math>\n <\/jats:inline-formula> is of importance for a more accurate prediction of the VDFs.<\/jats:p>","DOI":"10.1088\/1361-6595\/ad8a86","type":"journal-article","created":{"date-parts":[[2024,10,23]],"date-time":"2024-10-23T22:52:08Z","timestamp":1729723928000},"page":"115011","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":4,"title":["Zero-dimensional simulations of DC ns-pulsed plasma jet in N2<\/sub> at near atmospheric pressure: validation of the vibrational kinetics"],"prefix":"10.1088","volume":"33","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1275-7695","authenticated-orcid":true,"given":"Youfan","family":"He","sequence":"first","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2335-2634","authenticated-orcid":true,"given":"Jan","family":"Kuhfeld","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4027-5792","authenticated-orcid":true,"given":"Nikita D","family":"Lepikhin","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5823-1501","authenticated-orcid":false,"given":"Uwe","family":"Czarnetzki","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6878-6850","authenticated-orcid":true,"given":"Vasco","family":"Guerra","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2581-9894","authenticated-orcid":false,"given":"Ralf","family":"Peter Brinkmann","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1082-4359","authenticated-orcid":true,"given":"Andrew R","family":"Gibson","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5540-0947","authenticated-orcid":true,"given":"Efe","family":"Kemaneci","sequence":"additional","affiliation":[]}],"member":"266","published-online":{"date-parts":[[2024,11,15]]},"reference":[{"key":"psstad8a86bib1","doi-asserted-by":"publisher","DOI":"10.1088\/0022-3727\/45\/26\/263001","article-title":"The emerging role of reactive oxygen and nitrogen species in redox biology and some implications for plasma applications to medicine and biology","volume":"45","author":"Graves","year":"2012","journal-title":"J. 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