{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,27]],"date-time":"2026-02-27T01:34:21Z","timestamp":1772156061039,"version":"3.50.1"},"reference-count":73,"publisher":"The Royal Society","issue":"8","license":[{"start":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T00:00:00Z","timestamp":1754006400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,8,1]],"date-time":"2025-08-01T00:00:00Z","timestamp":1754006400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["royalsocietypublishing.org"],"crossmark-restriction":true},"short-container-title":["R. Soc. Open Sci."],"published-print":{"date-parts":[[2025,8]]},"abstract":"<jats:p>A novel, durable heterogeneous magnesium-supported catalyst, IRMOF-3@Di(2-pyridyl) ketone@Mg(II) (Di(2-pyridyl) ketone: Di-2pyk), was effectively synthesized using a convenient approach and fully characterized utilizing chemo-physical analysis techniques such as powder X-ray diffraction analysis, attenuated total reflection infrared spectroscopy, field emission scanning electron microscopy with energy-dispersive spectroscopy, transmission electron microscopy, CHN analysis, inductively coupled plasma optical emission spectroscopy, thermogravimetric analysis and Brunauer\u2013Emmett\u2212Teller measurements. This metal\u2013organic framework-based nanocatalyst displayed excellent catalytic behaviour in chemoselective hydrogenation of five biomass-based carbonyl compounds of furfural, cinnamaldehyde, levulinic acid, vanillin and citral in addition to a variety of aliphatic, aromatic, and \u03b1,\u03b2-unsaturated aldehydes and ketones at room temperature in water in the presence of sodium borohydride as a mild and safe hydrogen source reagent. The leaching and reusability experiments of this catalyst exhibited stability and reactivity after four runs.<\/jats:p>","DOI":"10.1098\/rsos.242257","type":"journal-article","created":{"date-parts":[[2025,8,6]],"date-time":"2025-08-06T05:00:01Z","timestamp":1754456401000},"update-policy":"https:\/\/doi.org\/10.1098\/crossmark-policy","source":"Crossref","is-referenced-by-count":0,"title":["Reusable Mg supported IRMOF-3 as a heterogeneous nanocatalyst for chemoselective reduction of biomass-based aldehydes and ketones to alcohols under mild conditions"],"prefix":"10.1098","volume":"12","author":[{"given":"Fatemeh Moghimpour","family":"Bijani","sequence":"first","affiliation":[{"name":"Department of Chemistry, Shiraz University","place":["Shiraz, Iran"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4407-2527","authenticated-orcid":true,"given":"Ali Reza","family":"Sardarian","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Shiraz University","place":["Shiraz, Iran"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"175","published-online":{"date-parts":[[2025,8,6]]},"reference":[{"key":"e_1_3_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202400602"},{"key":"e_1_3_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/9781788012775"},{"key":"e_1_3_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/9781788012775"},{"key":"e_1_3_6_5_2","first-page":"151","volume-title":"Metal catalysis: concepts and reactions","author":"Harder S","year":"2020","unstructured":"Harder S. 2020 Early main group metal\u2010catalyzed hydrosilylation of unsaturated bonds. In Metal catalysis: concepts and reactions, pp. 151\u2013173. Weinheim, Germany: Wiley. (doi:10.1002\/9783527818020)"},{"key":"e_1_3_6_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-022-00077-6"},{"key":"e_1_3_6_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3OB00531C"},{"key":"e_1_3_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.oprd.3c00305"},{"key":"e_1_3_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c11284"},{"key":"e_1_3_6_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-14565-w"},{"key":"e_1_3_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT00465K"},{"key":"e_1_3_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c02073"},{"key":"e_1_3_6_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jma.2021.05.012"},{"key":"e_1_3_6_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2024.02.003"},{"key":"e_1_3_6_15_2","doi-asserted-by":"publisher","DOI":"10.1007\/s44344-024-00002-3"},{"key":"e_1_3_6_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2018.02.033"},{"key":"e_1_3_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