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Here, three halogenated diphenyl ether (DPE) solvent additives (fluorinated DPE-F, chlorinated DPE-Cl and brominated DPE-Br) are developed to optimize active-layer (PM6:L8-BO) morphology. With the halogen atomic weight increases, three additives show a gradually increasing boiling point, while DPE-Cl and DPE-Br have similar but a much higher dipole moment compared to DPE-F. The higher boiling point and dipole moment of DPE-Br are expected to enhance the non-covalent interaction between the additive and L8-BO during the active layer film-forming process, offering improved intermolecular packing, charge transport, exciton dissociation and charge collection. As a result, the DPE-Br-treated OSC achieves a higher PCE (18.40%) compared to the DPE-F- and DPE-Cl-treated ones (17.73% and 18.03%). Impressively, using D18 as the donor, the OSCs based on DPE-Br-processed D18:L8-BO:BTP-eC9 obtain a further boosted PCE of \u223c20%, while their 11.6\u00a0cm2 opaque and semitransparent modules also achieve high PCEs of 16.42% and 10.50%, respectively, which are among the top values in OSCs and opaque\/semitransparent modules. This work highlights that the halogenation in DPE-derived additives is a promising strategy to optimize morphology for obtaining efficient OSCs and modules.<\/jats:p>","DOI":"10.1093\/nsr\/nwaf346","type":"journal-article","created":{"date-parts":[[2025,8,20]],"date-time":"2025-08-20T11:48:36Z","timestamp":1755690516000},"source":"Crossref","is-referenced-by-count":37,"title":["Halogenated diphenyl ether solvent additives enable \u223c20% efficiency organic solar cells and high-performance opaque\/semitransparent modules"],"prefix":"10.1093","volume":"12","author":[{"given":"Yibo","family":"Zhou","sequence":"first","affiliation":[{"name":"Xi'an Jiaotong University State Key Laboratory for Mechanical Behavior of Materials, , Xi'an 710049 ,","place":["China"]},{"name":"Xi'an University of Science and Technology School of Materials Science and Engineering, , Xi'an 710054 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenyan","family":"Su","sequence":"additional","affiliation":[{"name":"Xi'an University of Science and Technology School of Materials Science and Engineering, , Xi'an 710054 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zezhou","family":"Liang","sequence":"additional","affiliation":[{"name":"Jianghan University Key Laboratory of Flexible Optoelectronic Materials and Technology (Ministry of Education), Flexible Display Materials and Technology Co-Innovation Centre of Hubei Province, School of Optoelectronic Materials & Technology, , Wuhan 430056 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Wu","sequence":"additional","affiliation":[{"name":"Xi'an Jiaotong University State Key Laboratory for Mechanical Behavior of Materials, , Xi'an 710049 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