{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T11:09:29Z","timestamp":1779880169047,"version":"3.53.1"},"reference-count":50,"publisher":"Oxford University Press (OUP)","issue":"9","license":[{"start":{"date-parts":[[2022,7,29]],"date-time":"2022-07-29T00:00:00Z","timestamp":1659052800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004233","name":"UPV","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004233","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2022,9,16]]},"abstract":"<jats:title>Abstract<\/jats:title>\n               <jats:p>Amino transaminases (ATAs) have been supported on a 2D ITQ-2 zeolite through electrostatic interactions, resulting in a highly stable active biocatalyst to obtain a variety of valuable chiral amines starting from prochiral ketones derived from biomass. We have extended the biocatalyst applications by designing a chemo-enzymatic process that allows, as the first step, prochiral ketones to be obtained from biomass-derived compounds through an aldol condensation\u2013reduction step using a bifunctional metal\/base catalyst. The prochiral ketone is subsequently converted into the chiral amine using the immobilized ATA. We show that it is feasible to couple both steps in a semi-continuous process to produce industrially relevant chiral amines with yields of &amp;gt;95% and \u223c100% enantiomer excess.<\/jats:p>","DOI":"10.1093\/nsr\/nwac135","type":"journal-article","created":{"date-parts":[[2022,7,29]],"date-time":"2022-07-29T12:39:31Z","timestamp":1659098371000},"source":"Crossref","is-referenced-by-count":11,"title":["Enzymatic and chemo-enzymatic strategies to produce highly valuable chiral amines from biomass with \u03c9-transaminases on 2D zeolites"],"prefix":"10.1093","volume":"9","author":[{"given":"J Miguel","family":"Carceller","sequence":"first","affiliation":[{"name":"Instituto de Tecnologia Qu\u00edmica (UPV-CSIC), Universitat Polit\u00e8cnica de Val\u00e8ncia , Valencia 46022 , Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Karen S","family":"Arias","sequence":"additional","affiliation":[{"name":"Instituto de Tecnologia Qu\u00edmica (UPV-CSIC), Universitat Polit\u00e8cnica de Val\u00e8ncia , Valencia 46022 , Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria J","family":"Climent","sequence":"additional","affiliation":[{"name":"Instituto de Tecnologia Qu\u00edmica (UPV-CSIC), Universitat Polit\u00e8cnica de Val\u00e8ncia , Valencia 46022 , Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sara","family":"Iborra","sequence":"additional","affiliation":[{"name":"Instituto de Tecnologia Qu\u00edmica (UPV-CSIC), Universitat Polit\u00e8cnica de Val\u00e8ncia , Valencia 46022 , Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2232-3527","authenticated-orcid":false,"given":"Avelino","family":"Corma","sequence":"additional","affiliation":[{"name":"Instituto de Tecnologia Qu\u00edmica (UPV-CSIC), Universitat Polit\u00e8cnica de Val\u00e8ncia , Valencia 46022 , 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