2019.06.031"},{"key":"e_1_3_6_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2017.07.006"},{"key":"e_1_3_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/jccs.202000303"},{"key":"e_1_3_6_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC01767A"},{"key":"e_1_3_6_21_2","doi-asserted-by":"publisher","DOI":"10.2174\/1570193X17666200102105440"},{"key":"e_1_3_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c02492"},{"key":"e_1_3_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.9b00879"},{"key":"e_1_3_6_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130230"},{"key":"e_1_3_6_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119640"},{"key":"e_1_3_6_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b00811"},{"key":"e_1_3_6_27_2","doi-asserted-by":"publisher","DOI":"10.1080\/10242422.2018.1510492"},{"key":"e_1_3_6_28_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10853-020-04415-x"},{"key":"e_1_3_6_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2024.131278"},{"key":"e_1_3_6_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121383"},{"key":"e_1_3_6_31_2","doi-asserted-by":"publisher","DOI":"10.1055\/a-1697-7758"},{"key":"e_1_3_6_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c02362"},{"key":"e_1_3_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.0c02627"},{"key":"e_1_3_6_34_2","doi-asserted-by":"publisher","DOI":"10.3390\/catal14020148"},{"key":"e_1_3_6_35_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2023.03.005"},{"key":"e_1_3_6_36_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-022-23777-7"},{"key":"e_1_3_6_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b05031"},{"key":"e_1_3_6_38_2","doi-asserted-by":"publisher","DOI":"10.9767\/bcrec.16.2.10398.267-279"},{"key":"e_1_3_6_39_2","doi-asserted-by":"publisher","DOI":"10.3390\/catal10020162"},{"key":"e_1_3_6_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.5880"},{"key":"e_1_3_6_41_2","first-page":"2381","article-title":"Reduction of aldehydes and ketones by NaBH4 in presence of 1-alkyl-1,2,4-triazolium salts","volume":"33","author":"Gayathri KM","year":"2020","unstructured":"Gayathri KM, Paramparambath S, Satheesh A, Selvam S, Kandasamy E. 2020 Reduction of aldehydes and ketones by NaBH4 in presence of 1-alkyl-1,2,4-triazolium salts. Mater. Today 33, 2381\u20132384. (doi:10.1016\/j.matpr.2020.05.470)","journal-title":"Mater. Today"},{"key":"e_1_3_6_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.202000310"},{"key":"e_1_3_6_43_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT03495B"},{"key":"e_1_3_6_44_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10570-023-05350-1"},{"key":"e_1_3_6_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.6b02464"},{"key":"e_1_3_6_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202101531"},{"key":"e_1_3_6_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201701708"},{"key":"e_1_3_6_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b05085"},{"key":"e_1_3_6_49_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-019-02748-0"},{"key":"e_1_3_6_50_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2020.117719"},{"key":"e_1_3_6_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202001376"},{"key":"e_1_3_6_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202202300"},{"key":"e_1_3_6_53_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2016.05.013"},{"key":"e_1_3_6_54_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2020.07.014"},{"key":"e_1_3_6_55_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC04440K"},{"key":"e_1_3_6_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2CY00205A"},{"key":"e_1_3_6_57_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2021.04.023"},{"key":"e_1_3_6_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.3136"},{"key":"e_1_3_6_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201801054"},{"key":"e_1_3_6_60_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11164-022-04678-w"},{"key":"e_1_3_6_61_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-019-02756-0"},{"key":"e_1_3_6_62_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0NJ03680C"},{"key":"e_1_3_6_63_2","first-page":"286","article-title":"Post-synthetic modification of IRMOF-3 with an iminopalladacycle complex and its application as an effective heterogeneous catalyst in Suzuki-Miyaura cross-coupling reaction in H2O\/EtOH media at room temperature","volume":"443","author":"Nouri F","year":"2017","unstructured":"Nouri F, Rostamizadeh S, Azad M. 2017 Post-synthetic modification of IRMOF-3 with an iminopalladacycle complex and its application as an effective heterogeneous catalyst in Suzuki-Miyaura cross-coupling reaction in H2O\/EtOH media at room temperature. Mol. Catal. 