{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T19:24:23Z","timestamp":1740165863512,"version":"3.37.3"},"reference-count":18,"publisher":"Oxford University Press (OUP)","issue":"10","license":[{"start":{"date-parts":[[2024,10,8]],"date-time":"2024-10-08T00:00:00Z","timestamp":1728345600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/academic.oup.com\/pages\/standard-publication-reuse-rights"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2024,12,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n               <jats:p>Reversed-phase high-performance liquid chromatography was used to study the host-guest complexation of thiophosphacalixarenes (TPC 1\u20133) with acetamiprid, imidacloprid and carboxin as guests. The Onyx Monolithic C 18 column (150\u2009\u00d7\u20090.1\u00a0mm) and Phenomenex\u00ae were used with UV detection at 254\u00a0nm. The mobile phase consisted of dimethylformamide-acetonitrile-water. The association constant of the 1:1 guest-host complexes was determined from the relationship between the retention factor of the guest and concentration of the thiophosphacalix [6] arene host in the mobile phase. The stability constants are influenced by size, nature, position and quantity of substituents in the benzene ring of the calixarene skeleton. The detection limits for TPC 1, TPC 2 and TPC 3 are 0.95, 1.20 and 1.40\u00a0\u03bcg\/mL, while the quantification limits are 2.85, 3.60 and 4.20\u00a0\u03bcg\/mL for TPC 1, TPC 2 and TPC 3, respectively.<\/jats:p>","DOI":"10.1093\/chromsci\/bmae052","type":"journal-article","created":{"date-parts":[[2024,9,27]],"date-time":"2024-09-27T11:18:05Z","timestamp":1727435885000},"page":"972-977","source":"Crossref","is-referenced-by-count":0,"title":["RP-HPLC Study of the Complexation of Acetamiprid, Imidacloprid and Carboxin Guest Molecules With Thiophosphorylated Calix [6] Arene in Dimethylformamide-Acetonitrile-Water Mobile Phase"],"prefix":"10.1093","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8183-6325","authenticated-orcid":false,"given":"Chandramauly R","family":"Sharma","sequence":"first","affiliation":[{"name":"L J School of Applied Sciences, L J University , Ahmedabad-382210, Gujarat ,","place":["India"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vijay","family":"Mishra","sequence":"additional","affiliation":[{"name":"Navdeep Chemical Pvt. Ltd , Ankleshwar, Gujarat-393002 ,","place":["India"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yadvendra","family":"Agrawal","sequence":"additional","affiliation":[{"name":"L J Centre of Excellence, L J University , Ahmedabad-382210, Gujarat ,","place":["India"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"286","published-online":{"date-parts":[[2024,10,8]]},"reference":[{"key":"2024121310210748300_ref1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-1-4557-3148-0.00021-2","volume-title":"Sittig's handbook of pesticides and agricultural chemicals","author":"Pohanish","year":"2015","edition":"2nd Edition"},{"key":"2024121310210748300_ref2","doi-asserted-by":"publisher","first-page":"161","DOI":"10.1021\/ar00089a003","article-title":"Calixarenes","volume":"16","author":"Gutsche","year":"1983","journal-title":"Accounts of Chemical Research"},{"key":"2024121310210748300_ref3","doi-asserted-by":"publisher","first-page":"14485","DOI":"10.1021\/acs.chemrev.1c00503","article-title":"Structural chemistry of giant metal based supramolecules","volume":"121","author":"Virovets","year":"2021","journal-title":"Chemical Society Reviews"},{"key":"2024121310210748300_ref4","doi-asserted-by":"publisher","first-page":"905","DOI":"10.1070\/RC1998v067n11ABEH000472","article-title":"Phosphorus-containi (3, 4) ng calixarenes","volume":"67","author":"Antipin","year":"1998","journal-title":"Russian Chemical Reviews"},{"key":"2024121310210748300_ref5","doi-asserted-by":"publisher","first-page":"1","DOI":"10.14233\/ajchem.2013.12058","article-title":"Application of calixarenes in development of sensors","volume":"25","author":"Mokhtari","year":"2013","journal-title":"Asian Journal of Chemistry"},{"key":"2024121310210748300_ref6","doi-asserted-by":"publisher","first-page":"59","DOI":"10.1016\/j.molcata.2004.03.024","article-title":"Supramolecular calixarene-based catalytic systems in the Wacker-oxidation of higher alkenes","volume":"217","author":"Maksimov","year":"2004","journal-title":"Journal of Molecular Catalysis A: Chemical"},{"key":"2024121310210748300_ref7","doi-asserted-by":"publisher","first-page":"824","DOI":"10.1080\/03067319.2019.1616708","article-title":"Sensitive detection of heavy metals ions based on the calixarene derivatives-modified piezoelectric resonators: A review","volume":"99","author":"Eddaif","year":"2019","journal-title":"International Journal of Environmental Analytical Chemistry"},{"key":"2024121310210748300_ref8","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1007\/s10847-015-0553-4","article-title":"Calixarene-engineered surfaces and separation science","volume":"83","author":"Gezici","year":"2015","journal-title":"Journal of Inclusion Phenomena and Macrocyclic Chemistry"},{"key":"2024121310210748300_ref9","doi-asserted-by":"publisher","first-page":"1173","DOI":"10.1039\/C1CS15169J","article-title":"Host\u2013guest sensing by calixarenes on the surfaces","volume":"41","author":"Kim","year":"2012","journal-title":"Chemical Society Reviews"},{"key":"2024121310210748300_ref10","doi-asserted-by":"publisher","first-page":"e202202934","DOI":"10.1002\/chem.202202934","article-title":"Selective metal-ion complexation of a biomimetic calix [6] arene funnel cavity functionalized with phenol or Quinone","volume":"29","author":"Aoun","year":"2023","journal-title":"Chemistry - 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