{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T10:04:27Z","timestamp":1789725867000,"version":"4.0.1"},"reference-count":99,"publisher":"SAGE Publications","issue":"1","license":[{"start":{"date-parts":[[2022,9,7]],"date-time":"2022-09-07T00:00:00Z","timestamp":1662508800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2022,9,7]],"date-time":"2022-09-07T00:00:00Z","timestamp":1662508800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.sagepub.com\/page\/policies\/text-and-data-mining-license"}],"content-domain":{"domain":["journals.sagepub.com"],"crossmark-restriction":true},"short-container-title":["Astrobiology"],"published-print":{"date-parts":[[2023,1]]},"abstract":"<jats:p>\n                    Mineral transformations by two hyperthermophilic Fe(III)-reducing crenarchaea,\n                    <jats:italic toggle=\"yes\">Pyrodictium delaneyi<\/jats:italic>\n                    and\n                    <jats:italic toggle=\"yes\">Pyrobaculum islandicum<\/jats:italic>\n                    , were examined using synthetic nanophase ferrihydrite, lepidocrocite, and akaganeite separately as terminal electron acceptors and compared with abiotic mineral transformations under similar conditions. Spectral analyses using visible\u2013near-infrared, Fourier-transform infrared attenuated total reflectance (FTIR-ATR), Raman, and M\u00f6ssbauer spectroscopies were complementary and revealed formation of various biomineral assemblages distinguishable from abiotic phases. The most extensive biogenic mineral transformation occurred with ferrihydrite, which formed primarily magnetite with spectral features similar to biomagnetite relative to a synthetic magnetite standard. The FTIR-ATR spectra of ferrihydrite bioreduced by\n                    <jats:italic toggle=\"yes\">P. delaneyi<\/jats:italic>\n                    also showed possible cell-associated organics such as exopolysaccharides. Such combined detections of biomineral assemblages and organics might serve as biomarkers for hyperthermophilic Fe(III) reduction. With lepidocrocite,\n                    <jats:italic toggle=\"yes\">P. delaneyi<\/jats:italic>\n                    produced primarily a ferrous carbonate phase reminiscent of siderite, and with akaganeite, magnetite and a ferrous phosphate phase similar to vivianite were formed.\n                    <jats:italic toggle=\"yes\">P. islandicum<\/jats:italic>\n                    showed minor biogenic production of a ferrous phosphate similar to vivianite when grown on lepidocrocite, and a mixed valent phosphate or sulfate mineral when grown on akaganeite. These results expand the range of biogenic mineral transformations at high temperatures and identify spacecraft-relevant spectroscopies suitable for discriminating mineral biogenicity.\n                  <\/jats:p>","DOI":"10.1089\/ast.2022.0042","type":"journal-article","created":{"date-parts":[[2022,9,7]],"date-time":"2022-09-07T16:48:40Z","timestamp":1662569320000},"page":"43-59","update-policy":"https:\/\/doi.org\/10.1177\/sage-journals-update-policy","source":"Crossref","is-referenced-by-count":6,"title":["Spectral Detection of Nanophase Iron Minerals Produced by Fe(III)-Reducing Hyperthermophilic Crenarchaea"],"prefix":"10.1177","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4950-9636","authenticated-orcid":false,"given":"Srishti","family":"Kashyap","sequence":"first","affiliation":[{"name":"Department of Microbiology, University of Massachusetts, Amherst, Massachusetts, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8980-3798","authenticated-orcid":false,"given":"Elizabeth C.","family":"Sklute","sequence":"additional","affiliation":[{"name":"Planetary Science Institute, Tucson, Arizona, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9505-0398","authenticated-orcid":false,"given":"Peng","family":"Wang","sequence":"additional","affiliation":[{"name":"Bruker Optics, Inc., Billerica, Massachusetts, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"suffix":"Jr.","given":"Thomas J.","family":"Tague","sequence":"additional","affiliation":[{"name":"Bruker Optics, Inc., Billerica, Massachusetts, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4272-793X","authenticated-orcid":false,"given":"M. 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