443, 286\u2013293. (doi:10.1016\/j.mcat.2017.10.019)","journal-title":"Mol. Catal."},{"key":"e_1_3_6_64_2","article-title":"Mechanism of transfer hydrogenation of carbonyl compounds by zirconium and hafnium-containing metal-organic frameworks","volume":"522","author":"Rahaman MS","year":"2022","unstructured":"Rahaman MS, Tulaphol S, Hossain MdA, Mulvehill MC, Spurgeon JM, Maihom T, Sathitsuksanoh N. 2022 Mechanism of transfer hydrogenation of carbonyl compounds by zirconium and hafnium-containing metal-organic frameworks. Mol. Catal. 522, 112247. (doi:10.1016\/j.mcat.2022.112247)","journal-title":"Mol. Catal."},{"key":"e_1_3_6_65_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00609E"},{"key":"e_1_3_6_66_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2020.04.013"},{"key":"e_1_3_6_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c02827"},{"key":"e_1_3_6_68_2","doi-asserted-by":"publisher","DOI":"10.3390\/catal11080914"},{"key":"e_1_3_6_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c02156"},{"key":"e_1_3_6_70_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2023.106717"},{"key":"e_1_3_6_71_2","article-title":"Selective hydrogenation of furfural to furfuryl alcohol over Pd\/TiH2 catalyst","volume":"508","author":"Wang Z","year":"2021","unstructured":"Wang Z, Wang X, Zhang C, Arai M, Zhou L, Zhao F. 2021 Selective hydrogenation of furfural to furfuryl alcohol over Pd\/TiH2 catalyst. Mol. Catal. 508, 111599. (doi:10.1016\/j.mcat.2021.111599)","journal-title":"Mol. Catal."},{"key":"e_1_3_6_72_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA10838C"},{"key":"e_1_3_6_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c02658"},{"key":"e_1_3_6_74_2","unstructured":"Bijani FM Sardarian A. 2025 Supplementary material from: Reusable Mg Supported IRMOF-3 as a Nanocatalyst for Chemoselective Reduction of Biomass-Based Aldehydes and Ketones to Alcohols under Mild Conditions. Figshare (doi:10.6084\/m9.figshare.c.7891192)"}],"container-title":["Royal Society Open Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/royalsocietypublishing.org\/doi\/pdf\/10.1098\/rsos.242257","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/royalsocietypublishing.org\/doi\/full-xml\/10.1098\/rsos.242257","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/royalsocietypublishing.org\/doi\/pdf\/10.1098\/rsos.242257","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,8,6]],"date-time":"2025-08-06T05:00:03Z","timestamp":1754456403000},"score":1,"resource":{"primary":{"URL":"https:\/\/royalsocietypublishing.org\/doi\/10.1098\/rsos.242257"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,8]]},"references-count":73,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2025,8]]}},"alternative-id":["10.1098\/rsos.242257"],"URL":"https:\/\/doi.org\/10.1098\/rsos.242257","relation":{"has-review":[{"id-type":"doi","id":"10.1098\/RSOS.242257\/v1\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1098\/RSOS.242257\/v1\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1098\/RSOS.242257\/v2\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1098\/RSOS.242257\/v2\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1098\/RSOS.242257\/v1\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1098\/RSOS.242257\/v1\/review4","asserted-by":"object"},{"id-type":"doi","id":"10.1098\/RSOS.242257\/v2\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1098\/RSOS.242257\/v1\/review3","asserted-by":"object"},{"id-type":"doi","id":"10.1098\/RSOS.242257\/v2\/decision1","asserted-by":"object"}]},"ISSN":["2054-5703"],"issn-type":[{"value":"2054-5703","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,8]]},"assertion":[{"value":"2024-12-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-30","order":1,"name":"revised","label":"Revised","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-05-26","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-08-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"242257"}}