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While urban greening is widely advocated for mitigating extreme heat, its impacts on compound heat-O3 pollution remain poorly understood due to intricate urban meteorology-chemistry coupling. By integrating observations, reanalysis data, and urban-land-atmosphere modeling, we demonstrate that urban greenery provides a notable yet uneven cooling effect of\u00a0\u22120.26\u00b0C to\u00a0\u22121.08\u00b0C in Northern Hemisphere\u2019s metropolises, shaped by greenery fraction and local climate. Furthermore, the nonlinearly weakened O3 photochemical production within a greenery-stabilized urban boundary layer is capable of decreasing O3 in populated city centers. Despite the dual positive effects in alleviating heat and O3 exposures meteorologically, greenery-boosted biogenic emissions could chemically raise urban O3 via supplementing precursors, totally by up to 7.6\u00a0\u00b5g m\u22123. These findings underscore the need to incorporate fully coupled urban meteorology-chemistry interactions in urban greening strategies to achieve climatic and environmental co-benefits.<\/jats:p>","DOI":"10.1093\/nsr\/nwag494","type":"journal-article","created":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T11:12:34Z","timestamp":1786705954000},"source":"Crossref","is-referenced-by-count":2,"title":["Unraveling the potential of urban greenery for extreme heat and ozone mitigation in Northern Hemisphere cities"],"prefix":"10.1093","volume":"13","author":[{"given":"Mengmeng","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Severe Weather Meteorological Science and Technology, Nanjing University , Nanjing 210023 ,","place":["China"]},{"name":"School of Atmospheric Sciences, Nanjing University , Nanjing 210023 ,","place":["China"]},{"name":"Frontiers Science Center for Critical Earth Material Cycling , Nanjing 210023 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