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Soc. open sci."],"published-print":{"date-parts":[[2022,8]]},"abstract":"<jats:p>Two new metal-organic frameworks (MOFs) (Th\/ Ce -TCPE) based on 1,2,4,5-tetrakis(4-carboxyphenyl)ethylene were obtained using a straightforward reaction under moderate conditions. Th and Ce formed the central units of this MOF in the mononuclear and in the unusual trinuclear cluster configurations, respectively. The resulting MOFs were analysed by fluorescence spectroscopy to understand their luminescence. The obtained data revealed that benzene's electron cloud density and torsion angle on the ligand were affected by the acetic acid molecule and Th(IV), which caused Th-TCPE to irradiate stronger blue emission, but Ce-TCPE showed no fluorescence due to the self-quenching. Such a unique luminescence property could be used for fluorescence or radiopharmaceutical sensing.<\/jats:p>","DOI":"10.1098\/rsos.220525","type":"journal-article","created":{"date-parts":[[2022,8,31]],"date-time":"2022-08-31T07:06:35Z","timestamp":1661929595000},"update-policy":"https:\/\/doi.org\/10.1098\/crossmark-policy","source":"Crossref","is-referenced-by-count":3,"title":["Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene"],"prefix":"10.1098","volume":"9","author":[{"given":"Lin","family":"Li","sequence":"first","affiliation":[{"name":"Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, People's Republic of China"},{"name":"University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ting","family":"Yu","sequence":"additional","affiliation":[{"name":"Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, People's Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0846-9693","authenticated-orcid":true,"given":"Zhenghua","family":"Qian","sequence":"additional","affiliation":[{"name":"Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, People's Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiaoling","family":"Wu","sequence":"additional","affiliation":[{"name":"Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, People's Republic of China"},{"name":"University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hui","family":"He","sequence":"additional","affiliation":[{"name":"Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, People's Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guoan","family":"Ye","sequence":"additional","affiliation":[{"name":"Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, People's Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yanbo","family":"Qiao","sequence":"additional","affiliation":[{"name":"Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, People's Republic of China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"175","published-online":{"date-parts":[[2022,8,31]]},"reference":[{"key":"e_1_3_5_2_2","first-page":"38","article-title":"Development of actinide separation processes for future nuclear fuel cycles in Europe","volume":"11","author":"Taylor RJ","year":"2015","unstructured":"Taylor RJ, Bourg S, Glatz JP, Modolo G. 2015 Development of actinide separation processes for future nuclear fuel cycles in Europe. 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