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In this work, we report the discovery of a superconducting Tc(P) dome for the rhombohedral-I phase of ReO3 in the pressure range 12\u201339 GPa. The rhombohedral-I phase is featured by the nearly close-packed oxygen layers intercalated with Re cations, which is reminiscent of superhydride superconductors. The observed maximum Tc (\u223c 17.8 K) sets the record of high Tc among 5d transition-metal-oxides. First-principles calculations reveal that the strong hybridizations between Re-5d and O-2p orbitals significantly enhance the density of states at the Fermi level and the close-packed oxygen framework directly enhances the electron-phonon coupling. We attributed the observed record high-Tc to the synergistic effect of strong hybridizations and oxygen sublattice contribution. The present work establishes a rare case that the light-element oxygen lattice plays a crucial role in assisting the emergence of high-Tc superconductivity and provides more clues for further exploring new superconductors in 5d transition-metal oxides via high-pressure or heterostructure engineering.<\/jats:p>","DOI":"10.1093\/nsr\/nwag425","type":"journal-article","created":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T11:55:08Z","timestamp":1783598108000},"source":"Crossref","is-referenced-by-count":0,"title":["Discovery of record-breaking high-\n                    <i>T<\/i>\n                    c superconductivity among 5\n                    <i>d<\/i>\n                    transition-metal-oxides up to 17.8 K in ReO3"],"prefix":"10.1093","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5654-6155","authenticated-orcid":false,"given":"Pengfei","family":"Shan","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Condensed Matter Physics and 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