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Photopolymerizable formulations with acrylic functional monomers and two different porogens (water and methanol) in different ratios were studied to produce emulsions with 50 vol% of the internal phase. The results of morphological characterization indicate that all MIPs have cauliflower-like multiscale structures that change as a function of the solvent combination and fabrication process. X-ray fluorescence microscopy maps presented a layered structure and homogeneous distribution of copper in the printed MIP. Copper(II) ion adsorption\u2013desorption tests were performed on MIPs prepared using a three-dimensional (3D) printing approach and MIPs prepared by bulk polymerization. Results indicate that the 3D printed MIP is able to absorb copper up to ten times more efficiently than the nonprinted one and the printed MIP with 100% water content has the highest imprint recognition.<\/jats:p>","DOI":"10.1089\/3dp.2022.0107","type":"journal-article","created":{"date-parts":[[2022,10,3]],"date-time":"2022-10-03T10:50:26Z","timestamp":1664794226000},"page":"619-627","source":"Crossref","is-referenced-by-count":7,"title":["Three-Dimensional Printing of Molecularly Imprinted Polymers by Digital Light Processing for Copper Ion Sequestration"],"prefix":"10.1177","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2284-623X","authenticated-orcid":false,"given":"Roya","family":"Rezanavaz","sequence":"first","affiliation":[{"name":"Scion, Rotorua, New Zealand."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miruna","family":"Petcu","sequence":"additional","affiliation":[{"name":"Scion, Rotorua, New Zealand."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marie-Joo","family":"Le Guen","sequence":"additional","affiliation":[{"name":"Scion, Rotorua, New Zealand."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antoine","family":"Dubois","sequence":"additional","affiliation":[{"name":"Southern Brittany University, Lorient, France."}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"179","published-online":{"date-parts":[[2024,4,16]]},"reference":[{"key":"e_1_3_8_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/0167-7799(89)90006-1"},{"key":"e_1_3_8_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/jmr.760"},{"key":"e_1_3_8_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2019.02.028"},{"key":"e_1_3_8_5_2","first-page":"43","volume-title":"et al","author":"Pupin RR","unstructured":"Pupin RR, , Monteiro GC, , Foguel MV, et al. 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