{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T17:01:04Z","timestamp":1790182864915,"version":"4.1.0"},"reference-count":48,"publisher":"Oxford University Press (OUP)","issue":"17","license":[{"start":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T00:00:00Z","timestamp":1783555200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22278210"],"award-info":[{"award-number":["22278210"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012246","name":"Priority Academic Program Development of Jiangsu Higher Education Institutions","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012246","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011398","name":"State Key Laboratory of Materials- Oriented Chemical Engineering","doi-asserted-by":"publisher","award":["SKL-MCE-25A05"],"award-info":[{"award-number":["SKL-MCE-25A05"]}],"id":[{"id":"10.13039\/501100011398","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008783","name":"National Research Council of Science and Technology","doi-asserted-by":"publisher","award":["GTL24052-100"],"award-info":[{"award-number":["GTL24052-100"]}],"id":[{"id":"10.13039\/501100008783","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS-2025-02309471"],"award-info":[{"award-number":["RS-2025-02309471"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Graphene\u2019s atomically smooth surface offers a promising platform for achieving superlubricity, not only in solid-state contacts but also in mass transport. While its ability to minimize interfacial friction has been extensively explored in microelectromechanical systems, engines and biomedical implants, harnessing this property for near-frictionless molecular flow to enable ultra-fast permeation remains a fundamental challenge. The principal limitation lies in the fabrication of defect-free graphene membranes with an exposed surface for probing intrinsic molecular friction and the associated transport phenomena. Here, we demonstrate a ferroelectric-polarization-assisted strategy for fabricating a 3.5-nm-thick graphene skin membrane for ultra-fast and selective separation. This is achieved by electrospinning a graphene oxide (GO)-poly(vinylidene fluoride) (PVDF) mixture, followed by thermal reduction. The crucial step involves the electric-field-induced transition of PVDF from the paraelectric (\u03b1) to the ferroelectric (\u03b2) phase, which promotes ordered chain packing and reduces the polymer\u2019s affinity for GO, thereby driving the spontaneous segregation of GO to the PVDF nanofiber surface. The resulting graphene surface minimizes interfacial interactions with permeating molecules, reducing the molecular flow friction coefficient by 2\u20133 orders of magnitude. Acting either as a selective layer or a support, the membrane exhibits ultra-fast permeation of water and organic solvents, surpassing current state-of-the-art membranes for water and solvent purification. For instance, a water flux up to 105.1\u00a0L m\u22122\u00a0h\u22121, a salt rejection of\u00a0&amp;gt;99.99% and long-term stability of 1000\u00a0h are achieved for desalination of hypersaline with salt concentrations &amp;gt;150\u00a0g L\u22121. This work establishes a new paradigm for realizing ultra-fast molecular transport and provides a versatile platform for investigating nanoscale fluidics at material interfaces.<\/jats:p>","DOI":"10.1093\/nsr\/nwag419","type":"journal-article","created":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T11:54:09Z","timestamp":1783511649000},"source":"Crossref","is-referenced-by-count":0,"title":["A ferroelectric-induced few-nanometer-thick graphene membrane enables molecular sliding for ultra-fast separation"],"prefix":"10.1093","volume":"13","author":[{"given":"Wenqi","family":"Ji","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanan","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guozhen","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Binyu","family":"Mo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huan","family":"Yu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaihua","family":"Gao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiasheng","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yangyang","family":"Mao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huimin","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gongping","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]},{"name":"Suzhou Laboratory , Suzhou 215100 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5047-3143","authenticated-orcid":false,"given":"Young Moo","family":"Lee","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]},{"name":"Hanyang University Department of Energy Engineering, College of Engineering, , Seoul 04763 ,","place":["Republic of Korea"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wanqin","family":"Jin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nanping","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University , Nanjing 211800 ,","place":["China"]},{"name":"Suzhou Laboratory , Suzhou 215100 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