{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,27]],"date-time":"2026-02-27T01:34:27Z","timestamp":1772156067274,"version":"3.50.1"},"reference-count":34,"publisher":"The Royal Society","issue":"11","license":[{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T00:00:00Z","timestamp":1761955200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Administration for Marketing Regulation of Henan Province"},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["royalsocietypublishing.org"],"crossmark-restriction":true},"short-container-title":["R. Soc. Open Sci."],"published-print":{"date-parts":[[2025,11]]},"abstract":"<jats:p>\n                    A sensitive method for sulfur dioxide (SO\n                    <jats:sub>2<\/jats:sub>\n                    ) determination was developed with reaction cell inductively coupled plasma mass spectrometer (ICP-MS) by preconcentrating SO\n                    <jats:sub>2<\/jats:sub>\n                    from gas samples to solutions. O\n                    <jats:sub>2<\/jats:sub>\n                    flow rate was set at 0.7 ml min\n                    <jats:sup>\u22121<\/jats:sup>\n                    for optimal signal to noise ratio at\n                    <jats:italic toggle=\"yes\">m\/z<\/jats:italic>\n                    48 (\n                    <jats:sup>32<\/jats:sup>\n                    S\n                    <jats:sup>16<\/jats:sup>\n                    O\n                    <jats:sup>+<\/jats:sup>\n                    ). Favourable conditions to prepare SO\n                    <jats:sub>2<\/jats:sub>\n                    concentrated solutions including sampling flow rate, the volume of concentrated solution, the number of perfluoroalkoxy alkane (PFA) bubble absorption bottles and the composition of concentrated solution were investigated using SO\n                    <jats:sub>2<\/jats:sub>\n                    in nitrogen gas reference materials within the range of 5.00 parts per billion (ppb) to 1.00 parts per million (ppm). A limit of detection (LOD) of 0.11 ppb was achieved, corresponding to 100 l 5.00 ppb SO\n                    <jats:sub>2<\/jats:sub>\n                    with a sampling flow rate of 0.5 l min\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This method also showed favourable selectivity in the assay of atmosphere SO\n                    <jats:sub>2<\/jats:sub>\n                    level, providing its promising further application in monitoring gaseous environmental pollutants.\n                  <\/jats:p>","DOI":"10.1098\/rsos.251097","type":"journal-article","created":{"date-parts":[[2025,11,12]],"date-time":"2025-11-12T00:07:36Z","timestamp":1762906056000},"update-policy":"https:\/\/doi.org\/10.1098\/crossmark-policy","source":"Crossref","is-referenced-by-count":0,"title":["A sensitive method for atmospheric sulfur dioxide determination by reaction cell inductively coupled plasma mass spectrometer"],"prefix":"10.1098","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-0079-7167","authenticated-orcid":true,"given":"Qi-Xuan","family":"Sun","sequence":"first","affiliation":[{"name":"Henan Institute of Metrology","place":["Zhengzhou, People\u2019s Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bo","family":"Li","sequence":"additional","affiliation":[{"name":"Henan Institute of Metrology","place":["Zhengzhou, People\u2019s Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao-Ping","family":"Kong","sequence":"additional","affiliation":[{"name":"Henan Institute of Metrology","place":["Zhengzhou, People\u2019s Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shang-Qing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Northeastern University","place":["Shenyang, People\u2019s Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"175","published-online":{"date-parts":[[2025,11,12]]},"reference":[{"key":"e_1_3_7_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.measurement.2024.115255"},{"key":"e_1_3_7_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2023.133165"},{"key":"e_1_3_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2017.08.054"},{"key":"e_1_3_7_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2020.128002"},{"key":"e_1_3_7_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.uclim.2022.101291"},{"key":"e_1_3_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.4c00427"},{"key":"e_1_3_7_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9AN02322D"},{"key":"e_1_3_7_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.measurement.2023.112766"},{"key":"e_1_3_7_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2024.123864"},{"key":"e_1_3_7_11_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00340-022-07776-0"},{"key":"e_1_3_7_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3AN01431B"},{"key":"e_1_3_7_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2009.06.039"},{"key":"e_1_3_7_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2017.02.023"},{"key":"e_1_3_7_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2018.01.156"},{"key":"e_1_3_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac9812429"},{"key":"e_1_3_7_17_2","doi-asserted-by":"publisher","DOI":"10.3390\/s19040905"},{"key":"e_1_3_7_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.analchem.3c05936"},{"key":"e_1_3_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssensors.9b02448"},{"key":"e_1_3_7_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2024.135340"},{"key":"e_1_3_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.analchem.4c01480"},{"key":"e_1_3_7_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac50157a031"},{"key":"e_1_3_7_23_2","first-page":"1744","article-title":"Determination of sulfur dioxide by ultraviolet absorption spectrometry","volume":"39","author":"Syty A","year":"1967","unstructured":"Syty A. 1967 Determination of sulfur dioxide by ultraviolet absorption spectrometry. 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